• Title/Summary/Keyword: 산화/용해

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Property Change of Heat-reservoir Refractory Brick With Varying Compositions and Sintering Conditions Utilizing Mill-scale and Red-firing Clay As Raw Materials (밀스케일과 적점토를 원료로한 축열재에서 원료성분과 소성조선에 따른 특성 변화)

  • Kim, Jeong-Seog;Kim, Hong
    • Resources Recycling
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    • v.8 no.1
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    • pp.23-28
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    • 1999
  • Firing characteristics, transverse rupture strength, and heat capacity were studied of the heat-reservoir refractory materials made of red-firing clay, mill scale, and water glass. The firing shrinkage increased with increase of the clay proportion in samples. The volume of fired bodies showed shrinkage by drying up to $300^{\circ}C$, steady expansion in the 300-$700^{\circ}C$ range due to phase transition of iron oxides. and drastic expansion above $1200^{\circ}C$. Flexural strength decreased from 5.6 Mpa to 2.35 Mpa with the decrease of the ratio of clay to mill scale from 1:1 to 1:3 Heat capacities changed from 1.1 Joul/g$^{\circ}$C to 1.35 Joul/g$^{\circ}$C with the ratio of millscale to clay ratio from 1:1 to 1:3. Mill scale in the specimen appears to exist as liquid phase during firing. Firing the specimens in air leads to the eruption of the molten mill scale to the sample surfaces. Contrarily, firing samples in a refractory sagger with a cover suppressed the eruption of the molten mill scale to the surfaces. The addition of mill scale gave rise to porous sintered bodies which would delay cooling rates of heat-reservoir brick.

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The Effects of the Residual Ba and Zr on the Acid Pickling in Case of the Recovering of Zr in Pickling Waste Acid through the BaF2 Precipitation Process (BaF2 침전 공정을 통한 폐산세정액 내 Zr 회수 시 잔존 Ba 및 Zr이 산세정에 미치는 영향)

  • An, Chang Mo;Choi, Jeong Hun;Han, Seul Ki;Park, Chul Ho;Kahng, Jong Won;Lee, Young Jun;Lee, Jong Hyeon
    • Resources Recycling
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    • v.26 no.5
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    • pp.97-104
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    • 2017
  • Nuclear fuel cladding tubes are manufactured through pilgering and the annealing process. In order to remove the oxidized layer and impurities on the surface of the tube, a pickling process is required. Zirconium (Zr) is dissolved in a HF and $HNO_3$ acid mixture during the process and the pickling waste acid, including the dissolved Zr, is completely discarded after neutralization. This study observes the effects of the residual impurities (Ba) in the pickling solution regenerated from the $BaF_2$ precipitation process on the waste pickling solution. In addition, the concentration of Ba and Zr for the actual nuclear fuel cladding tube process was optimized. The regenerated pickling solution was tested through a pilot plant pickling process device that simulates the commercial pickling process of nuclear fuel cladding tubes, and the pickling efficiency was analyzed through AFM analysis of the roughness of the cladding tube surface.

Cellular protective effect of Ecklonia cava extract on ultra-fine dust (PM2.5)-induced cytoxicity (초미세먼지(PM2.5)로 유도된 in vitro 세포 독성에 대한 감태(Ecklonia cava) 추출물의 보호 효과)

  • Park, Seon Kyeong;Kang, Jin Yong;Kim, Jong Min;Yoo, Seul Ki;Han, Hye Ju;Shin, Eun Jin;Heo, Ho Jin
    • Korean Journal of Food Science and Technology
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    • v.51 no.5
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    • pp.503-508
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    • 2019
  • To evaluate the protective effect of Ecklonia cava on ultra-fine dust ($PM_{2.5}$)-induced cytotoxicity, we investigated the in vitro antioxidant activity and cell viability after exposure to $PM_{2.5}$. E. cava was extracted using water and 80% ethanol, and antioxidant activity was determined using the 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulphonic acid) (ABTS)/2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging and lipid peroxidation inhibition assays. The 80% ethanol extract showed relatively higher antioxidant activity than the water extract. The cell protective effects were determined by measuring the intracellular reactive oxygen species (ROS) content and viability of nasal epithelial (RPMI-2650), lung epithelial (A549), and brain neuroblastoma (MC-IXC) cells. Results showed that the 80% ethanol extract inhibited ROS production more than the water extract. In contrast, both extracts showed similar effects on cell viability in the $PM_{2.5}$-induced cell death assay. Thus, Ecklonia cava may act as an effective resource for preventing $PM_{2.5}$-induced cytotoxicity in nasal, lung, and brain cells.

Quality Characteristics of Kimchi Prepared for the Winter around Chonnam Area (전남지역 김장 배추김치의 품질 특성)

  • 박복희;조희숙;유맹자
    • Korean Journal of Human Ecology
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    • v.6 no.2
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    • pp.57-65
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    • 2003
  • To investigate quality characteristics of kimchi prepared for the winter around Chonnam area, home made kimchi samples collected from 22 area, and they were stored at -1${\pm}$1$^{\circ}C$. The results were as follows : The pH and acidity of kimchi samples were 4.75 and 0.84%. respectively. Salt concentration was 3.50% and in Redox potential measurement, Eh value was -134.08mV. Ascorbic acid and reducing sugar contents were 10.l8mg% and 13.25mg%, respectively, In color measurement, L value was 52.29 and a and b values were 19.68 and 27.69, respectively. Total viable count was 5.5${\times}$10$\^$6/ and lactic acid bacteria count and yeast were 4.6${\times}$10$\^$5/ and 8.8${\times}$10$\^$5/. respectively. Properties of hardness of kimchi measured instrumentally was 9.26kgf. Alcohol insoluble solids(AIS) content was 5.53% and hot water soluble pectin(HWSP) content and sodium hexametaphosphate soluble pectin(NaSP) content were 17.35% and 29.65%, respectively, also hydrochloric acid soluble pectin(HClSP) content was 53.0%.

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Bioconversion of nitrogen oxides and reduction of ferric ions by probiotic lactic acid bacteria (프로바이오틱스 유산균에 의한 질소 산화물 전환 및 철 이온 환원활성)

  • Kim, Selim;Hong, Jungil
    • Korean Journal of Food Science and Technology
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    • v.53 no.6
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    • pp.785-791
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    • 2021
  • Many lactic acid bacteria (LAB) have probiotic properties that exert various health benefits. In this study, the reduction potential of nitrogen oxide compounds and ferric ions by six LAB, including Lactobacillus kimchicus, L. lactis, L. casei, L. plantarum, L. rhamnosus GG, and Leuconostoc mesenteroides were evaluated. The L. kimchicus strain produced a substantial amount of nitrite reduced from nitrate added to the media, whereas the other five LAB strains did not. L. kimchicus also showed the most potent reducing activity of ferric to ferrous ions. However, the reduction potential of the autoclaved L. kimchicus was little pronounced. The scavenging activities of viable LAB or their cell lysates against different radicals were not consistent with the potency of the LAB's reducing ability. The present results indicate that L. kimchicus has a strong reduction potential for nitrogen oxides in viable status, and that this ability can be used as a probiotic property for various health benefits.

A New Short Stem, Lodging Resistance and High Yielding Vegetable Peanut cultivar, "Jopyeong" (조숙 단경 내도복 다수성 풋땅콩 "조평")

  • Pae, Suk-Bok;Park, Chang-Hwan;Cheong, Young-Keun;Jung, Chan-Sik;Lee, Myung-Hee;Lee, Yu-Young;Hwang, Chung-Dong;Oh, Se-Kwan;Kim, Jung-Tae;Park, Keum-Yong;Kim, Wook-Han;Choi, Gyu-Hwan;Lee, Jae-Chul;Jeong, Byung-Joon;Kim, Ho-Young
    • Korean Journal of Breeding Science
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    • v.40 no.1
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    • pp.63-67
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    • 2008
  • A new peanut cultivar "Jopyeong" (Arachis hypogaea ssp. hypogaea L.) was developed at the Yeongnam Agricultural Research Institute, NICS, in Milyang in 2006. It was developed from the cross between the very short stem cultivar "CUP brittle" and the high-yielding cultivar "Daekwang". "Jopyeong" which is Virginia plant type has 23 branch number per plant with early maturing and ellipse-shaped large kernel. Each pod has two grains with brown testa and 100 seed weight was 87g in the regional yield trials (RYT). This variety also showed more resistant to late leaf spots compared with check one. Especially it has resistance to lodging owing to short stem and erect plant type. In the regional yield trials "Jopyeong" was out-yielded than check variety by 11% with 8.37 ton/ha for fresh pod and by 4% with 3.95 ton/ha for grain.

A New Early Maturing, Lodging Resistance and High Yielding Vegetable Peanut "Seonan" (조숙 내도복 다수성 풋땅콩 품종 "선안")

  • Pae, Suk-Bok;Park, Chang-Hwan;Cheong, Young-Keun;Hwang, Chung-Dong;Lee, Myung-Hee;Shim, Kang-Bo;Jung, Chan-Sik;Kang, Churl-Whan;Park, Keum-Yong;Park, Chung-Berm;Choi, Gyu-Hwan;Lee, Jae-Chul;Kim, In-Jae;Kim, Sun-Lim;Kim, Je-Gyu
    • Korean Journal of Breeding Science
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    • v.40 no.2
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    • pp.178-183
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    • 2008
  • A new peanut variety "Seonan" (Arachis hypogaea ssp. hypogaea L.) was developed at the Yeongnam Agricultural Research Institute, NICS, in Milyang in 2007. It was developed from the cross between the erect short stem cultivar "SP9128" and the high-yielding cultivar "Daekwang". "Seanan" which is Virginia plant type has 18 branch number per plant with early maturing and long-ellipse shaped large kernel. Each pod has two grains with brown testa and 100 seed weight was 87 g in the regional yield trials (RYT). Especially this variety has resistance to lodging owing to short stem. The free sugar and tannin content of fresh peanut are 3.7% and 0.48%, respectively, similar to check variety. In the regional yield trials "Seonan" was outyielded than check variety by 14% with 8.59 MT/ha for fresh pod and by 7% with 3.75 MT/ha for grain.

A Study on the Vanadium Oxide Thin Films as Cathode for Lithium Ion Battery Deposited by RF Magnetron Sputtering (RF 마그네트론 스퍼터링으로 증착된 리튬 이온 이차전지 양극용 바나듐 옥사이드 박막에 관한 연구)

  • Jang, Ki-June;Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.6
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    • pp.80-85
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    • 2019
  • Vanadium dioxide is a well-known metal-insulator phase transition material. Lots of researches of vanadium redox flow batteries have been researched as large scale energy storage system. In this study, vanadium oxide($VO_x$) thin films were applied to cathode for lithium ion battery. The $VO_x$ thin films were deposited on Si substrate($SiO_2$ layer of 300 nm thickness was formed on Si wafer via thermal oxidation process), quartz substrate by RF magnetron sputter system for 60 minutes at $500^{\circ}C$ with different RF powers. The surface morphology of as-deposited $VO_x$ thin films was characterized by field-emission scanning electron microscopy. The crystallographic property was confirmed by Raman spectroscopy. The optical properties were characterized by UV-visible spectrophotometer. The coin cell lithium-ion battery of CR2032 was fabricated with cathode material of $VO_x$ thin films on Cu foil. Electrochemical property of the coin cell was investigated by electrochemical analyzer. As the results, as increased of RF power, grain size of as-deposited $VO_x$ thin films was increased. As-deposited thin films exhibit $VO_2$ phase with RF power of 200 W above. The transmittance of as-deposited $VO_x$ films exhibits different values for different crystalline phase. The cyclic performance of $VO_x$ films exhibits higher values for large surface area and mixed crystalline phase.

Evaluation of Ozone Resistance and Anti-Corrosion Performance of Water Treatment Concrete according to Types of Metal Spray Coating (수처리시설용 콘크리트의 금속용사 피막 종류에 따른 내오존성 및 전기화학적 방식 성능 평가)

  • Park, Jin-Ho;Choi, Hyun-Jun;Lee, Han-Seung;Kim, Sang-yeol;Jang, Hyun-O
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.4
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    • pp.61-68
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    • 2019
  • As the pollution of water resources deteriorates due to industrialization and urbanization, it is difficult to supply clean water through a water treatment method using chlorine. Therefore, the introduction of advanced water treatment facilities using ozone is on the increase. However, epoxy which is used as waterproofing and anticorrosives and stainless steel used in conventional waterproofing and anti-corrosive methods have deteriorated because of the strong oxidizing power of ozone, causing problems such as leaking. Moreover, it even causes the durability degradation of a concrete. Therefore, in this study, metal spraying system was used as the means of constructing a metal panel with excellent ozone resistance and chemical resistance which is an easier method than an existing construction method. Ozone resistance was evaluated in accordance with the type of metal sprayed coatings to develop a finishing method which can prevent the concrete structure of water treatment facilities from deterioration. Furthermore, electrochemical stability in actual sewage treatment plant environment was evaluated. Experimental results showed that Ti has superior ozone resistance after spraying and the electrochemical stability in the sewage treatment plant environment showed that Ti has the highest polarization resistance of $403.83k{\cdot}{\Omega}{\cdot}cm^2$, which ensures high levels of durability.

Study on Influencing Factors of Adhesive Strength for Polymer Coating on Metal Adherend by Dolly Test (돌리테스트로 고분자 코팅층과 금속 피착재의 접착강도 측정시 영향인자에 대한 연구)

  • Baeg, Ju-Hwan;Park, Hyun;Lee, Sung In;Ha, Yungeun;Cho, Young-Rae
    • Journal of the Microelectronics and Packaging Society
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    • v.26 no.2
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    • pp.1-8
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    • 2019
  • The demand and importance of adhesives and paint coatings applied to solid surfaces such as metals, ceramics, and plastics are increasing. In this study, the influencing factors on the adhesive strength between the polymer coating and the metal adherend were investigated by Dolly test when the adhesive or the paint coating was applied on the metal adherend. Two-component epoxy adhesive was used as the adhesive, and EH2350, a two-component epoxy paint for anti-corrosion, was used as the paint. Especially, the effect of adherend metals(Al, Fe, STS, Cu, Zn), surface roughness and surface contamination(tap water, salt water) on adhesive strength was studied as influencing factors. The adhesive strength between adhesive and adherend was different when the type of metal adherend was different even when the same adhesive was used. It was found that spray water cleaning was necessary before the paint coating process on the surface of the oxide contaminated adherend with tap water or salt water. As a result of this study, it was confirmed that Dolly test can be widely used in the future to measure adhesive strength between paint coating and adherend.