• Journal of the Korean Institute of Gas
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• v.27 no.1
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• pp.23-32
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• 2023

In this study, the Al₂O₃ nanofluid was synthesized as an additive for improving the injection efficiency and storage capacity of carbon dioxide (CO₂) in a depleted sandstone reservoir or deep saline aquifer. As the base fluid, deionized water (DIW) and saline prepared by referring to the composition of API Brine were used, and the fluid was synthesized by using Al₂O₃ nanofluid with CTAB (cetyltrimethyl-ammonium bromide), a cationic surfactant. After that, the dispersion stability was evaluated by using visual observation, dynamic light scattering (DLS), transmission electron microscope (TEM), and miscibility test. As a result, it was presented that stable nanofluid without agglomeration and precipitation after reaction with 70,000 ppm of brine could be synthesized when the nanoparticle concentration was 0.05 wt% or less.

• Korean Journal of Soil Science and Fertilizer
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• v.39 no.5
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• pp.245-252
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• 2006

This experiment was conducted to investigate the distribution and compositions of clay mineral and to replenish the soil classification system in Korea. Soil layer samples were collected from 26 residuum and colluvium soil series out of 390 soil series in Korea, and then analyzed for soil physical and chemical characteristics, mineral and chemical compositions of clay in B horizon soils. Major clay minerals of residuum and colluvium were illite and chlorite in soils originated from the sedimentary rock such as limestone, shale, sandstone and conglomerate; quartz and kaolin in soils originated from rhyolite, neogene deposits, porphyry and tuff; and kaolin and quartz in the soils originated from granite, granite gneiss and anorthosite. Clay minerals in Korean soils were divided into 4 groups: mixed mineral group(MIX) mainly contained with illite, kaolin and vemiculite; kaolin group(KA) with kaolin and illite; chlorite group(CH) with chlorite and illite; and smectite group(SM) with kaolin, illite and smectite. The most predominant clay mineral group was kaolin group(KA) with kaolin and illite; an mixed mineral group(MIX) with illite, kaolin and vemiculite. Cation exchange capacity (CEC) of clay was low in the soils mainly composed with MIX and KA groups and silica-alumina molar ratio of clay was high in the soils composed with SM group

• Korean Journal of Heritage: History & Science
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• v.47 no.2
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• pp.46-67
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• 2014

The Dinosaur track-bearing deposits recently found at Bangudae Petroglyph site in Ulju (National Treasure No. 285) have been studied in the aspects of sedimentology, paleoenvironments, and significance in natural history. The dinosaur tracks occur in the Daegu Formation (late Early Cretaceous), and over 80 footprints including 43 ornithopod footprints, 36 sauropod footprints, and 2 theropod footprints are preserved in this tracksite. The track-bearing deposits consist of irregularly interlaminated siltstone and mudstone, calcareous sandy to silty mudstone, thin-bedded tuffaceous sandstone, planar- to cross-laminated sandstone, and thin- to medium-bedded graded sandstone, and they are interpreted to be sheetflood deposits on an alluvial plain. Diverse types of ripples and mudcracks, rainprints, and invertebrate trace fossils are observed in these deposits, and the crest-lines of wave ripples do not show preferred orientation. Dinosaur footprints occur as true prints, underprints, overtracks, and casts on the bedding surfaces, and the orientation of trackways are scattered. It is interpreted that paleoclimatic condition of the track-bearing deposits were semiarid with alternation of wetting and drying periods, and that dinosaurs frequented small and shallow ponds during wetting periods and recorded their tracks on an alluvial plain. The frequent occurrence of dinosaur tracks in study area indicates that the Cretaceous deposits around Daegokcheon Stream are very useful sedimentological and paleontological records to understand the paleoecology and paleoenvironments during the dinosaur age in Korean Peninsula. Consequently the dinosaur track-bearing deposits around Daegokcheon Stream should be further studied in sedimentary geology and paleontology in order to enhance cultural heritage value of the Petroglyphs of Bangudae Terrace as the World Heritage.

• Korean Journal of Soil Science and Fertilizer
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• v.43 no.6
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• pp.837-843
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• 2010

This research investigated classification of clay activity degree by different clay mineral components. Based on compositions of different clay and oxide minerals within 390 soil series in Korea, 7 soils were selected to analyze for CEC and specific surface area of clay minerals. As a result, soils were mainly composed with Chlorite originated from sandstone, Smectite originated from Andesite porphyry and combination of Allophane and Ferrihydrite originated from volcanic ash, if the ratio of CEC value to clay content (degree of clay activity) was greater than 0.7. If the degree of clay activity was ranged between 0.3 and 0.7, soils were composed mainly with Kaolin originated from anorthite. Soils with this ratio also was composted with combinations of Kaolin, Illite and Vermiculite originated with river deposits. When the degree of the activity was less than 0.3, soils were commonly red-yellowish color and composed with two different minerals. One type of composition was Kaolin originated from granite and granite gneiss and the soils contained Geothite and Hematite. The other type was composited mainly with Illite and Vermiculite minerals originated from granite. These soils contained Gibbsite, Geothite and Hematite. The degree of clay activity was highly related with CEC and specific surface area. The greater degree of the activity displayed greater values of clay CEC and specific surface area. It is not easy to measure actual quantity and compositions of clay minerals, while the degree of clay activity can be measured from routine soil analyses. As a conclusion, the degree of clay activity may be not just a simple but also powerful tool to estimate physical-chemical properties of soils and to evaluate the soil classification in Korean soils.

• Journal of Conservation Science
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• v.34 no.3
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• pp.167-177
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• 2018

The Bayon style Avalokitesvara statue from the $13^{th}$ century Angkor period is on display at the Cambodia Angkor Conservation Office. This statue is composed of dark green felthspathic greywacke, the surface of which has been shown light brown discoloration, detected calcite crystallization. As a result of condition assessment, the statue was damaged due to overlap scaling and cracking. Ultrasonic tests have investigated remarkable physical weathering area, flaking and fragmentation in lower velocity. The physical condition of the statue requires a conservation method that improves the binding power. To protect against salt weathering and to ensure physical stability, new conservation material composed of mixed ethyl silicate and sandstone powder similar to that composing the statue was created. The material affected by damage was removed and replaced with the new conservation material.

• Tunnel and Underground Space
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• v.20 no.5
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• pp.360-368
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• 2010

The paper presents a case study from a surface mine where the controlled augmentation of throw and drop of the blasted muck piles was warranted to spread the muck piles on the lower berm of the bench. While the augmentation of throw increased the lateral spread and the looseness of the broken muck, the augmentation of drop significantly lowered the muck pile height for easy excavation by the excavators. In this light, the present paper highlights and discusses some pertinent changes in the blast design parameters for such specialized application of cast blasting in a surface mine, where a sandstone bench, with average height of 22-24 m was to be made amenable for excavation by 10 m3 rope shovels, which possessed maximum digging capability of up to 14 m. The results of tailoring the blast design parameters for augmentation of throw and drop are compared with the baseline blasts which were earlier practiced on the same bench by dividing the full height of the bench in 2-slices; upper slice (10-14 m high) and lower slice (12-15 m high). Results of fragment size, its distribution and total cycle time of excavator (shovel) are presented, and discussed.

• Korean Journal of Soil Science and Fertilizer
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• v.6 no.3
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• pp.141-152
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• 1973

The mineralogical studies of the eleven sub-soil samples derived from granite, granodiorite, diorite and arkose sandstone, taken from apple orchards in the province of Kyungsangbukdo, Korea are made to investigate the relationships between the mineral weathering, soil forming processes and mineralogical composition. The fine sand fraction (less than 0.2mm) and the clay fraction (less than 2 micron) are dispersed with the shaker after hydrogen peroxide treatment for the removal of organic matter, and separated from each suspension by gravity sedimentation. The fine sand are observed by mineral microscope and the clay are observed by X-ray diffraction patterns, differential thermal analysis curves and infrared spectrum. The outline of the results are as follows. 1. The primary minerals ; Quartz, changed-feldspar, plagioclase, alkali-feldspar are dominant in almost all samples, and some samples contain an appreciable amount of hornblende, biotite, muscovite and plant opal. There are also those samples which contain very small quantity of pyroxene group, tourmaline, epidote, cyanite, magnetite, volcanic glass and zircon. They are mainly derived from weathering products of granite, granodiorite, diorite, arkose or its mixtures. 2. All samples contain expanding or nonexpanding $14{\AA}$ minerals, illite and kaolin minerals, and some samples contain chlorite, cristobalite, gibbsite, and those primary minerals as quartz and feldspar, but the quantities vary according to the parent matrials. 3. Non-expanding $14{\AA}$ minerals may be dioctahadral vermiculite which sandwiches gibbsite layer or chlorite in between layer lattices. 4. As for clay minerals, montmorillonite was principal component in the samples derived from weathering products of arkose sandstone and tertiary. Minerals which are derived from weathering products of arkose have kaolin minerals and vermiculite as their principal component, and minerals derived from weathering products of acidic rock group are generally classified into two groups, the kaolin mineral group, and the kaolin minerals and vermiculite group.

• Economic and Environmental Geology
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• v.44 no.2
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• pp.171-180
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• 2011

For 21 rock samples consisting of granite, sandstone and the effective thermal conductivity (TC) was measured with the LFA-447 Nanoflash, and mineralogical compositions were also determined from XRD analysis. The structural models were used to examine the effects of quartz content and the size of minerals on TC of rocks. The experimental results showed that TC of rocks was strongly related to quartz content with $R^2$ value of 0.75. Therefore, the proposed regression model can be a useful tool for an approximate estimation of TC only from quartz content. Some samples with similar values of quartz content, however, illustrated great differences in TC, presumably caused by differences in the size of minerals. An analysis from structural models showed that TC of rocks with fine-grained minerals was likely to fall in the region between Series and EMT model, and it moved up to ME and Parallel model as the size of minerals increased. This progressive change of structural models implies that change of TC depending on the size of minerals is possibly related to the scale of experiments; TC was measured from a disk sample with a thickness of 3 mm. Therefore, in case of measurements with a thin sample, TC can be overestimated as compared to the real value in the field scale. The experimental data illustrated that the scale effect was more pronounced for rocks with bigger size of minerals. Thus, it is worthwhile to remember that using a measured TC as a representative value for the real field can be misleading when applied to many geothermal problems.

• Journal of the Korean Society of Groundwater Environment
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• v.5 no.3
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• pp.162-170
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• 1998

Geochemical characteristics of groundwater in Goryeong area, based on chemical analyses of 34 water samples and mineralogical study of rocks, differ among Nagdong, Hasandong and Jinju formations and Goryeong granite in relation to mineralogical compositions of the rocks. Concentrations of most solutes are higher in groundwater of the sedimentary formations than in that of granite. Ca$\^$2＋/ in the sedimentary groundwaters results mainly from reaction of CO$_2$-charged water with calcite and weathered plagioclase. Average groundwater in the Jinju formation is oversaturated with respect to calcite. Major types of groundwaters are hard Ca(HCO$_3$)$_2$ and CaSO$_4$with hardness of 155 mg/1 for Nagdong formation, 150 mg/1 for Hasandong formation and 140 mg/1 for Jinju formation whereas it is soft Ca(HCO$_3$)$_2$with hardness of 90 mg/1 for Goryeong granite. Ca(HCO$_3$)$_2$type resole from dissolution of calcite and plagiodase while CaSO$_4$type results from dissolution of pyrite and partly from domestic pollutants. CaSO$_4$type may indicate that the sedimentary groundwaters are more evolved geochemically than the granitic groundwater, but it is not obvious because the type might be affected by the dissolution of pyrite and domestic pollutions. Prite is expected to occur as a stable sulfide in the gray∼dark gray arkosic sandstones formed under reducing environment.

• Journal of the Mineralogical Society of Korea
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• v.2 no.2
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• pp.73-80
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• 1989

The sedimentary siderite rock or siderostone has been firstly found from the upper part of the Cambrian Myobong Slate in the Sangdong Tungsten Mine area. It occurs as layers between slate and calc-silicate rock (originally siliceous ankerite rock and ferroan dolostone) or within calc-silicate rock. Some parts of the siderostone bed, however, are considerably skarnized to iron-rich skarns, leaving only small-scaled relics. Siderostone consists mainly of siderite and quartz with minor amount of bertioerine and fluorite or apatite and is commonly microcrystalling granular in texture. Stratification is well developed in some siderstone. The siderostone and its skarnized rocks occasionally contain scheelite grains. Siderite also occurs in sandstone and slate. Mineralogy and textures of the siderostone suggest that it might be formed in the shallow marine basin where enough organic matter was present to maintain a low Eh and iron was supplied, and that siderite might be formed largely by diagenesis from iron-rich berthierine mud.