• Journal of the Korean Magnetics Society
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• v.16 no.1
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• pp.18-22
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• 2006

Effects of V substitution of Fe on the magnetic properties of $Fe_3O_4$ have been investigated by x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS), conversion electron Mossbauer spectroscopy (CEMS), and vibrating sample magnetometry (VSM) measurements on sol-gel-grown films. XRD data indicates that the $V_xFe_{3-x}O_4$ films maintain cubic structure up to x=1.0 with little change of the lattice constant. Analyses on V 2p and Fe 2p levels of the XPS data indicate that V exist as $V^{3+}$ mostly in the $V_xFe_{3-x}O_4$ films with the density of $V^{2+}$ ions increasing with increasing V content. Analyses on the CEMS data indicate that $V^{3+}$ ions substitute tetrahedral $Fe^{3+}$ sites mostly, while $V^{2+}$ ions octahedral $Fe^{2+}$ sites. Results of room-temperature VSM measurements on the films reveal that the saturation magnetization for the x=0.14 sample is larger than that of $Fe_3O_4$, while it becomes smaller than that of $Fe_3O_4$ for $x{\geq}0.5$. The coercivity of the $V_xFe_{3-x}O_4$ films is found to increase with x, attributed to the increase of anisotropy by the substitution of $V^{2+}(d^3)$ ions into the octahedral sites.

• Journal of Korean Ophthalmic Optics Society
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• v.5 no.2
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• pp.167-173
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• 2000

Four glasses of $B_2O_3-Bi_2O_3-PbO-SiO_2$ (BBPS) system were prepared by melting the appropriate amounts of reagent grade oxides of $B_2O_3$, $Bi_2O_3$, PbO, and $SiO_2$ in an open crucible. The differential thermal analysis showed crystallization temperature decreased with increasing $Bi_2O_3$ or PbO content in the sample. The structures of glasses system were studied using scanning electron microscopy and Fourier transform-Infra red (FT-IR) spectroscopy. The UV cut-off and refractive index were found to be sensitive to the $Pb^{+2}$ and $Bi^{+3}$ content in the glasses. The behavior of the IR spectra of the glasses in the BP series was consistent with a role of $Bi_2O_3$ as a network former. In the BP series of glasses, the result of IR spectrum indicated that PbO behaved as a network former.

• Journal of the Korean Magnetics Society
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• v.24 no.2
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• pp.46-50
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• 2014

The crystallographic properties and cationic distribution of $M_{0.2}Fe_{2.8}O_4$ (M =Mn, Ni, Cu) and $Fe_3O_4$ thin films prepared by sol-gel method have been investigated by X-ray diffraction (XRD) and conversion electron M$\ddot{o}$ssbauer spectroscopy (CEMS). The ionic valence, preferred site, and hyperfine field of Fe ions of the ferrites could be obtained by analyzing the CEMS spectra. The $M_{0.2}Fe_{2.8}O_4$ films were found to maintain cubic spinel structure as in $Fe_3O_4$ with the lattice constant slightly decreased for Ni substitution and increased for Mn and Cu substitution from that of $Fe_3O_4$. Analyses on the CEMS data indicate that $Mn^{2+}$ and $Ni^{2+}$ ions substitute octahedral $Fe^{2+}$ sites mostly, while $Cu^{2+}$ ions substitute both the octahedral and tetrahedral sites. The observed intensity ratio $A_B/A_A$ of the CEMS subspectra of the samples exhibited difference from the theoretical value. It is interpreted as due to the effect of the M substitution for A and B on the Debye temperature of the site. The relative line-broadening of the B-site CEMS subspectra can be explained by the dispersion of magnetic hyperfine fields due to random distribution of M cations in the B sites.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.22 no.3
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• pp.156-162
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• 2010

When eccentric or inclined load acts on foundation of the port & harbor structures, partial safety factors of bearing capacity limit state were estimated using reliability analysis. Current Korean technical standards of port and harbor structures recommend to estimate the geotechnical bearing capacity using the simplified Bishop method. In practice, however, simple method of comparing ground reaction resistance with allowable bearing capacity has been mostly used by design engineers. While the simple method gives just one number fixed but somewhat convenient, it could not consider the uncertainty of soil properties depending on site by site. Thus, in this paper, partial safety factors for each design variable were determined so that designers do perform reliability-based level 1 design for bearing capacity limit state. For these, reliability index and their sensitivities were gained throughout the first order reliability method(FORM), and the variability of the random variables was also considered. In order to verify partial safety factors determined here, a comparison with foreign design codes was carried out and were found to be reasonable in practical design.

• Journal of the Korean Chemical Society
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• v.18 no.2
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• pp.97-109
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• 1974

The crystal and molecular structure of sulfaguanidine monohydrate, $C_7H_{10}N_4O_2S{\cdot}H_2O$, was determined from visually estimated intensity data from Weissenberg photographs. The crystal data are monoclinic, space group $P2_1$/c with four molecules in a unit cell of dimensions, ${\alpha}=7.57{\pm}0.03,\;b=5.44{\pm}0.02,\;c=24.76{\pm}0.06{\AA},\;{\beta}=91.0{\pm}0.2^{\circ}$. The structure has been solved by an interpretation of a Patterson map and with a help of a direct procedure on a projection. The parameters were refined isotropically by block-diagonal least-squares methods using 1542 observed independent reflections to give R = 0.14. By hydrogen bonding a guanidyl nitrogen of a sulfaguanidine molecule is linked to the sulfonyl oxygens of the other molecules indirectly through two different water molecules. The role of water molecule is both a donor and an acceptor in hydrogen-bonding formation and these hydrogen bonds are tetrahedrally oriented. The hydrogen-bonding networks form infinite molecular layers parallel to (001) plane.

• Geophysics and Geophysical Exploration
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• v.5 no.4
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• pp.257-261
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• 2002

We have carried out integrated research including field survey and numerical modeling to appraise the applicability of SP method to the leakage problems of irrigation facilities. The leakage pattern of the dike studied here can be classified into the three categories: leakage through the abutment, leakage by piping through dike, and leakage due to the composite effects of landslide and distortion of the dike structure. for the numerical modeling to interpret quantitatively SP survey results acquired at dike, we have modified the computer code proposed by Sill (1983) to apply to the leakage problems. The numerical studies match the characteristic patterns of SP anomalies according to the leakage types and appear to be very useful to interpret the leakage zone and path. The SP monitoring results were also well coincided with tidal variations observed at every embankment so we found the SP method is quite effective not only to detect the leakage zone but also to determine the leakage trend. The numerical modeling results also reproduced the SP anomalies due to seawater leakage in the embankment.

• Geophysics and Geophysical Exploration
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• v.18 no.4
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• pp.223-231
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• 2015

Self-potential (SP) is sensitive to groundwater flow and there are many causes to generate SP. Among many mechanisms of SP, pore-fluid flow in porous media can generate potential without any external current source, which is referred to as electrokinetic potential or streaming potential. When calculating SP responses on the surface due to geothermal fluid within an engineered geothermal system (EGS) reservoir, SP anomaly is usually considered to be generated by fluid injection or production within the reservoir. However, SP anomaly can also result from geothermal water fluid within EGS reservoirs experiencing temperature changes between injection and production wells. For more precise simulation of SP responses, we developed an algorithm being able to take account of SP anomalies produced by not only water injection and production but also the fluid of geothermal water, based on three-dimensional finite-element-method employing tetrahedron elements; the developed algorithm can simulate electrical potential responses by both point source and volume source. After verifying the developed algorithm, we assumed a simple geothermal reservoir model and analyzed SP responses caused by geothermal water injection and production. We are going to further analyze SP responses for geothermal water in the presence of water production and injection, considering temperature distribution and geothermal water flow in the following research.

• Journal of the Korean Geotechnical Society
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• v.31 no.4
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• pp.57-66
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• 2015

Empirical seismic displacement equations based on the Newmark sliding block method are widely used to develop seismic landslide hazard map. Most proposed equations have been developed for embankments and landfills, and do not consider the dynamic response of sliding block. Therefore, they cannot be applied to Korean mountain slopes composed of thin, uniform soil-layer underlain by an inclined bedrock parallel to the slope. In this paper, a series of two-dimensional dynamic nonlinear finite difference analyses were performed to estimate the permanent seismic slope displacement. The seismic displacement of mountain slopes was calculated using the Newmark method and the equivalent acceleration time history. The calculated seismic displacements of the mountain slopes were compared to a widely used empirical displacement model. We show that the displacement prediction is significantly enhanced if the slope is modeled as a flexible sliding mass and the amplification characteristics are accounted for. Regression equation, which uses PGA, PGV, Arias intensity of the ground motion and the fundamental period of soil layer, is shown to provide a reliable estimate of the sliding displacement. Furthermore, the empirical equation is shown to reliably predict the hazard category.

• The Journal of Engineering Geology
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• v.25 no.4
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• pp.485-498
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• 2015

Structural analysis for a large-scale fault in Maegok-dong, Ulsan, was carried out based on filed-works to investigate the geometric and kinematic characteristics of the fault as well as its Quaternary slip. As results, a series of repeated stratigraphy, minor faults, fracture zones, and deformation band clusters are observed over a distance of about 100 m in the first studied site consisting of sedimentary rocks, which may indicate the damage zone of a large-scale fault in this site. In the second site, mainly composed of granitic clastic rocks, a large-scale thrust fault is expected based on low-angle dipping faults showing branched and/or merged patterns. Age of the last slip on this fault was restrained as after 33,275 ± 355 yr BP based on radiocarbon dating for organic material included in the gouge zone. Dimension of fault damage zone, dominant sense of slip, and age of the slip event associated with the fault suggest that these structures have a close relationship with the Ulsan Fault and/or Yeonil Tectonic Line, which are well-known large-scale neotectonic structural features around the study area. Therefore, it is necessary to study the characteristics of the faults in detail based on structural geology and paleoseismology in order to ensure seismic and geologic stability of the buildings under construction, and to prevent geologic hazards in this area.

• Journal of Korean Society of Disaster and Security
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• v.11 no.1
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• pp.31-38
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• 2018

The 99.1% of small dam and most of the levees in Korea are soil dam which can be constructed with lower cost and less effort compared with ones made of concrete. However, they are so vulnerable to overflow. Sudden collapses of these strucrues lead to increase flow rate rapidly, which may cause catastrophic problems in downstream regions. In this study, the experimental study on the collapse delay effect of riprap that was laid on slope of soil levee was carried out. A prismatic rectangular open channel was used and three different sizes of the riprap were installed on slope of a scaled earth dam. A new formula for the collapse time of the levee with the installation of riprap was presented, using the previous researches and the dimensional analysis. In this process, an unsteady flow condition was considered to derive the deviation time of the riprap. And additional experiments were conducted to understand the effect of reinforcement of riprap, and it was found that the reinforcement of riprap was more effective than twice sizing of intial riprap. If the collapse time is delayed, EAP (Emergency Action Plan) and forecasting can greatly reduce the degree of flood damage. Also, it will be meaningful that the results of this study are used for river design.