• Title/Summary/Keyword: 비활성 가스

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Volatile Aroma Compounds of Several Domestic Thymus quinquecostatus by Thermal Desorption Gas Chromatograph Mass Spectrometer (열탁착식 가스크로마토질량분석기에 의한 국내 산지별 백리향의 휘발성향기성분)

  • Chiang, Mae-Hee;Lee, Kwang-Woo;Baik, Jung-Ae
    • Journal of Bio-Environment Control
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    • v.20 no.1
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    • pp.14-20
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    • 2011
  • Objective of this research was to investigate the volatile aroma compounds and phenol contents for preservative effects. Aerial part of 5 Korean natured species of thyme located in Jeju alpine, jeju middle mountain, Kyeonggido, Ulleung island, and Gangwondo was analyzed by thermal desorption gas chromatograph mass spectrometer (TD-GC-MSD) method. Jeju middle mountain thyme was relatively high 62 species and has been investigated a high concentration of $7365.22{\mu}g/m^3$ contents according to the quantitative analysis. Total phenol contents containing thymol and carvacrol of Jeju middle mountain thyme were relatively high and showed 35.92%.

산소 유량에 따라 스퍼터된 ZnO 박막의 구조적, 광학적, 전기적 특성

  • Kim, Jong-Uk;Hwang, Chang-Su;Kim, Hong-Bae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.84-84
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    • 2011
  • RF magnetron sputtering을 이용하여 산소 유량에 따라 ZnO 박막을 유리기판 위에 제작하고 구조적, 광학적, 전기적 특성을 조사하였다. 박막 증착 조건의 초기 압력은 $1.0{\times}10^{-6}Torr$, RF 파워는 100W, 증착온도는 상온으로 고정하였으며 기판은 Corning 1737 유리 기판을 사용하였다. 공정 변수로 Ar:$O_2$가스 비율을 50:50 sccm, 75:25 sccm, 100:0 sccm으로 변화시켰다. 유리기판 위에 증착된 모든 ZnO 박막에서 (002) 면의 우선배향성이 관찰되었고 85% 이상의 투과율을 나타내었다. 산소유량이 적을수록 ZnO 박막의 결정성은 향상되었고, 광학적 밴드갭은 증가하였다. Hall 측정 결과 산소의 유량이 포함되어 있는 박막에서는 모두 완전한 산화물에 가까운 화학양론적 조성으로 면 저항이 $10^6{\Omega}/{\square}$ 이상인 부도체 특성을 보였으며, 산소가 포함되지 않은 샘플에서는 n타입의 반도체 특성이 확인되었다. 산소가 포함되지 않은 Ar 유량이 100sccm일 때 전기비저항 $3.56{\times}10^{+1}1{\Omega}cm$, 전하의 농도 $2.04{\times}10^{18}cm^{-3}$, 이동도 $8.59cm^2V^{-1}s^{-1}$로 반도체 활성층으로 적합한 전기적 특성을 얻었다. ZnO 박막의 경우 산소가 포함될 경우 결정성이 저하되고, 절연특성을 갖는 것을 확인할 수 있었다.

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A Study on Structure and Reactivity of Pt-Rh Bimetallic Catalysts (Pt-Rh 이원금속 촉매의 구조와 반응성에 관한 연구)

  • Kim, Young-Kil;Shin, Ki-Whan;Yie, Jae-Eui
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.661-669
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    • 1996
  • Pt-Rh/NaY catalysts with various Pt/Rh ratios were prepared by an ion-exchange method and their characteristics were investigated by $^{129}Xe$-NMR and EXAFS. Both the $^{129}Xe$-NMR and EXAFS data indicate that the surface of PtRh bimetallic clusters was enriched with Rh atoms. The catalytic activities of these catalysts for conversion of CO, HC and $NO_x$ were measured by using simulated automobile engine exhausts under lean, rich and stoichiometric conditions. The Pt-Rh/NaY(Pt/Rh=1) catalyst exhibited the greatest reactive activity among the catalysts used in this study.

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A Study on the Development of 3rd Stage IGG Blower for Shipbuilding Using CFD (CFD를 이용한 선박용 IGG Blower 개발에 관한 연구)

  • Lee, Jong-Jing;Yi, Chung-Seub;Jeong, Soon-Jae;Jang, Sung-Cheol;Kim, Chi-Won
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.1309-1314
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    • 2008
  • I.G.G is abbreviation for Inert Gas Generator, High temperature in Cargo Tank it desulfurize, exhausted and froze the gas that combined brimstone element and soot, then supply Inert gas by blower, and mack tank inside incombustible range this is equipment that nip in the bud the explosion. The blower for suppling inactivated gas has big impeller with heavy weight to achieve the high pressure, it causes a delay for first operation time and too much load is delivered to motor, total destruction by fire of motor is happening frequently. On this research, we will reduce the size & weight of impeller and install it with several stage, it makes an effect for reducing the first operation time. We also intend to contribute to efficient IGG blower design by research a flowing & pressure specialty from the diameter of impeller, number of blade, and size of casing.

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Effects of Activators and Heat Treatment on the Luminous Properties of $Zn_2SiO_4$ Phosphors (활성제 및 열처리효과가 $Zn_2SiO_4$ 형광체의 발광특성에 미치는 영향)

  • Park, Chan-Hyuk;Chung, Sung-Mook;Kim, Young-Jin;Song, Kuk-Hyun;Lee, Joon
    • Korean Journal of Crystallography
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    • v.13 no.2
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    • pp.63-68
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    • 2002
  • Zn/sub 2-x/Mn/sub x/SiO/sub 4/ phosphors for PDP were synthesized by solid state reaction method. The effects of firing temperature, ratio of hydrogen gas to nitrogen for heat treatment and concentration of activator and co-dopants on the luminous properties have been investigated. It was found that the phosphor fabricated at 1400℃ with x = 0.002 Mn concentration had a maximum brightness. Luminous properties of a phosphor were improved when Cr/sup 3+/ was added as a co-dopant rather than other co-dopants.

Study on Bread-making Quality with Barley Sourdough in Composite Bread (보리 Sourdough의 제빵성 연구)

  • Ryu, Chung-Hee;Kim, Sun-Young
    • Korean journal of food and cookery science
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    • v.21 no.5
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    • pp.733-741
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    • 2005
  • Waxy barley flour was fermented by two kinds of starter cultures; L. plantarum and L. brevis, alone or in combination and the effect was evaluated on waxy barley and wheat composite bread quality. In all three barley sourdoughs, fermentation decreased the pH, total sugar and reducing sugar, and increased lactic acid bacteria cell numbers. However yeasts (S. cerevisiae) were reduced. There was significant difference in physicochemical characteristics between the reference(composite barley dough containing improvement agent) and the barley sourdoughs (p <0.05). Barley sourdough fermented by L. plantarum showed more desirable farinogram properties of peak time, stability and elasticity than that of the reference. The rheofermentometer data for L. brevis produced the most $CO_2$ release curve, whereas L. plantarum held maximum $CO_2$ retention differed significantly from that of the breads made with barley sourdoughs fermented with the respectives starter cultures (p < 0.05). Barley sourdough bread fermented with L. plantarum resulted in better bread quality than the reference bread. The positive effect of fermentation with L. plantarum on bread quality was evident when comparing the well developed protein-starch matrix structure of the bread baked with barley sourdough with the reference bread.

Pre-Treatment of Sewage Sludge by Hydrodynamic Cavitation-II: Enhancement of Digestion Efficiency (수리동력학적 캐비테이션을 이용한 하수 슬러지의 전처리-II: 소화효율 향상)

  • Maeng, Jang-Woo;Lee, Eun-Young;Bae, Jae-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.3
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    • pp.264-270
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    • 2010
  • Waste activated sludge from sewage treatment plants mainly consisted of flocs of bacterial cell, and thus hard to be stabilized anaerobically due to rigid cell walls. One of the pretreatment methods to overcome this barrier is the venturi cavitation system (VCS) adopting hydrodynamic cavitation. This research was conducted to investigate the effects of the pretreatment of waste activated sludge by VCS on the anaerobic digestibility. Depending on the pretreatment period with the VCS, methane production, COD removal and VS removal efficiency increased 41%~45%, 36.5%~43.1% and 18.4~24.1%, respectively, compared to the control case. The increase in methane production from digester was 3.3~4.2 times higher than the theoretical methane potential of the increased SCOD after the VCS pre-treatment. This suggests that the VCS pre-treatment not only increases SCOD but also improves the digestibility of solid fractions. The energy mass balance indicated that the energy consumed for sludge pre-treatment could be recovered by the increased methane production after pre-treatment, suggesting the high potential for field application.

A Study on the Reaction Characteristics of Carbon Dioxide Methanation Catalyst for Full-Scale Process Application (이산화탄소 메탄화 공정 적용을 위한 Ni/CeO2-X 촉매의 반응 특성 연구)

  • Lee, Ye Hwan;Kim, Sung Su
    • Applied Chemistry for Engineering
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    • v.31 no.3
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    • pp.323-327
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    • 2020
  • The reaction characteristics of Ni/CeO2-X which is highly efficient at a low temperature was investigated for an application to carbon dioxide methanation process. The CeO2-X support was obtained by the heat treatment of Ce(NO3)3 at 400 ℃ and the catalyst was prepared by impregnation process. The operating parameters of the experiment were the internal pressure of the reactor, the composition of oxygen, methane, and hydrogen sulfide in the inlet gas and the reaction temperature. When Ni/CeO2-X was used for the carbon dioxide methanation reaction, the CO2 conversion rate increased by more than 25% as the pressure increased from 1 to 3 bar. The increase was large at a low reaction temperature. When both oxygen and methane were in the inlet gas, the CO2 conversion rate of the catalyst decreased by up to 16 and 4%, respectively. As the concentration of oxygen and methane increased, the reduction rate of the CO2 conversion rate tended to increase. In addition, the hydrogen sulfide in the inlet gas reduced the CO2 conversion rate by up to 7% and caused catalyst deactivation. The results of this study will be useful as basic data for the carbon dioxide methanation process.

Comparison of Dry Reforming of Butane in Catalyst Process and Catalyst+Plasma Process over Ni/γ-Al2O3 Catalyst (뷰테인 건식 개질 반응을 위한 Ni/γ-Al2O3 촉매를 이용한 촉매 공정과 촉매+플라즈마 공정 비교)

  • Jo, Jin-Oh;Jwa, Eunjin;Mok, Young-Sun
    • Journal of the Korean Institute of Gas
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    • v.22 no.1
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    • pp.26-36
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    • 2018
  • Conventional nickel-based catalyst processes used for dry reforming reactions have high activation temperatures and problems such as carbon deposition and metal sintering on the active sites of the catalyst surface. In this study, the characteristics of butane dry reforming reaction were investigated by using DBD plasma combined with catalytic process and compared with existing catalyst alone process. The physical and chemical properties of the catalysts were investigated using a surface area & pore size analyzer, XRD, SEM and TEM. Using $10%Ni/{\gamma}-Al_2O_3$ at $580^{\circ}C$, in the case of the catalyst+plasma process, the conversion of carbon dioxide and butane were improved by about 30% than catalyst alone process. When the catalyst+plasma process, the conversion of carbon dioxide and butane and the hydrogen production concentration are enhanced by the influence of various active species generated by the plasma. In addition, it was found that the particle size of the catalyst is decreased by the plasma in the reaction process, and the degree of dispersion of the catalyst is increased to improve the efficiency.

Studies on Beha vior of Cellulolytic and Methanogenic Bacteria Participated in Anaerobic Decomposition of Rice Straw and its Decomposition Products (볏짚의 혐기분해(嫌氣分解)에 관여(關與)하는 섬유소분해균(分解菌)과 메탄생성균상(生成菌相) 및 그 분해(分解) 생성물(生成物)에 관(關)한 연구(硏究))

  • Jung, Kwang-Yong;Joo, Yeong-Hee;Kim, Jai-Joung
    • Korean Journal of Soil Science and Fertilizer
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    • v.22 no.4
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    • pp.323-328
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    • 1989
  • This study was conducted to find out the behavior of anaerobic microorganisms and anaerobic decomposition products of rice straw in the strict anaerobic condition. The number of methanogenic bacteria were more isolated than cellulolytic bacteria from the digester decaying rice straw during the entire incubation time. The activity of anaerobic microorganisms, such as methanogens and cellulolytics, were high the early incubation time in the treatment of rice straw with urea, but without urea was low at that time and increased moderately after 10 days incubation. Volatile fatty acid as intermediate anaerobic decomposition products had a longer retention time and higher accumulation rate in the treatment of rice straw without urea than with urea, and predominant fatty acid was propionic acid. Gas generation rate as final products were very intimate relationship with the activity of methanogenic bacteria. Average Eh value was -250mV during the incubation time and $CH_4$ : $CO_2$ percent ratio was about 60~65 : 35~40 in this Eh value. Decomposition rate of rice straw calculated from $CH_4$ and $CO_2$ gas wars 45.6% for 50 days in the treatment of rice straw with urea, and 36.8% without urea.

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