• Title/Summary/Keyword: 비환원주의

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Antioxidant activities of brown beech mushroom (Hypsizygus marmoreus) pileus and stipe (갈색 느티만가닥버섯 추출물의 부위별 항산화 활성)

  • Park, Min Jeong;Yu, Chan Yeol;Cho, Soo Jeong
    • Journal of Mushroom
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    • v.19 no.4
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    • pp.322-328
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    • 2021
  • This study was carried out to evaluate potential of Hypsizygus marmoreus (brown cultivar) as a functional food and drug materials. H. marmoreus were divided into pileus and stipe and extracted in hot water and 80% ethanol. The total polyphenol content was highest in the hot water extracts (pileus 17.15±0.19 mg of GAE g, stipe 7.37±0.16 mg of GAE/g) and pileus compared to the ethanol extracts (pileus 10.23±0.14 mg of GAE/g, stipe 3.76.±0.19 mg of GAE/g) and stipe. Also, hot water extracts of pileus from H. marmoreus (brown cultivar) was more effective DPPH, ABTS, ORAC value, reducing power than ethanol extracts and stipe extracts. The pileus and stipe extracts were confirmed to be non-cytotoxic in the mouse macrophage cell line RAW 264.7 determined by WST-1 (4-[3-(4-iodophenyl)-2-(4-nitrophenyl)-2H-5-tetrazolio]-1,3-benzene disulphonate) assay. Overall, extracts of H. marmoreus (brown cultivar) was higher antioxidant activity than other mushrooms, and no cytotoxicity. Therefore, H. marmoreus (brown cultivar) showed potential as a functional food and drug materials. The brown cultivar of H. marmoreus have higher antioxidant activity than white cultivar, H. marmoreus seem to have different antioxidant activity depending on the cultivar.

손바닥 선인장 열매 추출물의 기능성

  • 김정옥;이기동;권중호
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 2003.10a
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    • pp.142.2-142
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    • 2003
  • 손바닥 선인장(Opuntia ficus indica)은 중심자목 선인장과에 속하는 다년생 초본으로 열매는 서양배 모양이며 많은 종자가 들어있고 다량의 점질물을 함유하고 있다. 손바닥 선인장 열매(prickly pear pulp)는 14.5%의 고형분 함량을 가지고 있으며, 0.21%의 단백질, 0.12%의 지방, 0.44%의 회분, 0.19%의 pectin 이외에 미량의 비타민 A와 C 그리고 여러 종류의 무기질을 포함하고 있다. 주요 당류로서 sucrose(68.7%), fructose(18.0%) 및 glucose(12.8%)를 함유하고 있으며, 점질다당류의 구성분인 mannose 가 0.5% 포함되어 있다. 손바닥 선인장 열매는 높은 혈중 콜레스테롤, 염증 및 비만 등의 치료에 유용한 것으로 알려져 있다. 본 연구에서는 손바닥 선인장 열매 추출물의 기능적 특성을 반응표면분석에 의해 모니터링 하였다. 그 결과 환원당 함량은 최대값이 33.39 mg%로 추출온도 69.87$^{\circ}C$, 추출시간 68.84 min및 시료에 대한 용매비 16.29 ml/g일 때였다. 총 플라보노이드 함량은 추출온도 89.7$0^{\circ}C$, 추출시간 170 min 및 시료에 대한 용매비 17.07 ml/g일 때 2,03 mg%로 최대값을 나타내었다. 펙틴 함량은 추출온도 96.54$^{\circ}C$, 추출시간 135.28 min및 시료에 대한 용매비 20.02 nWg일 때 최대값 82.04 mg%를 나타내었으며, 비타민 C 함량은 추출온도 61.8$0^{\circ}C$, 추출시간 101.98 min 및 시료에 대한 용매비 12.14 ml/g일 때 최대값이 3.76 mg%였다.

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Active Material Crossover through Sulfonated Poly (Ether Ether Ketone) Membrane in Iron-Chrome Redox Flow Battery (철-크롬 산화환원흐름전지에서 Sulfonated Poly (Ether Ether Ketone)막의 활물질 Crossover)

  • Kim, Young-Sook;Oh, So-Hyeong;Kim, You-Jeong;Kim, Seong-ji;Chu, Cheun-Ho;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.17-21
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    • 2019
  • The redox flow battery (RFB) is a large-capacity energy storage equipment, and the vanadium redox flow cell is a typical RFB, but VRFB is expensive. Iron-chrome RFBs are economical because they use low-cost active materials, but their low performance is an urgent problem. One of the reasons for the low performance is the crossover of the active materials. In this study, the sulfonated Poly (ether ether ketone) (sPEEK) membrane, which is a hydrocarbon membrane, was used instead of the fluorine membrane to reduce the crossover of the active materials. The chromium ion permeability of the sPEEK membrane was $1.8{\times}10^{-6}cm^2/min$, which was about 1/33 of that of the Nafion membrane. Thus, it was shown that the use of the sPEEK membrane instead of the fluorine membrane could solve the high active material crossover problem. The activation energy of iron diffusion through the sPEEK membrane was 24.9 kJ/mol, which was about 66% of Nafion membrane. And that the e-PTFE support in the polymer membrane reduces the active material crossover through Iron-Chrome Redox Flow Battery (ICRFB).

The Effect of Fumed Silica on Nitrate Reduction by Zero-valent Iron (흄드 실리카가 영가철에 의한 질산성질소 환원에 미치는 영향)

  • Cho, Dong-Wan;Jeon, Byong-Hun;Kim, Yong-Je;Song, Ho-Cheol
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.6
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    • pp.599-608
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    • 2010
  • The effect of silica(fumed) on nitrate reduction by zero-valent iron(ZVI) was studied using batch experiment. The reduction of nitrate was tested in three different aqueous media including de-ionized water, artificial groundwater and real groundwater contaminated by nitrate. Kinetics of nitrate reduction in groundwater were faster than those in de-ionized water, and first-order rate constant($k_{obs}$) of ZVI/silica(fumed) process was about 2.5 time greater than that of ZVI process in groundwater. Amendment of Silica(fumed) also decreased ammonium presumably through adsorption on silica surface. The pHs in all processes increased due to oxidation of ZVI, but the increase was lower in groundwater due to buffering capacity of groundwater. The result also showed amount of reduced nitrate increased as initial nitrate concentration increased in groundwater. Separate adsorption isotherm experiments indicated that fumed silica itself had some degree of adsorption capacity for ammonium. The overall results indicated that silica(fumed) might be a promising material for enhancing nitrate reduction by ZVI.

Effect of Mixed Cultivation of Green Manure Crops on Mineral Nutrients, Microbial Activities, Weed Occurrences and Yields of Red-pepper (토양 무기양분, 미생물활성, 잡초발생 및 고추수량에 대한 녹비작물 혼파효과)

  • Sung, Jwa-Kyung;Lee, Sang-Min;Lee, Yong-Hwan;Lee, Youn;Lee, Ju-Young;Jang, Byong-Choon
    • Proceedings of the Korean Society of Organic Agriculture Conference
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    • 2009.12a
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    • pp.301-301
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    • 2009
  • 겨울철 농경지 이용율 제고 및 자연경관 조성을 위하여 녹비작물을 재배하는 면적이 지속적으로 증가하고 있는 추세이다. 그 동안 녹비작물에 대한 연구는 주로 파종적기, 작물에 대한 양분공급효과 및 타감 효과 등에 집중되어왔다. 본 연구에서는 토양 중 양분공급 및 미생물활성의 경시적 변화, 잡초억제 및 작물생육에 대한 녹비작물의 투입효과를 알아보기 위하여 수행하였다. 국립농업과학원 구내포장에서 2007년 9월 하순에 헤어리베치(8kg/10a)와 호밀(10kg/10a) 종자를 파종한 후, 이듬해 4월 하순에 수확하여 토양에 환원하였다. 질소공급량은 화학비료(15.2kgN/10a) 대비 헤어리베치(32.2kg/10a, 212%), 호밀(9.2kg/10a, 60%) 및 헤어리베치+호밀(15.5kg/10a, 102%)로 헤어리베치의 질소공급효과가 매우 높았다. 토양 무기태질소 함량은 녹비 처리 후 30일경에 최대에 도달하였으나, 호밀 처리구는 조사기간 동안 큰 변화가 없었다. 토양 유기물 함량의 변화는 시험 전(10DBI)과 비교하여 큰 차이를 보이지 않았으나, 녹비환원 후 10일경에 일시적으로 감소하는 경향을 보였는데 이는 녹비환원 후 토양경운에 의한 영향으로 판단되며, 무기태질소와는 달리 호밀처리구의 유기물함량이 지속적으로 증가하는 경향을 보였다. 토양 탄수화물(수용성 당)은 시험 전에 가장 높았으며, 시간의 경과와 함께 서서히 감소되는 양상을 보였으며 토양 미생물탄소 및 미생물질소의 양은 녹비처리구가 화학비료 처리구에 비해 높았으며 녹비환원 후 50일 까지는 증가하다가 그 이후에 감소하는 경향을 보였는데 이는 토양의 무기태질소 및 탄수화물과 밀접한 관계가 있는 것으로 판단되었다. 녹비처리 후 85일경에 잡초발생량을 조사한 결과, 화학비료 처리구에 비하여 헤어리베치 처리구는 40%, 호밀 처리구는 68%, 헤어리베치+호밀 처리구는 40%의 잡초억제효과가 있었다. 고추과의 수량은 화학비료 처리구(702kg/10a)>헤어리베치(694kg>10a)>헤어리베치+호밀(361kg/10a)>호밀(179kg/10a)의 순으로 나타났다.

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Removal of TNT Reduction Products via Oxidative-Coupling Reaction Using Manganese Oxide (망간산화물을 이용한 TNT 환원부산물의 산화-결합반응에 의한 제거 연구)

  • Kang, Ki-Hoon;Lim, Dong-Min;Shin, Hyun-Sang
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.5
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    • pp.476-485
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    • 2005
  • In this study, abiotic transformation of TNT reduction products via oxidative-coupling reaction was investigated using Mn oxide. In batch experiments, all the reduction products tested were completely transformed by birnessite, one of natural Mn oxides present in soil. Oxidative-coupling was the major transformation pathway, as confirmed by mass spectrometric analysis. Using observed pseudo-first-order rate constants with respect to birnessite loadings, surface area-normalized specific rate constants, $k_{surf}$, were determined. As expected, $k_{surf}$ of diaminonitrotoluenes (DATs) ($1.49{\sim}1.91\;L/m^2{\cdot}day$) are greater about 2 orders than that of dinitroaminotoluenes (DNTs) ($1.15{\times}10^{-2}{\sim}2.09{\times}10^{-2}\;L/m^2{\cdot}day$) due to the increased number of amine group. In addition, by comparing the value of $k_{surf}$ between DNTs or DATs, amino group on ortho position is likely to be more preferred for the oxidation by birnessite. Although cross-coupling of TNT in the presence of various mediator compounds was found not to be feasible, transformation of TNT by reduction using $Fe^0$ followed by oxidative coupling using Mn oxide was efficient, as evaluated by UV-visible spectrometry.

Production of Fermented Honey Wine (벌꿀발효주의 제조)

  • Rhim, Jong-Whan;Kim, Dong-Han;Jung, Soon-Teck
    • Korean Journal of Food Science and Technology
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    • v.29 no.2
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    • pp.337-342
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    • 1997
  • In order to compare methods of making a mead and a melomel, changes of alcohol contents, reducing sugar, soluble solids, pH and total acidity during fermentation of a mead and Japanese plum melomel was investigated. Fermentation rate of the melomel were much faster than the mead. Reducing sugar and soluble solids were continuously decreased until the 16th day of fermentation, while alcohol contents were increased continuously during the same period. After fermentation of 21 days, alcohol contents of the mead was reached 7.6%, while that of the Japanese plum melomel reached 12.4%. pH and total acidity were not changed considerably during the whole fermentation period. Clear honey wines with transmittance of 99.4% were obtained by membrane filtration. In conclusion, the method of making melomel using the osmotically extracted fruit juice with honey was found to be more advantageous than the method of making a simple mead.

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Treatment of Acid Mine Drainage Using Immobilized Beads Carrying Sulfate Reducing Bacteria (황산염환원균 고정화 담체를 이용한 산성광산배수 처리)

  • Kim, Gyoung-Man;Hur, Won;Baek, Hwan-Jo
    • Economic and Environmental Geology
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    • v.41 no.1
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    • pp.57-62
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    • 2008
  • The application of constructed subsurface-flow wetlands for treatment of wastewater from abandoned mines is being increased. Crushed limestone, oak chips, and mushroom composites are often employed in a bulk form, as the substrates in the bed media. Efficiency of the subsurface-flow treatment system drops with time as the hydraulic conductivity of the wetland soil decreases significantly, presumably due to chemical reactions with the wastewater. The purpose of this study is to investigate the applicability of immobilized beads carrying sulfate reducing bacteria for acid mine drainage treatment system. The ingredients of immobilized beads are organic materials such as mushroom composite and oak chips, limestone powder for a pH buffer, mixed with a modified Coleville Synthetic Brine. It was found that immobilized beads are more efficient than the bulk form for pH recovery, sulfate and heavy metal removal.

Computational Study on Design of the AIG for the Enhancement of Ammonia Injection in the SCR System (SCR 시스템 내 암모니아 분사 균일도 개선을 위한 AIG 설계에 관한 해석적 연구)

  • Seo, Moon-Hyeok;Chang, Hyuksang
    • Clean Technology
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    • v.18 no.4
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    • pp.410-418
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    • 2012
  • The performance of the ammonia injection gun (AIG) used for maximizing the utilization of reducing agent in the selective catalytic reduction (SCR) system is decided by several parameters such as the pattern of flow distribution, geometry of the air distribution manifold (ADM) and the array and geometry of nozzles. In the study, the uniformity of jet flows from the nozzles in AIG was analyzed statistically by using the computational fluid dynamics (CFD) method to evaluate the role of design parameters on the performance of the SCR system. The uniformity of jet flows from the nozzles is being deteriorated with increasing the supplying flow rate to the AIG. Distribution rates to each branch pipe become lower with decreasing distance to the header, and flow rates from nozzle are also reduced with decreasing distance to the header. The uniformity of jet flows from nozzles becomes stable significantly when the ratio of summative area of nozzles to each sectional area of the branch pipe is below 0.5.

A CFD Study on Aerodynamic Performances by Geometrical Configuration of Guide Vanes in a Denitrification Facility (탈질 설비 내 안내 깃의 기하학적 형상에 따른 공력 성능에 대한 전산 해석적 연구)

  • Chang-Sik, Lee;Min-Kyu, Kim;Byung-Hee, Ahn;Hee-Taeg, Chung
    • Clean Technology
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    • v.28 no.4
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    • pp.316-322
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    • 2022
  • The flow pattern at the inlet of the catalyst layer in a selective catalytic reduction (SCR) system is one of the key parameters influencing the performance of the denitrification process. In the curved diffusing parts between the ammonia injection grids and the catalyst layers, guide vanes are installed to improve flow uniformity. In the present study, a numerical simulation has been performed to investigate the effect of the geometrical configuration of the guide vanes on the aerodynamic characteristics of a denitrification facility. This application has been made to the existing SCR process in a large-scaled coal-fired power plant. The flow domain to be solved covers the whole region of the flow passages from the exit of the ammonia injection gun to the exit of the catalyst layers. ANSYS-Fluent was used to calculate the three-dimensional steady viscous flow fields with the proper turbulence model fitted to the flow characteristics. The root mean square of velocity and the pressure drop inside the flow passages were chosen as the key performance parameters. Four types of guides vanes were proposed to improve the flow quality compared to the current configuration. The numerical results showed that the type 4 configuration was the most effective at improving the aerodynamic performance in terms of flow uniformity and pressure loss.