• Title/Summary/Keyword: 비평형 효과

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Effects of the Non-equilibrium Heat-treatment on Modification of Microstructures of Al-Si-Cu Cast Alloy (비평형 열처리에 의한 주조용 Al-Si-Cu합금 조직의 개량 효과)

  • Kim, Heon-Joo
    • Journal of the Korean Society for Heat Treatment
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    • v.13 no.6
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    • pp.391-397
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    • 2000
  • Addition of Ca element and nonequilibrium heat treatment which promotes shape modification of eutectic Si and ${\beta}$ intermetallic compound were conducted to improve the mechanical properties of Al-Si-Cu alloy. Modification of eutectic Si and dissolution of needle-shape ${\beta}$ intermetallic compounds were possible by nonequilibrium heat treatment in which specimens were held at $505^{\circ}C$ for 2 hours in Al-Si-Cu alloy with Fe. Owing to the decrease in aspect ratio of eutectic Si by the heat treatment of the alloy with 0.33wt.% Fe, the increase in elongation was prominent to be more than double that in the as-cast specimen. Dissolution of needle-shape ${\beta}$ intermetallic compounds in the alloy with 0.85wt.% Fe led to the improvement of tensile strength as the length of ${\beta}$ compounds decreased to 50%.

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NUMERICAL SIMULATION OF THERMOCHEMICAL NON-EQUILIBRIUM FLOW AROUND BLUNT BODIES CONSIDERING CATALYTIC WALL EFFECTS (촉매벽 효과를 고려한 무딘 물체 주위의 열화학적 비평형 유동에 대한 수치적 연구)

  • Kim, J.W.;Kwon, O.J.
    • Journal of computational fluids engineering
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    • v.18 no.3
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    • pp.87-93
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    • 2013
  • A computational study has been performed to examine the effects of catalytic walls on the stagnation region heat transfer. The boundary conditions for none, finite, and fully catalytic walls have been incorporated into a multi-block compressible Navier-Stokes solver. In the present study, both chemical and thermal non-equilibrium effects were included. The flows over a blunt body model were simulated by varying surface catalytic recombination rates. A full range of catalycities was explored in the context of a constant wall temperature assumption. Detailed information on species concentrations, temperature, and surface heat flux are presented. Comparison with available flight data of surface heat flux is also made.

Fully coulpled CMC modeling for three-dimensional turbulent nonpremixed syngas flame (CMC 모델을 이용한 난류 비예혼합 Syngas 화염장 해석)

  • Kim, Gun-Hong;Lee, Jung-Won;Kim, Yong-Mo;Ahn, Kook-Young
    • 한국연소학회:학술대회논문집
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    • 2006.04a
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    • pp.111-120
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    • 2006
  • The fully coupled conditional moment closure(CMC) model has been developed to realistically simulate the structure of complex turbulent nonpremixed syngas flame, in which the flame structure could be considerablyl influenced by the turbulence, transport history, and heat transfer as well. In order to correctly account for the transport effect, the CMC transport equations fully coupled with the flow and mixing fields are numerically solved. The present CMC approach has successfully demonstrated the capability to realistically predict the detailed structure and the overall combustion characteristics. The numerical results obtained in this study clearly reveal the importance of the convective and radiative heat transfer in the precise structure and NOx emission of the present confined combustor with a cooling wall.

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The efficiency of subtraction technique in a nonequilibrium molecular dynamics simulation of a simple liquid shear flow (단순액체의 층밀리기 흐름에 대한 비평형 분자동력학 계산에서 공제방법의 효과)

  • 안성청
    • Journal of the Korea Society for Simulation
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    • v.6 no.1
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    • pp.53-60
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    • 1997
  • Results from a nonequilibrium molecular dynamics (NEMD) simulation are presented for an argon liquid subject to a shear flow. The segmented molecular dynamics method and the subtraction technique used in NEMD program to reduce the thermal fluctuation noise in data are studied with different shear rates. The standard deviation in the shear stress reduced from 0.030 to 0.004 by the segmented molecular dynamics method for 50 repeated segments. On the other hand, the standard deviation of the data remained the same when the subtraction technique was applied, where as the results of shear stress by constant value in a random way.

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Properties of Al Films Deposited on Steel Sheets with Magnetron Sputtering and Oblique Angle Deposition (스퍼터링과 빗각증착으로 코팅된 알루미늄 코팅층의 특성)

  • Yang, Ji-Hun;Jeong, Jae-Hun;Song, Min-A;Park, Hye-Seon;Jeong, Jae-In
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.265-265
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    • 2012
  • 스퍼터링을 이용하여 금속을 코팅하면 대부분 주상정 형태의 미세구조로 성장한다. 금속 코팅층의 미세구조를 코팅공정으로 제어하여 치밀한 구조의 코팅층을 합성하기 위해서 평형(balanced magnetron)과 비평형(unbalanced magnetron) 스퍼터링에 의한 박막 구조 변화를 비교하고, 빗각 증착(oblique angle deposition) 효과가 코팅층의 미세구조에 미치는 영향을 확인하였다. 실험에 사용된 타겟은 6 인치 직경의 알루미늄이었으며 기판은 실리콘 웨이퍼와 냉연강판이 사용되었다. 알루미늄 코팅층은 주사전자현미경으로 미세구조를 관찰하였으며, 미세구조 변화가 내부식 특성에 미치는 영향을 평가하기 위해서 알루미늄이 코팅된 냉연강판의 염수분무 시험을 실시하였다. 빗각 증착에 의한 코팅층 미세구조 변화가 가장 두드러지게 나타났으며, 빗각 증착에 의해서 알루미늄 코팅층이 치밀해지는 현상을 관찰할 수 있었다. 알루미늄이 코팅된 냉연강판을 분석한 결과, 빗각 증착으로 코팅된 알루미늄 코팅층이 두께 약 $3{\mu}m$에서 염수분무 200 시간 후에도 적청이 발생하지 않는 우수한 내식성을 보였다.

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Chemical Equilbrium Analysis of the $30\;ton_f$ - class KARI LRE Nozzle Flow (KARI 30톤급 액체 로켓 엔진 노즐 유동 화학 평형 해석)

  • Lee, Dae-Sung;Kang, Ki-Ha;Cho, D.R.;Choi, Jeong-Yeol;Choi, H.S.
    • Journal of the Korean Society of Propulsion Engineers
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    • v.12 no.3
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    • pp.9-15
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    • 2008
  • Nozzle flow analyses of $30\;ton_f$-class KARI liquid rocket engine for high altitude propulsion are carried out using a chemically frozen and equilibrium flow analysis code developed previously. It is considered that the combined frozen- and shifting- equilibrium analysis is cost-effective regarding the convergence characteristics and modeling uncertainties, though the non-equilibrium analysis is most reliable approach. A dependable performance prediction could be attainable through the present analyses that account for the recombination process and thermal and kinetic energy recovery during the expansion process with viscous effects.

Kinetics of Catalytic Reactions Occurring in a Small Reaction Volume (작은 반응 매질에서 일어나는 촉매 반응 속도에 관한 연구)

  • Kim, Jung-Han;Sung, Jae-Young
    • Journal of the Korean Chemical Society
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    • v.52 no.3
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    • pp.217-222
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    • 2008
  • We investigate the kinetics of diffusion-influenced catalytic reactions occurring in small reaction volume. From a simple exact model study, we find that the reaction rate coefficient decreases with the size of reaction volume. The explicit expression for the average reaction rate constant is presented, which can be regarded as a generalization of well-known Collins-Kimball rate constant into the reactions occurring in a small reaction volume. It turns out that the traditional diffusion influenced reaction dynamics is followed by a single exponential relaxation phase with a rate constant dependent on the reaction volume for the catalytic reactions occurring in small reaction volumes.

스퍼터링을 이용한 ITO 박막의 저온 증착

  • Jang, Seung-Hyeon;Lee, Yeong-Min;Yang, Ji-Hun;Jeong, Jae-In
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.263-263
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    • 2010
  • 투명도전막(indium tin oxide; ITO)은 투명하면서도 전기 전도도가 높기 때문에, 액정표시소자(LCD; Liquid Crystal Display), 전자발광소자(ELD; Electroluminescent Display) 및 전자 크로믹 소자(Electrochromic Display)를 포함하는 평판형 표시 소자(FPD; Flat Panel Display)와 태양전지 등에 이용되고 있다. 낮은 비저항과 높은 투과율의 ITO 박막은 $300^{\circ}C$ 이상의 고온에서 코팅해야 하는 것으로 알려져 있다. 그러나 최근 플라스틱과 같은 연성 소자가 전자부품에 널리 이용되면서 ITO를 저온에서 증착해야할 필요성이 대두되고 있다. 본 연구에서는 ITO를 플라스틱에 적용하기 위한 저온 코팅 공정 및 시편의 전 후처리공정을 개발하여 박막의 특성을 알아보고자 한다. 실험에 사용된 기판은 고투과율의 고분자(polyethylene terephthalate; PET) 필름이며 $5\;{\times}\;10\;cm^2$의 크기로 절단하여 알코올로 초음파 세척을 실시하였고, 진공 용기에 장입한 후 펄스전원을 이용하여 3분간 in-situ 청정을 실시하였다. ITO 코팅은 마그네트론 스퍼터링을 이용하였으며, 코팅시간, 전처리, 후처리, 기판온도, 산소유량 등 코팅 조건에 따른 박막의 특성을 조사하였다. ITO 박막의 코팅 조건에 따른 박막의 결정구조 분석은 x-선 회절(x-ray diffraction; XRD)을 이용하였고, 박막의 표면형상과 두께 보정 및 단면의 미세조직과 결정 성장 여부 등은 투과전자 현미경(transmission electron microscope; TEM)을 이용하여 분석하였다. 또한 ITO 박막의 면저항과 분광특성은 four-point Probe (CMP-100MP, Advanced Instrument Technology), spectrophotometer (UV-1601, SHIMADZU)를 이용하여 측정하였다. ITO 박막의 광학특성 분석 결과 전광선 투과율은 두께에 따라 변화 하였지만, 색차와 Haze 값은 증착 조건에 따라 큰 차이는 보이지 않았다. 그리고 박막의 결정화에 영향을 주는 가장 중요한 인자는 기판온도이지만, 기판온도를 높이지 못할 경우 비평형 마그네트론(unbalanced-magnetron; UBM)에 의해서 플라즈마 밀도를 높이는 방법으로 유사한 효과를 얻을 수 있음을 확인하였다.

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A Nonlinear Low-Reynolds-Number k -$\varepsilon$ Model for Turbulent Separated and Reattaching Flows (난류박리 및 재부착 유동의 해석을 위한 비선형 저레이놀즈수 k -$\varepsilon$ 난류모형의 개발)

  • 박태선;성형진
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.8
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    • pp.2051-2063
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    • 1995
  • An improved version of nonlinear low-Reynolds-number k-.epsilon. model is developed. In this model, the limiting near-wall behavior and nonlinear Reynolds stress representations are incorporated. Emphasis is placed on the adoption of Ry(.iden. $k^{1}$2/y/.nu.) instead of $y^{[-10]}$ (.iden. $u_{{\tau}/y/{\nu}}$) in the low-Reynolds-number model for predicting turbulent separated and reattaching flows. The non-equilibrium effect is examined to describe recirculating flows away from the wall. The present model is validated by doing the benchmark problem of turbulent flow behind a backward-facing step. The predictions of the present model are cross-checked with the existing measurements and DNS data. The model performance is shown to be generally satisfactory.

A Low-Reynolds-Number 4-Equation Model for Turbulent Separated and Reattaching Flows (난류박리 및 재부착 유동의 해석을 위한 저레이놀즈수 4-방정식 난류모형의 개발)

  • 이광훈;성형진
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.8
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    • pp.2039-2050
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    • 1995
  • The nonlinear low-Reynolds-number k..epsilon. model of park and Sung is extended to predict the turbulent heat transports in separated and reattaching flows. The equations of the temperature variance( $k_{\theta}$ and its dissipation rate(.epsilon.$_{\theta}$ are solved, in concert with the equations of the turbulent kinetic energy(k) and its dissiation rate(.epsilon). In the present model, the near-wall effect and the non-equilibrium effect are fully taken into consideration. The validation of the model is then applied to the turbulent flow behind a backward-facing step and the flow over a blunt body. The predicted results of the present model are compared and evaluated with the relevant experiments.