• Transactions of the Korean Society of Mechanical Engineers
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• v.16 no.10
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• pp.1990-1997
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• 1992

The characteristic of supersonic flow with condensation along a wavy wall of small amplitude in channel is investigated through the direct marching method of characteristics. The very complex problem that may appear where the overlapping of the same family characteristics occurs, can be satisfactorily solved by means of the modified method suggested by Zucrow. In the present study for the case of supersonic moist air flow, the dependency of location of formation and reflection of oblique shock wave generated by the wavy wall, and the distributions of flow properties, on the relative humidity and temperature at the entrance of wavy wall is clarified by plots of streamline, ios-Mach umber and ios-flow properties. Also, it is confirmed that the wavy wall plays an important key role in the formation of oblique shock wave, and that the effect of condensation on the flow field appears apparently.

• Journal of the Mineralogical Society of Korea
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• v.8 no.1
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• pp.1-12
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• 1995

옥천 변성대 남서부 지역에서 산출되는 변성 니질암에서는 muscovite, biotite 및 chlorite를 주로하는 phyllosilicate가 서로 intergrowth 또는 interlayer를 이루는 것이 편광현미경 관찰, EPMA 분석, Back Scattered Electron (BSE) image 관찰 및 Transmission Electron Micro-scope(TEM) 관찰을 통하여 확인되었다. 이들 광물들은 편광현미경 관찰에서 흔히 각각의 입자를 식별할 수 없을 정도의 미세 규모로 서로 intergrow 되어 있으며BSE image에서는 0.1$\mu\textrm{m}$ 이하의 아주 작은 크기에서부터 10.0$\mu\textrm{m}$ 정도 크기까지 다양한 규모의 intergrow를 형성하고 있음이 관찰되었다. TEM scale에서는 개별 layer 크기(약 10$\AA$)에서부터 수십 개 layer 크기의 interlayering을 보여준다. 이와 같은 intergrowth 또는 interlayering의 결과로 EPMA 분석에서 종종 보기에는 규진(homogeneous)한 입자라 하더라도 두 개 이상의 광물 성분이 섞여 있는 분석값을 나타내며 이러한 nonstoichiometry는 BSE image에서 interlayer(또는 intergrow) 된 것으로 관찰되는 부분에서 더욱 두드러진다.Chlorite zone에서는 chlorite와 muscovite의 interlayering (C/M)이 주로 발견되며 biotite zone과 garnet zone에서는 chlorite와 biotite의 interlayer (C/B)가 주로 관찰된다. 이는 chlorite zone에서는 속성작용에서 보편적으로 나타나는 C/M으로부터 chlorite가 분리되는 광물반응이 일어나는데 반해서 biotite zone과 garnet zone에서는 chlorite로부터 C/B를 거쳐 biotite를 생성하는 광물반응이 일어나는 것을 의미한다. 이와 같은 현상은 변성작용에서 phollosilicate의 광물반응의 엄밀한 의미에서는 평형(equilibrium) 상태에서 균질한 광물을 생성하기보다는 비평형(disequilibrium) 반응으로 일어난다는 것을 의미한다.

• Proceedings of The Korean Society of Agricultural and Forest Meteorology Conference
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• 2013.11a
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• pp.26-27
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• 2013

산림생태계의 에너지, 물질, 정보의 교환 과정과 그 변화를 이해하려면 먼저 생태계의 구조와 기능이 어떻게 상호작용하는지를 이해해야 한다. 생태계의 기능은 한, 두 가지의 특징에 의해서만 이루어지는 것이 아니다. 그렇기 때문에 그 기능을 파악하고 적절히 이용하거나 대응하기 위해서는 한 생태계와 주변 환경 전체를 바라볼 수 있는 시스템 사고가 필요하다. 이에 우리는 생태계의 '구조'를 파악함으로써 생태계의 '상태'를 이해하고자 한다. 본 연구에서는 Ruddell and Kumar (2009)의 접근법을 따라, 어떻게 한 생태계의 상태를 파악할 수 있는가라는 질문을 광릉활엽수림에 적용하여 답하고자 한다. 즉, 우리는 산림생태계가 열린 복잡계라고 가정하고, 생태계 내에서 다양한 프로세스들 간의 시시각각 변하는 네트워크의 구조가 각 시점의 시스템의 상태를 나타내는 지표가 될 수 있다고 가정하였다. 이 연구에서는 그 구조적 특징을 정량화하여 나타내는데 초점을 맞추었다. 각각의 프로세스를 대표하는 상태 변수들 간의 정보 흐름의 양과 방향, 시간 규모를 계산해냄으로써 네트워크 구조를 파악하고자 하였다. 온대 산악지형 활엽수림인 GDK의 2008년 순생태계교환량(NEE), 총일차생산량(GPP), 생태계호흡량(RE), 현열플럭스(H), 잠열플럭스(LE), 하향단파복사(Rg), 강수량(Precipitation), 기압(Pressure), 기온(T), 포차(VPD)의 시계열 자료를 월별로 나누어 최장 18 시간 규모의 정보 흐름을 계산하였다. 정보 흐름의 구조를 파악하기 위하여 변수들 간의 전이엔트로피(Transfer entropy)와 상호정보(Mutual Information)를 계산하는 방법을 사용하였다. 또한 시계열 자료를 이용함으로써 변수들 간에 정보가 전달되는 시간 규모의 특성을 파악할 수 있었다. 최종적으로, 계산한 정보 흐름을 시각화하여 프로세스 네트워크 구조를 나타내었다. 결과는 월별로 생태계의 정보 흐름의 종류, 방향과 시간 규모, 그에 따른 프로세스 간 상호 작용의 특징 등을 보여준다. 이를 통해 계절적 환경 변화에 따라 시스템의 네트워크 구조와 상태가 어떻게 변화하는지 이해할 수 있을 것이다. 이 연구는 추후 우리 연구실에서 생산한 8 년 자료에 적용함으로써 다양한 날씨 및 기후변화와 환경 변화에 따라 생태계의 구조와 상태가 어떻게 변화하는지 연구하는 시작점이 될 것이다. 이 접근법은 단위나 차원에 무관하게 다양한 종류의 자료에 적용할 수 있는 반면에, 일관성 있게 정의된 시스템의 상태 및 그 상태를 구성하는 주요 하부 시스템들의 네트워크 상태를 이해하는데 이용될 수 있다. 본 연구는 비평형 열역학과 복잡계의 관점에서 바라 본 시스템 사고를 적용하려 하는 여러 연구 분야에 새로운 도전을 촉발할 좋은 선행연구가 될 것이라 기대된다.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.3
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• pp.162-166
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• 2011

Phosphorous contaminated in the effluent from sewage treatment plants can cause the eutrophication in surface water bodies. In this study, a powder of titanium oxysulfate-sulfuric acid made of ion-exchange materials was immobilized in an alginate gel and this material was examined to evaluate its phosphorous removal efficiency. Equilibrium and kinetic studies were carried out to quantify the adsorption capacity and time dependent removal rate of phosphorous. Adsorption isotherms and kinetic parameters were obtained for the entrapped titanium beads with three different methods. Equilibrium data were analyzed using Langmuir adsorption isotherm model and found to be well fitted to the model. The maximum adsorption capacity for phosphorous by the titanium bead synthesized with the solution method was 92.26 mg/g. Kinetic data followed a pseudo-second-order kinetic model. Due to the low production cost and high adsorption capacity, the titanium bead synthesized by the solution method has a potential to be utilized for the cost-effective removal of phosphorous from wastewater.

• Composites Research
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• v.30 no.6
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• pp.371-378
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• 2017

In this study, hygroelastic behavior of thermosetting epoxy is predicted by molecular dynamics simulations. Since consistent exposures to humid environments lead to macroscopic degradation of polymer composite, computational simulation study of the hygroscopically aged epoxy cell is essential for long-time durability. Therefore, we modeled amorphous epoxy molecular unit cell structures at a crosslinking ratio of 30, 90% and with the moisture weight fraction of 0, 4 wt% respectively. Diglycidyl ether of bisphenol F (EPON862) and triethylenetetramine (TETA) are chosen as resin and curing agent respectively. Incorporating equilibrium and non-equilibrium ensemble simulation with a classical interatomic potential, various hygroelastic properties including diffusion coefficient of water, coefficient of moisture expansion (CME), stress-strain curve and elastic modulus are predicted. To establish the structural property relationship of pure epoxy, free volume and internal non-bond potential energy of epoxy are examined.

• Resources Recycling
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• v.30 no.1
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• pp.14-25
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• 2021

As a demand of high-end steel raises, the importance of secondary refinement process also increases. However, the content of each component in molten steel, slag and inclusions change with the time, meaning the secondary refinement process is not an equilibrium state. Furthermore, many reactions occur between molten steel, slag, inclusion, refractory and alloying element during secondary refinement process. In order to consider the above complex reactions with non-equilibrium state, a few researchers developed kinetic models in secondary refinement process based on the experimental numerical equations. It is important to analyze and review to the previously reported models to develop a precise model. Therefore, in present study, the complex reaction models based on kinetic in secondary refinement process were analyzed, reviewed, and introduced. Moreover, the single reaction models also introduced which would be applied to the complex reaction models.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2014.11a
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• pp.188-189
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• 2014

코스트 저감과 연비 향상을 위한 부품 중 반복 하중과 내열성 부품의 적용이 증대하고 있다. 기존의 자동차 부품에서는 펄라이트가 석출되기 때문에 고탄소 철계 부품에 팩크로마이징 공정을 이용한 크롬탄화물을 형성하면서 탄화수소계 가스를 투입하므로서 기존의 불활성 분위기를 깨고 비평형상태로 분위기를 유지함으로 높은 경도의 $(Cr,Fe)_{23}C_6$와 $(Cr,Fe)_7C_3$ 복합 탄화물의 형성과 이에 의한 마찰계수 변화를 관찰하였다.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.10
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• pp.1090-1098
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• 2005

Benzoyl peroxide is very toxic to aquatic organisms but environmental concentration or exposure effects were not studied. Distribution of the chemical among multimedia environment was estimated using EQC(Equilibrium Criterion) model based on the physical-chemical properties to evaluate the risk of benzoyl peroxide in environment. Level I describes a situation that 100,000 kg of benzoyl peroxide is emitted into the environment which is equilibrium and steady-state without degradation and advection condition. Level II describes a situation that a constant rate of 1,000kg/h of benzoyl peroxide is continuously discharged into the environment which is equilibrium and steady-state with degradation and advection condition. Level III describes a situation that 1,000 kg/h of benzoyl peroxide is continuously introduced in each air, water, soil, and sediment compartment which are non-equilibrium and steady-state with degradation, advection, and inter-media transfer condition. In Level I and II calculations the chemical was distributed to soil(68.3%) and water(28.7%). In Level III calculation it was primarily distributed to soil(99.9%) and overall residence time was estimated to be 3.4 years. Benzoyl peroxide can be persistent in environment.

• Korean Journal of Soil Science and Fertilizer
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• v.39 no.1
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• pp.21-28
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• 2006

We investigated the mobilization of Cd, Pb, and Cr in two different soils in response to sorption capacities and competition for available sorption site while they moved under saturated water conditions. Two soil samples that were clay and sandy clay loam were collected within 20 cm from the upland surface. To do this, we used three different systems of heavy metal combinations such as single, binary, and ternary as solution phase. And then we observed the breakthrough curve (BTC) and elution as a function of pore volume by applying heavy metal solution and displacing K solution until these curves reached to maximum and minimum. The results showed that BTC and elution curves were not symmetric and it required more pore volumes with increasing species of heavy metals in solution phase, as well as longer tailings. Compared the areas over and under BTC and elution curve, relatively small amount of heavy metal was displaced by K even though there were differences in electronegativity among heavy metals. Conclusively, we assumed that heavy metals transport in soil could be influenced by soil physical nonequilibrium and chemical equilibrium in solution as far as there were more than two species of heavy metals existed.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.36 no.11
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• pp.1056-1062
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• 2008

The interaction between thrust plume and satellite base region was investigated by using direct simulate Monte-Carlo calculations. For the accurate simulation of N2 and H2 collisions and rotation-translation transition, a variable soft-sphere model and a recent rotational relaxation model of N2 and H2 were used. For the investigation of the interaction between thrust plume and base region, the number density distribution for each species, translational and rotational temperature distributions, heat flux, and pressure were examined by direct simulation of Monte-Carlo calculations. It was found that most of the surface properties are affected by H2 collisions and a strong non-equilibrium state is observed at the base region. It was demonstrated that an accurate model is needed to simulate H2 collisions and the rotation-translation transition. The results by the present calculation are more accurate than previous direct simulation Monte-Carlo calculations because more accurate rotational relaxation models were used in simulating the inelastic collisions.