• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2006.11a
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• pp.150-153
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• 2006

Gas generator should be adopted either fuel rich or oxidizer rich combustion because of the temperature restriction to avoid any possible thermal damages to turbine blade. This study focuses to model the non-equilibrium chemical reaction of kerosene/LOx with detailed kinetics developed by Dagaut using Perfectly stirred reactor(PSR) assumption. To predict more reliable species fraction and other gas properties, Frenklach's soot model was added to Dagaut's detailed kinetics.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.162-167
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• 2003

최근 수년간 유선 시뮬레이션은 연산 속도의 효율성과 수치 분산으로 인한 오차를 감소시킬 수 있는 장점으로 인해 많은 연구가 이루어졌으며 오염물의 거동을 모사 하는데 많이 사용되고 있다. 이 연구에서는 유선 시뮬레이션의 기법을 이용하여 1차의 비평형 흡착을 고려한 오염물 거동 수치 모사를 수행하였다. 1차의 비평형 흡착의 경우 흡착 계수에 따라 오염물의 이동 속도가 민감하게 반응하는 것을 확인할 수 있었고 흡착 계수의 값이 커질수록 오염의 전파 지연 효과가 크게 나타남을 알 수 있었다. 1차의 비평형 흡착의 경우에 평형 흡착과는 달리 오염이 진행되면서 오염물의 농도를 감소시키는 영향을 나타내었으며 이로 인하여 오염물이 더 이상 진행하지 못하는 제로라인을 형성하게 하였다. 이 제로라인은 흡착 계수의 값이 클수록 탈착 계수의 값이 작을수록 오염원에 가깝게 형성되었다.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.34 no.7
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• pp.89-96
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• 2006

The combustion temperature in gas generator should be kept below around 1,000K to avoid any possible thermal damages to turbine blade by adopting either fuel rich or oxidizer rich combustion. Thus, non-equilibrium chemical reaction dominates in the gas generator. Meanwhile, Kerosene is a compounded fuel mixed with various types of hydrocarbon elements and difficult to model the chemical kinetics. This study focus to model the non-equilibrium chemical reaction of kerosene/LOX with detailed kinetics developed by Dagaut using PSR(Perfectly stirred reactor) assumption. Also, droplet evaporation time is taken into account by calculating for the residence time of droplet and by decoupling reaction temperature from the reactor temperature. In Dagaut’s surrogate model for kerosene, chemical kinetics of kerosene consists of 1592 reaction steps with 207 chemical species. The comparison of calculation results with experimental data could provide very reliable and accurate numbers in the prediction of combustion gas temperature, species fraction and other gas properties.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1993.11a
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• pp.82-87
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• 1993

산업폐기물 소각시스템으로 현재 널리 이용되고 있는 대형 로타리 킬른형 소각로를 모델로 선정하여 소각로 설계에 필요한 제반변수에 대한 영향을 슈퍼컴퓨터를 이용하여 분석하였다. 화염억제 작용이 있으며 소각처리시 유독물질을 배출하는 $CCl_4$를 폐기물로 주입하는 경우 비평형 난류반응모델을 도입하여 반응장 해석을 한 결과 실험결과와 정성적으로 일치된 결과를 얻을 수 있었다.

• Clean Technology
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• v.17 no.2
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• pp.150-155
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• 2011

The removal process of heavy metal ion in aqueous solution by the functionalized silica bead was simulated using the finite difference method. Equilibrium model and non-equilibrium model were proposed and the effects of dimensionless groups and various parameters were investigated. Freundlich isotherm was used in equilibrium model and 1st order adsorption rate expression was assumed in non-equilibrium model. The comparison results by the predictions of equilibrium and non-equilibrium models showed good agreement. The predictions of equilibrium model were compared with experimental results reported in literature and showed the marginal agreement.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 1998.04a
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• pp.30-30
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• 1998

다목적 실용위성의 자세 제어용으로 장착되는 하이드라진 단일 추진제 추력기의 연소성능 특성을 살펴보았다. 일차적으로, 연소기내의 화학 평형 계산을 통하여 하이드라진 연소 생성물인 암모니아의 분해율과 초기 엔탈피 수준에 따른 추력기의 성능 특성을 살펴보았다. 다음 순서로, 연소기 내의 비평형 화학 반응 계산을 통하여 연소진행 시간에 화학 조성 및 성능 특성을 살펴 볼 수 있었으며, 최종적으로, 점성 및 비점성, 동결 및 비평형 화학 반응 해석에 따른 성능 특성 변화를 살펴보았다. 본 연구 결과로부터 각 작동 변수에 따른 추격기 성능 특성의 변화를 이해할 수 있었으며, 이는 단일 추진제 추력기 연소실의 구성, 설계 및 추력기의 운용 조건 설정에 중요한 자료로 이용될 수 있을 것으로 기대된다.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2007.04a
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• pp.143-147
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• 2007

Kerosene and diesel are compounded fuels with various types of hydrocarbon elements and difficult to model the chemical kinetics. This study focuses on the prediction of the non-equilibrium reaction of fuel-rich combustion with detailed kinetics developed by Dagaut using PSR(perfectly stirred reactor) assumption. In Dagaut's surrogate model for kerosene and diesel, chemical kinetics consists of 2352 reaction steps with 298 chemical species. Also, Frenklach's soot model was implemented along with detailed kinetics to calculate the gas properties of fuel rich combustion efflux.

• Journal of the Mineralogical Society of Korea
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• v.17 no.4
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• pp.299-307
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• 2004

Surfactant adsorption by two montmorillonite types with different interlayer cations of Ca and Na was characterized by examining the time dependence of surfactant behavior on the clay surfaces. Surfactants with different micelle concentration were conducted in our experiment to observe a nonequilibrium activity of cationic surfactant on the clay over reaction periods ranging from 0.1 min to 11 days. As compared with Ca-montmorillonite (SAz), a more active intrusion of surfactant molecules into the interlayers was found in Na-montmorillonite (SWy). During a short 'initiation' stage, the basal spacing of SWy montmorillonite increased rapidly with logarithmic time. For SAz montmorillonite, however, the abrupt basal spacing increase occurred at the later stage of the reaction. From the result, the difference in the adsorption behavior exhibited by the two montmorillonite types partly results from their intrinsic nature, that is, inorganic cations originally existing on the clay surfaces. Additionally, the micelle concentration of surfactants affects the development of organo-montmorillonite, especially, in the intercalant formation and stabilization under nonequilibrium.

• Journal of the Korean GEO-environmental Society
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• v.16 no.5
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• pp.5-11
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• 2015

The double sheeted permeable reactive barrier containing two different reactive materials can be applied to remediate the groundwater contaminated by nutrients and heavy metals. In this study, in order to evaluate the removal efficiency of contaminants including ammonium, cadmium and phosphate by double layered permeable reactive barrier containing zeolite and steelmaking slag, column tests were performed. In addition, nonequilibrium reaction in column tests was analyzed by two-site nonequilibrium advection-dispersion model. Column test results showed that zeolite is effective for removal of ammonium, while steelmaking slag is effective for removal of phosphate and cadmium. The sequential reaction of zeolite and steelmaking slag gave the better removal efficiency for ammonium.

• Journal of Energy Engineering
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• v.2 no.1
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• pp.54-67
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• 1993

Two turbulent reaction models of the premixed CC1$_4$/CH$_4$/air mixture are successfully incorporated in a 3-dimensional computer program and is applied for Dow Chemical incinerator equipped with two main off-center burners. The first reaction model is fast chemistry model(model 1), in which chemical reaction is governed by the turbulent mixing itself. And the second one is nonequilibrium model(model 2), where the effect of the chemical kinetics due to the presence of CC1$_4$is considered by the incorporation of the burning velocity data of CC1$_4$. The second model not only shows the flame inhibition trend due to the presence CC1$_4$compound, but also predicts qualitatively the vortical stratification of the CC1$_4$concentration appeared experimentally at the kiln exit. Other comparisions of two models are made in detail.