• Title/Summary/Keyword: 비용해성 용액

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막분리공정을 이용한 용수처리

  • 김해수
    • Proceedings of the Membrane Society of Korea Conference
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    • 1993.06a
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    • pp.83-95
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    • 1993
  • 현재 존재하는 다양한 filtration 테크놀러지는 feed stream으로부터 제거되는 파티클의 사이즈에 근거하여 그 범주를 정할 수 있다. 부유 고체물의 재래식 macrofiltration 은 feed solution이 수직 방향으로 filter media을 통하여 흐르게끔 하는 것이다. 전체 용액은 메디아를 통하여 지나가는데 단지 한개의 stream만 만든다. 그런 여과 장채의 보기를 들면, cartridge, filter, bag filter, sand filter, multimedia filter들이 있다. Macrofiltration separation은 1 미크론 이상가는 비용해성 파티클에 국한된다.

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Prediction of Degree of Mixing for Insoluble Solution with Vortex Index in a Passive Micromixer (마이크로 믹서에서 와도 지수에 의한 비용해성 물질의 혼합 예측)

  • Cho Il-dae;Kim Bum-joong;Maeng Joo-sung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.2 s.233
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    • pp.232-238
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    • 2005
  • The 'Mixing Index($D_I$)' is used as a conventional guidance measuring the degree of mixing for multiphase flows. For the case when insoluble solutions flow in a passive micromixer, a new method to calculate $D_I$ is proposed. The 'Vortex Index(${\Omega}_I$)' is suggested and formulated. We infer that ${\Omega}_I$ relates to the degree of chaotic advection. Various arbitrary shaped microchannels were tested to calculate the $D_I\;and\;{\Omega}_I$, and then a simple algebraic equation, $D_I=Aexp(B{\Omega}_I)$, is obtained. This equation may be used instead of the conventional partial differential equation, concentration equation, to estimate the degree of mixing.

Organic Wastewater Treatment Using Modified Fenton's Oxidation (변형 펜턴산화법을 이용한 유기폐수의 처리)

  • Kim, Ji Yeon;Yoon, Tai Il;Park, Se Jin
    • Clean Technology
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    • v.5 no.1
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    • pp.49-61
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    • 1999
  • Fenton's oxidation can improve the biodegradability of refractory organic wastewater by generating $OH{\cdot}$ which is one of the most reactive species. Fenton's reagent is used to treat a variety of industrial waste containing a range of toxic organic compounds. But this process cannot be economical because of high chemical cost of $H_2O_2$, ferrous ion solution and high sludge disposal cost. In this study, we proposed a modified Fenton's oxidation process which can reduce the reagent cost and obtain better removal efficiencies with less Fenton's reagents, and have a good potential of sludge recycling. In modified Fenton reaction, ferrous ion solution is adjusted to optimal pH with NaOH. Then it added to the sample and reacted to $H_2O_2$. For the experiment, synthetic wastewater made of phenol, which is one of the typical water pollutants, was used and the ionic strength of this wastewater was controlled by adding $NaHCO_3$. The effects of DO, ionic strength, and $H_2O_2$ dosing methods were investigated. As a result, modified Fenton's treatment efficiencies are better than conventional Fenton's reaction treating leachate and dyeing wastewater. And modified Fenton's treatment efficiencies combined to the sludge recycling for a half of Iron dosage are as good as the conventional Fenton's for a normal Iron dosage.

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Preparation of Disulfonated Poly(arylene ether sulfone) Random Copolymer Thin Film Composite Membranes Using a Benign Solvent (친환경용매 기반의 술폰화 폴리아릴렌 에테르 술폰 랜덤 공중합체 Thin Film Composite 제조)

  • Lee, Chang Hyun;McGrath, James E.;Freeman, Benny
    • Membrane Journal
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    • v.24 no.4
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    • pp.292-300
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    • 2014
  • Chlorine-resistant sulfonated poly(arylene ether sulfone) random copolymer (SPAES)-thin film composite (TFC) membranes for desalination are prepared using monoglyme as a selective solvent, which dissolves SPAES, but should be inert to porous polysulfone layer (e.g., Udel$^{(R)}$). Different from formic acid and diethylene glycol used as other selective solvents, monoglyme is environmentally friendly and has much lower boiling temperature. After a pretreatment of Udel$^{(R)}$ support film in isopropyl alcohol-glycerine mixture to minimize pore penetration leading to fairly reduced water flux, coating of SPAES solution in monoglyme onto the support and stepwise drying processes are conducted for defect-free TFC formation. The transport behavior through SPAES-TFC membranes is observed, correlating with the effects of sulfonation level, protonation, and physical and chemical crosslinking of SPAES selective layers.

Optimization for Removal of Nitrogen Using Non-consumable Anode Electrodes (비소모성 Anode(산화전극)을 이용한 질소 제거 최적화)

  • Hyunsang, Kim;Younghee, Kim
    • Clean Technology
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    • v.28 no.4
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    • pp.309-315
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    • 2022
  • Research was conducted to derive the optimal operation conditions and the optimal cathode for using a DSA electrode as an anode to minimize electrode consumption during the removal of nitrogen from wastewater by the electro-chemical method. Of the various electrodes tested as cathodes, brass was determined to be the optimal electrode. It had the highest NO3-N removal rate and the lowest concentration of residual NH3-N, a by-product when Cl is present in the solution. Investigating the effect of current density found that when the initial concentration of NO3-N was 50 mg L-1, the optimal current density was 15 mA cm-2. In addition, current densities above 15 mA cm-2 did not significantly affect the NO3-N removal rate. The effect of electrolytes on removing NO3-N and minimizing NH3-N was investigated by using Na2SO4 and NaCl as electrolytes and varying the reaction times. When Na2SO4 and NaCl are mixed at a ratio of 1.0 g L-1 to 0.5 g L-1 and reacted for 90 min at a current density of 15 mA cm-2 and an initial NO3-N concentration of 50 mg L-1, the removal rate of NO3-N was about 48% and there was no residual NH3-N. On the other hand, when using only 1.5 g L-1 of NaCl as an electrolyte, the removal rate of NO3-N was the highest at about 55% and there was no residual NH3-N.