• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.5
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• pp.75-84
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• 2016

This paper presents an investigation of the mechanical properties on non-sintered cement pastes immersed in sea waters at three different temperatures. The non-sintered cement pastes were synthesized using blended binder(Class F fly ash; FA and ground granulated blast furnace slag; GGBFS) and alkali activator(sodium hydroxide and sodium silicate). Binders were prepared by mixing the FA and GGBFS in different blend weight ratios of 6:4, 7:3 and 8:2. The alkali activators were used 5wt% of blended binder, respectively. Calcium carbonate was used as an chemical additive. The compressive strength, bulk density and absorption of alkali-activated FA-GGBFS blends pastes were measured at 3 and 28 days after immersed in sea waters at three different temperatures($5^{\circ}C$, $15^{\circ}C$ and $25^{\circ}C$). The XRD and SEM tests of the pastes were conducted at 28 days. Water-soluble chloride(free chloride) and acid-soluble chloride(total chloride) contents in the pastes were also measured after 28 days immersion in sea water. The experimental results showed that increasing the content of FA in alkali-activated FA-GGBFS blends pastes immersed in sea water increases the absorption, water-soluble chloride content and acid-soluble chloride content, and reduces the compressive strength and bulk density. And it was found that there was a variation of strength change for the alkali-activated FA-GGBFS blends pastes immersed in sea waters at three different temperatures that depends on the blending ratio of FA and GGBFS.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.04a
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• pp.186-187
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• 2022

The purpose of this study was to give fluidizing properties to non-sirtered cement made using by-products that can replace Portland cement by using a fluidizing agent. Blast furnace slag, C-type fly ash, and F-type fly ash were used for non-sirtered cement, and sand was used for aggregate. The amount of fluidizing agent used was fixed at 1%, and the water-cement ratio (W/C) was different by setting the binder blending ratio of the non-sintered cement differently, and the fluidity test and flow were compared. As a result of the experiment, when the flow standard was 170mm when the fluidizing agent was used, the fluidizing properties were shown at an average water-cement ratio (W/C) of 36%. Through this study, it was confirmed that the fluidizing properties appeared when the fluidizing agent was used in non-sintered cement.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2005.11a
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• pp.101-104
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• 2005

The world's cement demand is anticipated to increase about 2.558$\%$ every year until the first half of the 21st century. To be closed the increase of cenment damand and simultaneously comply with the Kyoto Protocal, cement that gives less carbon dioxide(Co2) discharge should be urgently developed. If cement can be manufactured with industrial byproducts such as granulated blast furnace slag(GBFS), phosphogypsum(PG), and waste lime(WL) instead of clinker as its counterproposal, there would be many advantages including maximum use of these industrial byproducts for high value-added resources, conservation of natural resources and energy by omitting the use of clinker, minimized environmental pollution problems caused by Co2 discharge and reduction of the cost. So this study aims to solve the problems by manufacturing non-sintered cement.

• Journal of the Korea Institute of Building Construction
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• v.23 no.1
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• pp.35-43
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• 2023

In this study, the mechanical properties of concrete mixed with non-sintered hwangto(NHT) as an alternate material for cement were evaluated, and the compressive strength prediction equation of concrete based on ultrasonic pulse velocity analysis was proposed. Cement replacement rates for mixed NHT were set to 0, 15, and 30%, and design compressive strength was set to 30 and 45MPa to evaluate the effect on the amount of cement and NHT powder. The mechanical properties items analyzed were compressive strength, ultrasonic pulse velocity, and elastic modulus, and were measured on days 1, 3, 7, and 28. As the replacement rate of NHT increased, the mechanical properties tended to decrease. In addition, as a result of analyzing the correlation between compressive strength and ultrasonic pulse velocity, the correlation coefficient(R²) showed a high relationship(R²=0.95) on concrete mixed with NHT.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.3
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• pp.138-144
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• 2017

In order to reduce carbon dioxide emission in construction industry, less amount of cement use can be one of the alternatives to manufacture concrete. One of the non-sintered construction materials are limestone, which is the raw material to manufacture ordinary Portland cement(OPC). A large amount of limestone have already been used as binders such as blended cement in Europe and US. Even European countries were already established the standard of blended cement, where the limestone can be used up to 35 percent. In this study, experimental researches were conducted to investigate the effects of limestone replacement on the mechanical properties and durability of concrete with 15%, 25% and 35% of limestone substitution to use limestone in blended cement. 15 percent use of limestone in blended cement developed equivalent or even higher compressive strengths compared to Plain mixture. Porosity of limestone cement with 15 percent substitution was much lower than Plain mixture. Most durability tests such as concrete carbonation, freeze-thaw cycle and drying shrinkage strains were conducted to evaluate long-term performance, and the test results indicated that 15 percent of limestone use did not significantly influence on the concrete durability compared with plain concrete.

• Economic and Environmental Geology
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• v.54 no.2
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• pp.285-297
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• 2021

Globally, nuclear-decommissioning facilities have been increased in number, and thereby hundreds of thousands of wastes, such as concrete, soil, and metal, have been generated. For this reason, there have been numerous efforts and researches on the development of technology for volume reduction and recycling of solid radioactive wastes, and this study reviewed and examined thoroughly such previous studies. The waste concrete powder is rehydrated by other processes such as grinding and sintering, and the processes rendered aluminate (C3A), C4AF, C3S, and ��-C2S, which are the significant compounds controlling the hydration reaction of concrete and the compressive strength of the solidified matrix. The review of the previous studies confirmed that waste concretes could be used as recycling cement, but there remain problems with the decreasing strength of solidified matrix due to mingling with aggregates. There have been further efforts to improve the performance of recycling concrete via mixing with reactive agents using industrial by-products, such as blast furnace slag and fly ash. As a result, the compressive strength of the solidified matrix was proved to be enhanced. On the contrary, there have been few kinds of researches on manufacturing recycled concretes using soil wastes. Illite and zeolite in soil waste show the high adsorption capacity on radioactive nuclides, and they can be recycled as solidification agents. If the soil wastes are recycled as much as possible, the volume of wastes generated from the decommissioning of nuclear power plants (NPPs) is not only significantly reduced, but collateral benefits also are received because radioactive wastes are safely disposed of by solidification agents made from such soil wastes. Thus, it is required to study the production of non-sintered cement using clay minerals in soil wastes. This paper reviewed related domestic and foreign researches to consider the sustainable recycling of concrete waste from NPPs as recycling cement and utilizing clay minerals in soil waste to produce unsintered cement.

• Tunnel and Underground Space
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• v.27 no.5
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• pp.312-323
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• 2017

In this study, an influence of mixing ratio among firing oyster shell, non-firing oyster shell, magnetic separated converter steel slag and fly ash used as admixtures on strength properties of soil cement was evaluated by correlation analysis among compressive strength, deformation modulus and mixing ratio of admixtures. As a result, the strength of the specimens containing non-firing oyster shells was found to be larger than that of firing oyster shells, and it was confirmed that firing oyster shells could negatively affect the strength of soil cement specimens unlike previous studies. In addtion, there was a positive correlation between the ratio of magnetic separated converter slag and strength properties, so it is confirmed that it can be used as an admixture.

• Journal of the Korea Concrete Institute
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• v.26 no.4
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• pp.499-506
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• 2014

A number of studies on eco-friendly and healthy building materials are being conducted as modern people are becoming more conscious about health and the environment they live in. Among those materials, studies on Hwangtoh are the most prevalent but due to its strength, crack coming from drying shrinkage, and susceptibility to water, the usage of Hwangtoh is incomplete and limited to be used as a common building material. Cement concrete, considered as one of the most widely used building materials, is extensively used in construction because it is economical, easily accessible and moldable and has proper compressive strength. Due to carbon dioxide created in the process of making cement concrete, it is recognized as pollution. Accordingly, there are a lot of studies on reduction of carbon dioxide in cement concrete industry. There are increasing numbers of researches as well as developments on Hwangtoh or traditional construction materials used in South Korea to reduce the environmental problems. Therefore, this study suggests the basic features of the construction material that can replace cement concrete in the future with the non-sindtered cement mixed with non-sintering hwangtoh which is made with the furnace slag and multiple stimulants.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.04a
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• pp.17-18
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• 2022

Carbon dioxide emissions in the construction sector account for 38% of all industries, and environmental destruction is occurring due to indiscriminate use of natural resources. The purpose of this study is to develop by-product aggregate Non-Sintered Cement(NSC) that can replace sand used as natural aggregate and Portland cement. Therefore, Ground Granulated Blast Furnace Slag, Type C Fly Ash and Type F Fly Ash are used to replace cement, and water granulated ferro-nickel slag(FNS) is used to replace aggregate. The flow, compressive strength and flexural strength of the formulation using sand as an aggregate and the formulation replacing 100% FNS were compared. As a result of the experiment, the formulation using FNS had higher overall strength than the formulation using sand, and as the substitution rate of Type C fly ash increased, the strength was the best. Formulation using FNS is more fluid than using sand. Through this study, we show the possibility of 100% substitution of FNS and its applicability to secondary concrete products of by-product aggregate NSC.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.05a
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• pp.297-298
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• 2023

In the concrete industry, efforts are being made to reduce CO₂ emissions, and technologies that collect, store, and utilize CO₂ have recently been studied. This study analyzed the change in compressive strength after the accelerated carbonation test of Non-Sintered Cement(NSC) mortar. Type C Fly Ash and Type F Fly Ash were mixed in a 1:1 ratio and then mixed with Blast Furnace Slag fine powder to produce NSC. The mortar produced was cured underwater until the target age. In addition, an accelerated carbonation test was conducted under the condition of a concentration of 5 (±1.0%) of CO₂ gas for 14 days. The mortar compressive strength was measured before and after 14 days of accelerated carbonation test based on the 7th and 28th days of age. As a result of the experiment, the compressive strength was improved in all binder. In general, the compressive strength of NSC mortar subjected to the accelerated carbonation test was similar to that of Ordinary Portland Cement(OPC) mortar not subjected to the accelerated carbonation test.