• Title/Summary/Keyword: 비모세관공극

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Enhanced Removal of Benzene-NAPL in Soil using Concurrent Injection of Cosolvent and Air (Cosolvent와 공기 동시 주입 공정에 의한 토양 내 벤젠-NAPL 세정 증대 연구)

  • Song, Chung-Hyun;Jeong, Seung-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.11
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    • pp.1095-1101
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    • 2008
  • Nonaqueous phase liquids (NAPL) are the continuous source for soil and groundwater contamination. The first objective of the study was to verify the effect of co-injection of cosolvent and air on NAPL removal from soil-column system. The second objective of the study was to investigate the effect of alcohol-partitioning property on the NAPL removal by the co-injection process of cosolvent and air. Enhanced removal of benzene-NAPL by the co-injection process of ethanol and air was also verified within the soilcolumn system. However, the co-injection process of Tert-butanol (TBA) and air showed no enhancement of benzene-NAPL removal. This study found that the viscous pressure of TBA was so higher than the capillary pressure and TBA easily displaced the benzene-NAPL and air present in soil pores. Air of the coinjection process did not work for NAPL removal but hindered NAPL mobilization. NAPL partitioning property and viscous pressure of cosovlent should be considered for application of the co-injection process of cosolvent and air.

Evaluation of Shrinkage and Creep Behavior of Low-Heat Cement Concrete (저열 시멘트 콘크리트의 건조수축 및 크리프 거동 평가)

  • Mun, Jae-Sung;Yang, Keun-Hyeok;Kim, Si-Jun
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.4
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    • pp.305-311
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    • 2016
  • This study examined the long-term inelastic characteristics, including unrestrained shrinkage and creep, of low-heat cement concrete under different ambient curing temperatures. To achieve the designed compressive strength of 42MPa, water-to-binder ratios were selected to be 27.5, 30, and 32.5% for curing temperatures of 5, 20, and $40^{\circ}C$, respectively. Test results showed that the shrinkage strains of concrete mixtures tended to decrease with the decrease in curing temperature because of the delayed evaporation of internal capillary and gel waters. Meanwhile, creep strains were higher in concrete specimens under lower curing temperature due to the occurrence of the transition temperature creep. The design models of KCI provision gave better accuracy in comparison with test results than those of ACI 209, although a correction factor for low-heat cement needs to be established in the KCI provision.

Analysis on the Rainfall Triggered Slope Failure with a Variation of Soil Layer Thickness: Flume Tests (강우로 인한 조립토 사면에서의 토층 두께 변화에 따른 사면의 활동 분석: 실내 모형실험)

  • SaGong, Myung;Yoo, Jea-Ho;Lee, Sung-Jin
    • Journal of the Korean Geotechnical Society
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    • v.25 no.4
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    • pp.91-103
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    • 2009
  • Slope failure depends upon the climatic features related to related rainfall, structural geology and geomorphological features as well as the variation of the mechanical behaviors of soil constituting a slope. In this paper, among many variables, effects of soil layer thickness on the slope failure process, and variations of matric suction and volumetric water content were observed. When the soil layer is relatively thick, the descending wetting front decreases matric suction and the observed matric suction reaches to "0" value. When the wetting front reaches to the impermeable boundary, the bottom surface of steel soil box, ascending wetting front was observed. This observation can be postulated to be the effects of various sizes of pores. When macro size pores exist, the capillary effects can be reduced and infilling of pore will be limited. The partially filled pores would be filled with water during the ascending of the wetting front, which bounces from the impermeable boundary. This assumption has been assured from the observation of variation of the volumetric water contents at different depth. When the soil layer is thick (thickness = 20 cm), for granular material, erosion is a cause triggering the slope failure. It has been found that the initiation of erosion occurs when the top soil is fully saturated. Meanwhile, when the soil layer is shallow (thickness = 10 cm), slope slides as en mass. The slope failure for this condition occurs when the wetting front reaches to the interface between the soil layer and steel soil box. As the wetting front approaches to the bottom of soil layer, reduction of shear resistance along the boundary and increase of the unit weight due to the infiltration occur and these produce complex effects on the slope failure processes.

Improvement of Durability and Change of Pore Structure for Concrete Surface by the Penetrative Surface Protection Agent (함침계 표면보호제에 의한 콘크리트 표면의 세공구조 변화 및 내구성 향상)

  • Kang, Suk-Pyo;Kim, Jung-Hwan
    • Journal of the Korea Concrete Institute
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    • v.18 no.1 s.91
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    • pp.125-132
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    • 2006
  • Recently, surface finishing and protection materials were developed to restore performance of the deteriorated concrete and inhibiting corrosion of the reinforcing-bar. For this purpose, surface protection agent as well as coatings are used. Coatings have the advantage of low Permeability of $CO_2,\;SO_2$ and water. However, for coatings such as epoxy, urethane and acryl, long-term adhesive strength is reduced and the formed membrane of those is blistered by various causes. Also when organic coatings are applied to the wet surface of concrete, those have a problem with adhesion. On the other hand, surface protection agent penetrates into pore structure in concrete through capillary and cm make a dense micro structure in concrete as a result of filling effect. Furthermore, the chemical reaction between silicate from surface protection agent and cement hydrates can also make a additional hydration product which is ideally compatible with concrete body. The aim of this study is to examine the effect of penetrative surface protection agent(SPA) by evaluating several concrete durability characteristics. The results show that the concrete penetrated surface protection agent exhibited higher durability characteristics for instance, carbonation velocity coefficient, resistance to chemical attack and chloride ion penetration than the plain concrete. These results due to formation of a discontinuous macro-pore system which inhibits deterioration factors of concrete by changed the pore structure(porosity and pore size distributions) of the concrete penetrated surface protection agent.

Fundamental Study on the Strength Development of Cement Paste using Hardening Accelerator and High-Early-Strength Cement (경화촉진제와 조강시멘트를 사용한 시멘트 페이스트의 강도발현에 대한 기초적 연구)

  • Min, Tae-Beom;Cho, In-Sung;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.13 no.4
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    • pp.407-415
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    • 2013
  • The purpose of this research is to verify the performance of hardening accelerator in cement paste through mechanical performance evaluation and micro structure analysis on hardening accelerator for development of super high early strength concrete. The research results showed that hardening accelerator produced $Ca(OH)_2$ when hydrated with cement, enhancing the degree of saturation of Ca ion by using differential thermal analysis. Moreover, porosity was reduced rapidly as capillary pores were filled by hydration products of $C_3S$. According to the experiment using hydration measurement testing, when 1% and 3% of accelerator were mixed, hydration rate increased toward the second peak point compared to high early strength cement, before the first peak point disappeared. It turned out that adding accelerator accelerated the hydration rate of cement, especially $C_3S$. The shape of C-S-H is shown depending on the amounts of accelerator added and the production and age of $Ca(OH)_2$ by using SEM to observes hydration products. Therefore, it's evident that hardening accelerator used in this research increases amounts of $Ca(OH)_2$ and accelerates $C_3S$, it is effective for the strength development on early age.

Autogenous Shrinkage Mock-up Test of High Performance Concrete by Emulsified Refined Cooking Oil (유화처리 정제식용유를 사용한 고성능 콘크리트의 자기수축 Mock-up 실험)

  • Jo, Man-Ki;Han, Cheon-Goo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.3
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    • pp.307-315
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    • 2016
  • The aim of this research is analyzing the fundamental properties and autogenous shrinkage reducing performance of 70 and 100MPa grade high performance concrete including emusified refined cooking oil(ERCO) under the mock-up conditions. As a results of experiment, the mixture contained 0.5% of ERCO showed slightly decreased slump flow while the slump was increased and segregation resistance performance was improved as 2.5 of EIS. For air content, all mixtures satisfied target air content with increased unit weight and delayed setting time with ERCO addition. In the case of compressive strength, when ERCO was added 0.5%, the result of approximately 5 to 10% of increased compressive strength was observed. For the autogenous shrinkage, ERCO contributed on 20-30% of shrinkage reducing performance comparing to Plain mixture without ERCO. It is considered that capillary pore filling action of soap particles occurred by the reaction of ERCO in cement paste between fatty aicd and calcium hydroxide contributed the shrinkage reducing performance. Based on these mock-up test results, application of the high performance concrete mixture with ERCO on CFT actual structure was decided.