• Proceedings of the Korean Fiber Society Conference
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• 2001.10a
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• pp.243-246
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• 2001

열가소성 고무탄성체인 폴리에테르에스테르계 고분자는 결정에 의한 물리적 가교를 형성할 수 있는 하드세그멘트 블록과 비결정성의 소프트세그멘트 블록으로 구성되어 탄성을 발현하는 성질을 갖는다. 이때 하드세그멘트의 함량의 변화는 고분자의 결정화 특성을 변화시켜 최종단계에서의 물성에 큰 영향을 미친다. 본 연구에서는 하드세그멘트가 PBT 구조로 이루어지고 소프트세그멘트는 PTMGT 구조를 갖는 4GT/PTMGT 고분자의 결정화 거동을 분석하였다. (중략)

• Proceedings of the Korean Society of Rheology Conference
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• 2006.06a
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• pp.89-92
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• 2006

• Korean Chemical Engineering Research
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• v.56 no.5
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• pp.725-731
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• 2018

The effects of catalysts addition on the carbonization reaction of biomass have been studied in a thermogravimetric analyzer (TGA). The sample biomasses were Bamboo and Pine. The catalysts tested were K, Zn metal compounds. The carbonization reactions were tested in the nonisothermal condition from the room temperature to $850^{\circ}C$ at a heating rate $1{\sim}10^{\circ}C/min$ on the flowing of $N_2$ purge gases. Also, the effects of catalyst on the torrefaction were tested in the temperature condition of 220, 250, $280^{\circ}C$ at 30 min. Combustion characteristic for the torrefied catalyst biomass were studied in the nonisothermal conditions of $200{\sim}850^{\circ}C$. As the results, the initial decomposition temperatures of the volatile matters ($T_i$) and the temperature of maximum reaction rate ($T_{max}$) were decreased with increasing the catalyst amounts in the sample biomass. The char amounts remained after carbonization at $400^{\circ}C$ increased with the catalyst amounts. Therefore catalysts addition can be decreased the energy for carbonization process and improved the heating value of product char. The catalysts reduced the optimum torrefaction conditions from $250^{\circ}C$ to $220^{\circ}C$. The torrefied catalyst biomass have lower activated energy from 46.5~58.7 kJ/mol to 25.1~27.0 kJ/mol in the nonisothermal combustion reaction.

• Journal of the KSME
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• v.33 no.9
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• pp.780-792
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• 1993

난류 열유속 측정을 위한 실험기법을 고찰해본 결과, 열선-냉선 조합 프로브의 사용이 현재로 서는 가장 가능성 있는 기법임을 알 수 있었다. 이와 같은 기법에서 가장 중요한 요소는 난류의 온도 변동량을 정확히 측정할 수 있는 계측장치의 확보임을 알았다. 그동안 사용되어 왔던 각종 냉선온도계의 검토와 본 연구실에서 새로이 개발한 냉선온도계의 설계 및 제작 기법에 대해 소 개하였다. 여러 가지 관점에서의 성능 비교를 통해 본 연구실에서 개발된 냉선 브리지의 성능이 상당히 우수함을 보였다. 난류 열유속의 측정과 비등온 유동에서의 난류 속도 성분을 측정하기 위한 프로브는 X형 hot-wire 프로브와 I형 cold wire 프로브를 조합하여 만들어졌으며, 온도와 속도를 함께 고려하여 교정함으로써 온도구배가 있는 속도장과 난류열유속을 측정할 수 있는 방법을 소개하였다.

• Journal of the Korea Organic Resources Recycling Association
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• v.21 no.1
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• pp.76-84
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• 2013

In this study, thermal weight loss, non-isothermally experiment, chemical composition analysis, calorific value, activation energy (E) were investigated to analysis the kinetic study of RDF, wood pellets, waste wood, waste textile and waste vinyl. When the chemical composition of solidification fuel was compared, the moisture content of RDF was less than the wood pellet and when the kinetic study was compared, the combustion reaction rate of the waste vinyl was higher than any other solidification fuels. However when the combustion efficiency was compared by the activation energy, the RDF had the higher efficiency than other wastes. RDF can be found that the reaction takes place between $320{\sim}720^{\circ}C$ depending on the heating rate.

• Polymer(Korea)
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• v.33 no.5
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• pp.435-440
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• 2009

Thermal degradation behavior of CR (chloroprene) -modified NR (natural rubber) compounds, having different sulfur/accelerator compositions, was studied by non-isothermal TGA method. Data were analyzed using both Kissinger and Flynn-Wall-Ozawa analysis to assess the activation energies. Activation energy obtained from Kissinger analysis was $147.0{\pm}2.0$ kJ/mol for all samples, showing little effect of sulfur/accelerator composition changes in the samples. On the other hand, activation energy from Flynn-Wall-Ozawa analysis exhibited much variations with conversion, showing average value of $211.6{\pm}19.0$ kJ/mol. From the results, it was considered that whole thermal degradation processes of the samples were composed of complex multiple step processes, of which reaction mechanisms were different from each other.

• Applied Chemistry for Engineering
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• v.23 no.5
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• pp.456-461
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• 2012

To verify the utilization of biomass as energy, the combustion characteristic has been studied by an experimental combustion furnace under an isothermal and non-isothermal combustion. The wood pellet, rice straw and rice husk were used as biomass samples in this work. The characteristics of emission gases, dusts and residues from biomass combustion have been analyzed and compared with those of reuse derived fuel (RDF). From isothermal combustion experiments, it was found that the incomplete combustion of rice straw was greater that that of rice husk, wood pellet and RDF. This is due to the fact that the combustion reaction rate of the rice straw was faster than that of other samples, and the oxygen concentration in rice straw combustion was rapidly decreasing. It was also found that $NO_{X}$ concentration of emission gas from wood pellet combustion was the lowest. From non-isothermal combustion experiments, it was found that all samples were burned before $900^{\circ}C$. Also, the temperature range of $NO_{X}$ emission was similar to that of CO emission, on the other hand, $SO_{2}$ was emitted at a higher temperature than that of CO emission.

• Transactions of the Korean Society of Automotive Engineers
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• v.24 no.5
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• pp.605-611
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• 2016

Mg alloy sheet exhibits significant differences in tensile and compressive yield stress depending on the temperature, as well as variations in its hardening behavior. Such unusual behavior makes it difficult to simulate the forming process of Mg alloy sheets. Results of analysis tend to deviate significantly from the experimental data because commercial software do not completely implement the unusual hardening behavior, yield asymmetry and temperature dependent changes in the Mg alloy's material properties. In the previous study, an in-plane tension-compression cyclic tester was developed to predict the cyclic behavior of Mg alloy sheets at an elevated temperature of up to $250^{\circ}C$. A new constitutive equation was suggested to analyze the unusual behavior, and was implemented in the commercial software in the form of user subroutine. In this paper, a stamping process of Mg seat cushion panel for automotive parts was simulated using the experimental data and user subroutine. Based on the analysis, an optimal temperature condition was determined and a stamping die shape at each step was suggested in the non-isothermal stamping of Mg alloy sheets.

• Journal of the Korean Society of Propulsion Engineers
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• v.18 no.2
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• pp.42-51
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• 2014

An experiment was conducted to study fuel injection characteristics of high boiling point test fuels (HBPTF), which are newly developed with higher boiling points than conventional aviation fuels, for various injection pressures when the fuel was heated to the temperature higher than their boiling points. The injection characteristics with elevating fuel temperature were quantified by the flow coefficient (${\alpha}$) and the cavitation number ($K_c$), and it was found that the trends between ${\alpha}$ and $K_c$ for various fuels were very similar with each other. In addition, compared with a conventional fuel, HBPTFs not only have higher fuel temperatures at which the effect of fuel boiling on the injection initiates, but also are less affected by the fuel boiling inside the injectors at temperatures over the boiling point.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.5
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• pp.554-560
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• 2021

CRUD (chalk river unidentified deposits) is a porous material deposited on the surface of nuclear fuel during nuclear power plant operation. The CRUD is composed of metal oxides, such as iron, nickel, and chromium. It is essential to investigate the effects of the CRUD layer on the wall heat transfer between the nuclear fuel surface and the coolant in the event of a nuclear accident. CRUD only negatively affects the temperature of the nuclear fuel due to heat resistance because the effects of the CRUD layer on two-phase boiling heat transfer are not considered. In this study, the physical property models for the porous CRUD layer were developed and implemented into the SPACE code. The effects of boiling heat transfer models on the peak cladding temperature and quenching were investigated by simulating a reflood experiment. The calculation results showed some positive effects of the CRUD layer.