• Title/Summary/Keyword: 비구조적 지표

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Fundamental Mechanisms of Platinum Catalyst for Oxygen Reduction Reaction in Fuel Cell: Density Functional Theory Approach (연료전지 산소환원반응 향상 위한 백금 촉매의 구조적 특성: 밀도범함수이론 연구)

  • Kang, Seok Ho;Lee, Chang-Mi;Lim, Dong-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.5
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    • pp.242-248
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    • 2016
  • The overall reaction rate of fuel cell is governed by oxygen reduction reaction (ORR) in the cathode due to its slowest reaction compared to the oxidation of hydrogen in the anode. The ORR efficiency can be readily evaluated by examining the adsorption strength of atomic oxygen on the surface of catalysts (i.e., known as a descriptor) and the adsorption energy can be controlled by transforming the surface geometry of catalysts. In the current study, the effect of the surface geometry of catalysts (i.e., strain effect) on the adsorption strength of atomic oxygen on platinum catalysts was analyzed by using density functional theory (DFT). The optimized lattice constant of Pt ($3.977{\AA}$) was increased and decreased by 1% to apply tensile and compressive strain to the Pt surface. Then the oxygen adsorption strengths on the modified Pt surfaces were compared and the electron charge density of the O-adsorbed Pt surfaces was analyzed. As the interatomic distance increased, the oxygen adsorption strength became stronger and the d-band center of the Pt surface atoms was shifted toward the Fermi level, implying that anti-bonding orbitals were shifted to the conduction band from the valence band (i.e., the anti-bonding between O and Pt was less likely formed). Consequently, enhanced ORR efficiency may be expected if the surface Pt-Pt distance can be reduced by approximately 2~4% compared to the pure Pt owing to the moderately controlled oxygen binding strength for improved ORR.

A Dye Tracer Study of Infiltration Pattern in a Residual Soil Developed from Granite (화강암 기원 잔적토양에서 염료추적자의 침투 유형에 관한 연구)

  • 전철민;김재곤;이진수;김탁현
    • Economic and Environmental Geology
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    • v.37 no.4
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    • pp.383-389
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    • 2004
  • Understanding flow pattern of water and solute in subsurface is essential for the reduction and prevention of contamination of soil and groundwater and for the investigation and remediation of contaminated site. The objective of this study is to examine the infiltration pattern in a soil developed from the Jurassic granite using (Brilliant Blue FCF $C_{37}H_{34}N_{2}Na_{2}O_{9}S_{3}$), the nonfluorescent and nontoxic food dye. All image processing was conducted using geographic image processing software, ER Mapper, Version 6.2. The dye coverage was determined by counting the stained pixels in the photographs (80${\times}$80cm, 80TEX>${\times}$5cm) for the vertical and horizontal view. A homogeneous matrix flow occurred in the A horizon with weak, medium granular structure and fingering at the interface of finer-textured A horizon and coarser-textured C horizon. Pegmatitic vein originated from the granite and plant root in C horizon induced preferential flow.

An Experimental Study on the Settlement Characteristics of the Corner of Earth Retaining Wall According to the Ground Excavation (지반굴착에 따른 흙막이벽 우각부 모서리 구간의 침하특성에 대한 실험 연구)

  • Yoon, Won-Sub;Cho, Chul-Hyun;Cho, Young-Kweon;Chae, Young-Su
    • Journal of the Korean Geosynthetics Society
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    • v.12 no.2
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    • pp.55-66
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    • 2013
  • The experiment of model soil structures has been executed for the soil retaining wall in various conditions of excavation, in this study, to analyze the behavior of the corner of opening. The ground for experiment has been constituted with the sandy soil of relatively loose density, the construction condition has been divided into the opening length of corner, embedded depth, existence of strut, etc., and the excavation has been carried out for 4 stages in total. The behavior characteristics at the corner of opening area has been verified by concentrate analysis of the displacement of wall and the subsidence of ground surface, for each construction and excavation condition, using the measuring instrument mounted inside the model soil structure. In the result of experiment, it has been analyzed that the opening area of corner is unstable structurally compared to the linear area, as it shows that the wall displacement and subsidence of ground surface have been increased when the opening length of corner gets longer. The longer the embedded depth, ground surface settlement of coner was decreased 40%. To apply deeper embedded depth than designed estimate was an advantage in the safety. As a result of the analysis of coner behavior with added struts, maximum surface settlement and maximum horizontal displacement was evaluated 40% and 30%, respectively. Hence increased embedded depth with the added struts in coner edge was effective in the safety.

Geophysical Exploration of Songsalli Ancient Tombs and Analysis of King Muryeong's Tomb Structure, Gongju (공주 송산리 고분군(公州 宋山里 古墳群)에서의 물리탐사와 무령왕릉(武寧王陵)의 구조분석)

  • Oh, Hyun-dok
    • Korean Journal of Heritage: History & Science
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    • v.46 no.4
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    • pp.4-23
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    • 2013
  • Songsalli Ancient Tombs of Gongju consists of seven tombs. King Muryeong's tomb, the seventh tomb, is a brick chamber tomb discovered during the drainage works for the fifth and the sixth tombs in 1971. The excavation at the time focused on topographic surveys of the tomb entrance and the inside of the burial chamber as well as collection of the remains. The burial mount survey confirmed the status of some stone slab remaining and lime-mixed soil layers, but the survey did not examine the exterior structure of the whole tomb as the mounds were removed even more deeply. The excavation revealed damages to the bricks and mural damages due to moisture and fungus in the sixth and the seventh tombs. Between 1996 and 1997, Gongju National University conducted a comprehensive detailed survey of Songsalli Ancient Tombs including a geophysical survey, with an aim to identify the root causes of such degradation. Based on the results, repair took place in 1999 and the fifth, sixth and seventh tombs were placed under permanent conservation to conserve the cultural assets. General public is currently denied access. The purpose of this study was to conduct a three-dimensional resistivity and GPR surveys on the ground surface of the fifth, sixth and seventh tombs of Songsalli Ancient Tombs in order to understand the underground status after repair. The study also aimed to understand the thickness of all the tomb walls and exterior structure based on GPR inside King Muryeong's tomb. The exploration on the ground surface found that the three tombs and soil adjacent to the tombs had resistivity as low as 5 to $90{\Omega}m$, which confirmed that the soil water content was still as high as that prior to the repair work. Additionally, GPR found that the wall construction of the burial chamber of King Muryeong's tomb was approximately 70cm in thickness, while the structure was of 2B with two bricks, about 35cm in length, put together longitudinally(2B brick masonry). The pathway to the burial chamber was of the 2B structure just like that of the burial chamber walls, while its thickness was 80cm with an eyebrow-type arch connected to it. Also, the ceiling exterior appears to have an arch structure, identical to the shape inside.

Growing Environment Characteristics and Vegetation Structure of Lonicera harae, Medicinal Plant (약용식물 길마가지나무 자생지의 생육환경특성과 식생구조)

  • Son, Yonghwan;Park, Sunghyuk;Jeong, Daehui;Cho, Hyejung;Son, Hojun;Jeon, Kwonseok
    • Korean Journal of Plant Resources
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    • v.34 no.4
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    • pp.297-310
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    • 2021
  • Lonicera harae is a species of shrub in the Caprifoliaceae family, mostly distributed in East asia. So far, the related research on the genus of Lonicera is insufficient compared to the Lonicera japonica belonging to the same genus, which requires attention to domestic native plants. Therefore, this study aims to provide baseline data for cultivation and utilization through the growth environment and vegetation structure of the natural habitat. Lonicera harae, which plant found throughout the Korean Peninsula. The natural habitats of Lonicera harae is the forest, valley and lowland areas of the southern region. study examined 24 quadrats in 11 regions, including Gwangju, Wanju and Namhae. As a result, environmental condition of Lonicera harae was 8 to 483 m above sea level, normally distributed over 173 m, Slope was 5 to 25 degree with 8.5 degree on average. The list of plants were classified as a total of 229 taxa comprising 80 families, 166 genus, 198 species, 3 subspecies, 24 varieties, 4 forma. As a result of the clustering analysis, the three clusters were divided into three groups; Robinia pseudoacacia, Zelkova serrata, Larix kaempferi. Species diversity was 1.399 and Dominance and Evenness were found to be 0.978 and 0.022 respectively.

The Parallel Recovery Method for High Availability in Shared-Nothing Spatial Database Cluster (비공유 공간 데이터베이스 클러스터에서 고가용성을 위한 병렬 회복 기법)

  • You, Byeong-Seob;Jang, Yong-Il;Lee, Sun-Jo;Bae, Hae-Young
    • Proceedings of the Korea Information Processing Society Conference
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    • 2003.11c
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    • pp.1529-1532
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    • 2003
  • 최근 인터넷과 모바일 시스템이 급속히 발달함에 따라 이를 통하여 지리정보와 같은 공간데이터를 제공하는 서비스가 증가하였다. 이는 대용량 데이터에 대한 관리 및 빠른 처리와 급증하는 사용자에 대한 높은 동시처리량 및 높은 안정성을 요구하였고, 이를 해결하기 위하여 비공유 공간 데이터베이스 클러스터가 개발되었다. 비공유 공간 데이터베이스 클러스터는 고가용성을 위한 구조로서 문제가 발생할 경우 다른 백업노드가 대신하여 서비스를 지속시킨다. 그러나 기존의 비공유 공간 데이터베이스 클러스터는 클러스터 구성에 대한 회복을 위하여 로그를 계속 유지하므로 로그를 남기기 위해 보통의 질의처리 성능이 저하되었으며 로그 유지를 위한 비용이 증가하였다. 또한 노드단위의 로그를 갖기 때문에 클러스터 구성에 대한 회복이 직렬적으로 이루어져 고가용성을 위한 빠른 회복이 불가능 하였다. 따라서 본 논문에서는 비공유 공간 데이터베이스 클러스터에서 고가용성을 위한 병렬 회복 기법을 제안한다. 이를 위해 클러스터 구성에 대한 회복을 위한 클러스터 로그를 정의한다. 정의된 클러스터 로그는 마스터 테이블이 존재하는 노드에서 그룹내 다른 노드가 정지된 것을 감지할 때 남기기 시작한다. 정지된 노드는 자체회복을 마친 후 클러스터 구성에 대한 회복을 하는 단계에서 존재하는 복제본 테이블 각각에 대한 클러스터 로그를 병렬적으로 받아 회복을 한다. 따라서 정지된 노드가 발생할 경우에만 클러스터 로그를 남기므로 보통의 질의처리의 성능 저하가 없고 클러스터 로그 유지 비용이 적으며, 클러스터 구성에 대한 회복시 테이블단위의 병렬적인 회복으로 대용량 데이터인 공간데이터에 대해 빠르게 회복할 수 있어 가용성을 향상시킨다.들을 문법으로 작성하였으며, PGS를 통해 생성된 어휘 정보를 가지고 스캐너를 구성하였으며, 파싱테이블을 가지고 파서를 설계하였다. 파서의 출력으로 AST가 생성되면 번역기는 AST를 탐색하면서 의미적으로 동등한 MSIL 코드를 생성하도록 시스템을 컴파일러 기법을 이용하여 모듈별로 구성하였다.적용하였다.n rate compared with conventional face recognition algorithms. 아니라 실내에서도 발생하고 있었다. 정량한 8개 화합물 각각과 총 휘발성 유기화합물의 스피어만 상관계수는 벤젠을 제외하고는 모두 유의하였다. 이중 톨루엔과 크실렌은 총 휘발성 유기화합물과 좋은 상관성 (톨루엔 0.76, 크실렌, 0.87)을 나타내었다. 이 연구는 톨루엔과 크실렌이 총 휘발성 유기화합물의 좋은 지표를 사용될 있고, 톨루엔, 에틸벤젠, 크실렌 등 많은 휘발성 유기화합물의 발생원은 실외뿐 아니라 실내에도 있음을 나타내고 있다.>10)의 $[^{18}F]F_2$를 얻었다. 결론: $^{18}O(p,n)^{18}F$ 핵반응을 이용하여 친전자성 방사성동위원소 $[^{18}F]F_2$를 생산하였다. 표적 챔버는 알루미늄으로 제작하였으며 본 연구에서 연구된 $[^{18}F]F_2$가스는 친핵성 치환반응으로 방사성동위원소를 도입하기 어려운 다양한 방사성의 약품개발에 유용하게 이용될 수 있을 것이다.었으나 움직임 보정 후 영상을 이용하여 비교한 경우, 결합능 변화가 선조체 영역에서 국한되어 나타나며 그 유의성이 움직임 보정 전에 비하여 낮음을 알 수 있었다. 결론: 뇌활성화 과제 수행시에 동반되는

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Investigation of fault in the Kyungju Kaekok-ri area by 2-D Electrical Resistivity Survey (2차원 전기비저항 탐사를 이용한 경주 개곡리 지역의 단층조사)

  • Lee, Chi-Seop;Kim, Hee-Joon;Kong, Young-Sae;Lee, Jung-Mo;Chang, Tae-Woo
    • Geophysics and Geophysical Exploration
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    • v.4 no.4
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    • pp.124-132
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    • 2001
  • Electrical resistivity survey has been conducted for delineating geological fault structure in Kaekok-ri near Kyungju. In general, electrical resistivity survey has an advantage of searching buried faults and its traces compared with other geophysical survey methods. Distribution of electrical conductivity in the ground is influenced by the ratio of pores, groundwater and clay minerals. These properties are evidenced indirectly to explain for weathering condition, faults and fracture Bones. Thus the electrical resistivity survey can be an effective method to find buried faults. We have carried out two dimensional (2-D) interpretation by means of smoothness-constrained least-squares and finite element method. Field data used in this paper was acquired at Kaekok-ri, Wuedong-eup, Kyungju-si, where is Ulsan Fault and is close to the region in which debatable quaternary fault traces were found recently. The dipole-dipole array resistivity survey which could show the 2-D subsurface electrical resistivity structure, was carried out in the area with three lines. The results showed good property of fault, fracture zone and fault traces which we estimated were congruous with the results. Through this study, 2-D electrical resistivity survey interpretation for fault is useful to apply.

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The Occupational Structure of the Junior College Students' Transfer and Occupation Status Effect (편입학의 직업지위 효과와 직업구조: 전문대졸자 vs. 일반대 편입학자)

  • Choi, Sun-Mee
    • Journal of vocational education research
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    • v.35 no.4
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    • pp.63-88
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    • 2016
  • This study surveyed and analyzed the labor market result when comparing the case that junior college students found a job after transferring to 4-year university with the case that they found the job directly after graduating the junior college. The difference of the occupational structure following the transfer was surveyed in detail and this study examined what effect the transfer had on the occupation status. The graduate occupation movement survey(GOMS) was used and the samples of 544 persons were extracted to use through propensity score matching(PSM) to raise the choice convenience of the sample. The occupation status index to use as a dependent variable was developed to apply. The study result is as follows. First, as a result of confirming the occupational structure of the transfer, the transfer students were distributed in more various industrial fields evenly compared to the non-transfer students in the horizontal industrial structure, and non-transfer students were intensively distributed in the certain field. In the vertical occupation status structure, transfer students were distributed in the high occupation status more than non-transfer students who were broadly distributed in the low occupation status. Second, it was revealed the college transfer was highly effective for the occupation status, which appeared statistically significantly. The explanation variable that appeared significantly outside of that included the parents' academic background, major affiliation, employment pattern, major job coincidence, and job coincidence. The higher students' academic background was, the higher the occupation status was and in case of the engineering natural science affiliation, the occupation status was higher than the humanities social science. In case of full-time workers, their occupation status was higher than one of part time workers and it was revealed the occupation status was high when the their major coincided with the job and their educational/technical level coincided with their job.

Efficiency of the Hierarchical Structure for a Bus Network (시내버스 노선망 위계구조의 효율성 분석 (대전시 사례분석을 중심으로))

  • Lee, Beom-Gyu;Jang, Hyeon-Bong
    • Journal of Korean Society of Transportation
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    • v.27 no.3
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    • pp.49-58
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    • 2009
  • Four alternative plans for the bus network in Daejeon metropolitan city, which have different hierarchical structure, were proposed : Alternative 1 represents a bus network without hierarchical structure, and Alternative 2, 3, and 4 represent bus networks with primary, intermediate, and advanced hierarchical structures, respectively. Efficiency of the alternative plans were evaluated based on the evaluation index including travel time cost, waiting time cost, and transition penalty cost. The travel time cost was decreased as the level of hierarchical structure gets higher until it reaches the extremely high level. As the level of hierarchical structure get higher, the waiting time cost significantly decreased while the transition penalty cost increased. Collectively, a bus network with hierarchical structure was shown to be more efficient than without it in the light of total travel cost. For the bus network with hierarchical structure, total travel cost shows a concave curve, which implies that there exists an optimal level of hierarchical structure in a bus network.

Geophysical Prospecting for Geothermal Resources at Northern Part of Kumseongsan, Euiseong (의성 금성산 북부지역의 지열자원 지구물리탐사)

  • Lee, Gidong;Han, Kihwan;Kim, Kibeom;Lee, Jongmoon
    • Journal of the Korean GEO-environmental Society
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    • v.7 no.6
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    • pp.35-44
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    • 2006
  • Various geophysical methods and geological survey were applied for prospecting of geothermal resources and the attitude of volcanic body at northern part of Kumseongsan, Euiseong. They include magnetic, self-potential, radioactive and resistivity methods, temperature logging near the earth's surface and geological survey. The results of this study are summarized as follows. Various geophysical anomalies is related to the geologically Cretaceous conduit. Anomalies of resistivity and temperature logging seem to be related to the geological structure and terrestrial heat. Small radioactive and self-potential anomalies seem to be associated with chemical character of rocks. The sedimentary rocks dip steeply toward the volcanic rocks, aquifuge. Ideal geological structure for bearing ground water and geothermal resources was founded in the study area. The study area and the adjacent two hot springs area consist of Cretaceous sedimentary and volcanic rocks, and have similar geology.

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