• Applied Chemistry for Engineering
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• v.2 no.2
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• pp.155-164
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• 1991

The reaction mechanism and the effects of the oxidation state of vanadium oxide and of support on catalytic activity for the oxidation of o-xylene were investigated. The oxidation of o-xylene simultaneously proceeded through the consecutive and parallel mechanisms. The high valence of vanadium favored selective oxidation to phthalic anhydride, while the low valence caused complete oxidation of phthalic anhydride to CO and $CO_2$. Crystalline $V_2O_5$ showed better selectivity for partial oxidation rather than amorphous one.

• Polymer(Korea)
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• v.26 no.6
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• pp.737-744
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• 2002

Thermodynamic miscibility of the binary blends composed of semi-crystalline poly (butylene 2,6-naphthalate) (PBN) and amorphous poly (4-vinylphenol) (PVPh) was investigated using differential scanning calorimetry (DSC) and Fourier transform infrared (FTIR) spectroscopy. DSC scan results showed that there was a single glass transition temperature (T$\_$g/) for each blend. Crystalline melting temperature (T$\_$m/) depression of the PBN in the blends was also observed with the increase of PVPh content. Both results of the single T$\_$g/ and the depression of T$\_$m/ for the PBN/PVPh blends indicate that the blends are thermodynamically miscible at the molecular level. FTIR spectroscopic analysis confirmed that strong intermolecular hydrogen bonding interactions between the ester carbonyl groups of the PBN and the hydroxyl groups of the PVPh are occurred.

• Elastomers and Composites
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• v.46 no.3
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• pp.245-250
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• 2011

The self diffusions and hole volumes of amorphous region of poly(acrylonitrile)-poly(vinyl chloride) fibers were investigated by experiments of stress relaxation. The experiments of stress relaxation were carried out using the tensile tester with the solvent chamber. The flow parameters of filament fibers were obtained by applying the experimental stress relaxation curves to the theoretical equation of stress relaxation. From the flow parameters, the hole volumes, self diffusions, viscosities and thermodynamic parameters of solid polymers were calculated. It was observed that the flow parameters of these samples are directly related to the hole volumes, self diffusions and flow activation energies of flow segments.

• The Transactions of the Korea Information Processing Society
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• v.4 no.8
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• pp.1975-1986
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• 1997

Recent evolution of communication networks has led toward increasingly a complex, large-scale protocol. Protocol conformance tests therefore, which consider only control flow, have many problems on testing data flow, transition condition, delay and so on. We propose, design, and implement the tool to solve these problems. The tool, which solves nondeterminism, generates test suites from an integrated flow graph and excludes infeasible path with reachable tree. The presented tool reduces the length of UIO sequence and is efficient partially to test the path that error rate is high. Our automatic test suite generator provides basis of protocol testing environment and high production.

• The Journal of Korean Philosophical History
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• no.30
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• pp.191-225
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• 2010

This paper is the outcome of attempting to approach for reading the Analects of Confucius through the polysemy of Chinese character and indecidability of articles. For this purpose at first, I explained which this Chinese character can be applied for 'philosophy language'. In the 16th century Matteo Ricci had tried to find out the possibility of ideographic script as standing for a universal language. On the other hand, Hegel and Heidegger strictly insisted on the Chinese character is inappropriate for expressing the logic thought of the human being. The reason was as next; firstly, this character had not the preposition and articles, and secondly the only one word could not indicates the bisemy including the meaning of opposition, lastly this language system expresses and communicates only with the change of word order without inflection. But With some scholar like Cassirer, Saussure and Derrida we can confirm the possibility which will discover the Chinese character for using the logic and reasoning language of from different view. Because in the language system of this Chinese character the connection of words in contexts is more important other than meaning as the individual word, in comparison to the language of the West. The Chinese character hides the original meaning until being what kind of event and thing relationship watch inside with different letters. So to speak, the Chinese character is called as 'language of indecidability'. For these points, even though The Chinese character lacks of preposition, articles, and inflection speech etc. the letter systematic, this language system can play a role for expressing as the philosophic language which manages with the complicated problems of the human being.

• Proceedings of the KAIS Fall Conference
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• 2002.05a
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• pp.130-133
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• 2002

금형온도가 사출 성형품에 미치는 영향 중에 결정성수지인 PP(Polypropylene)와 비결정성수지인 PS(Polysyene)는 금형온도가 높아짐에 따라 각기 다른 결과를 나타내었다. PS성형품은 금형온도가 높을수록 수축율이 줄어들고 두께 편차가 적어지는 경향을 관찰할 수 있었고, PP성형품의 경우에는 결정의 생성으로 인한 상반된 경향이 관찰되었다. 또한, 금형온도에 따른 캐비티의 매끄러운 면과 거친 면의 결과로 볼 때 금형온도가 높을수록 캐비티의 충전성 및 전사성이 향상되었다. MmSH(Momentary Mold Surface Heating)조건인 경우는 수축율과 전사성 모두다 양호한 결과를 보여주었다.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.4 no.3
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• pp.172-176
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• 2003

In this paper, we studied the effects of mold temperature on the microstructure of injection molded parts. The weld line decreases in length and width as mold temperature increases. We investigated the dimensional stability of the parts made of two kinds of resin(polypropylene and polystyrene) by varying the mold temperature. As the mold temperature is high, both the shrinkage ratio and the thickness difference for the PS parts decreases. But the observation of PP parts shows a tendency to increase. The easiness of cavity filling and transcription of the mold texture is improved as the mold temperature is high.

• Journal of the Korean Chemical Society
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• v.54 no.6
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• pp.717-722
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• 2010

Two derivatives of star shaped compounds based on naphthylamine with symmetric trisubstituted benzene as core, methoxy and ethoxy as end substitutions are synthesized. The synthesized compounds are characterized by UV-visible, FT-IR and NMR spectrometric techniques. The electronic and thermal properties of the compounds are studied using cyclic voltametry (CV) and differential scanning calorimetry (DSC) respectively. The data's obtained have similarity with the arylamines that have been already used in optoelectronic devices. So these compounds are interesting materials for applications in such devices.

• Applied Chemistry for Engineering
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• v.10 no.5
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• pp.711-717
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• 1999

A multilayer-structure material containing ductile and brittle layer simultaneously was examined and compared with a single layer material using fracture mechanical properties. We found that impact strength of multilayer structure material was considerably higher than single layer's and toughness was enhanced by about two times or higher in similar glass transition temperature($T_g$) region and the same dimension. The superposition principle of impact pulse was used for interpretation of kinetic stress wave as a high-velocity crack proceeds in the plastic. It was understood that the optimum condition of ductile/brittle thickness ratio could be designed in the final toughness enhancement of multilayer.

• Polymer(Korea)
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• v.24 no.4
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• pp.513-519
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• 2000

The effect of petroleum resin as a tackifier for polyalphaolefin (APAO) hot melt adhesive on thermal properties, crystallinity and adhesion strength was investigated. The presence of petroleum resin resulted in the melting temperature decrease in APAO/petroleum blend, especially, in APAO with low ethylene content/C$_{5}$ petroleum blend. It was also found that petroleum resin caused the decrease of crystallinity regardless of ethylene content in APAO. The maximum adhesion strength was found to be at 50/50 (APAO/petroleum) composition. $C_{5}$ resin was more effective to increase adhesion strength than $C_{9}$ for APAO with high ethylene content. In addition, it was found that the adhesion strength was improved with the decrease of crystallinity in APAO/petroleum resin hot melts.