• Title/Summary/Keyword: 블렌딩

Search Result 222, Processing Time 0.025 seconds

Preparation and Characterization of the Blends of Poly(vinyl alcohol) and N-(2-hydroxy)propyl-3-trimethylammonium Chitosan Chloride (폴리(비닐 알코올)과 N-(2-하이드록시)프로필-3-트리메틸 키토산 클로라이드 블렌드의 제조와 특성 분석)

  • 김영호;최재원;이은영
    • Polymer(Korea)
    • /
    • v.27 no.5
    • /
    • pp.405-412
    • /
    • 2003
  • Poly(vinyl alcohol) (PVA) and N-(2-hydroxy)propyl-3-trimethylammonium chitosan chloride (HTCC), a water soluble chitosan derivative synthesized by the reaction of quaternary ammonium compound with chitosan, were blended using water as a solvent and the PVA/HTCC blend films with various compositions were prepared by solution casting method. The miscibility between the two polymers and the thermal properties of the blend films were investigated using FT-IR, DSC, DMA, and TGA. Single glass transition temperatures and single melting temperatures of the blend films along with the strong and clear film state for the whole composition of blending ratios suggest the miscibility between PVA and HTCC. The PVA/HTCC blend films with HTCC content of 1% and greater showed excellent antimicrobial activity.

Emulsion Blends of Polyurethane Ionomers from Ester and Ether Type Polyols (Ester 및 Ether형 Polyurethane Ionomer의 Emulsion 블랜드)

  • Kim, Sang-June;Kim, Byung-Kyu
    • Applied Chemistry for Engineering
    • /
    • v.3 no.4
    • /
    • pp.614-619
    • /
    • 1992
  • Two types of polyurethane(PU) ionomer dispersion having different type of soft segment, viz. Poly (tetramethylene adipate) glycol(PTAd), and polypropylene glycol(PPG) were emulsion blended. Viscosity of emulsion blend, mechanical, and surface properties of the emulsion cast films were determined as a function of blend composition. Mechanical properties showed a large scatter of data or negative deviation from the additivity rule, and this was attributed to the incompatibility of soft segments. Contact angle measurement indicated that air facing surface of emulsion cast film contained more of PPG PU, due probably to its smaller particle diameter compared to PTAd PU.

  • PDF

A Study on the Preparation of Solvent Type Low Foaming Scouring Agents (용제형 저기포성 정련제의 제조에 관한 연구)

  • Park, Eun-Kyung;Park, Hong-Soo;Kim, Young-Keun
    • Applied Chemistry for Engineering
    • /
    • v.4 no.2
    • /
    • pp.358-364
    • /
    • 1993
  • Low foaming scouring agents(SLFS) were prepared by blending of 2-ethylhexylaminoethyl sulfate, Na-dioctyl sulfosuccinate, Newpol PP-2000, MJU-100, ethylene glycol and organic solvent. As the results of several tests, SLFS-2 showed good scouring effect, penetrating ability, emulsifiability and anti-alkaline property, and showed not much water pollution. The foaming power of SLFS-2 measured by Ross & Mites method was 8mm foam height immediately after foaming. And the foaming power of SLFS-2 measured by Ross & Clark method were less than 300mm foam height at $30^{\circ}C$, and 15mm at $80^{\circ}C$. As a result, SLFS-2 was proved as a good low foaming scouring agent.

  • PDF

Dispersity and Electro-Conductivity of PU Grafted MWCNT/PU Composite via Simple Blending Method (블렌딩을 이용한 폴리우레탄 그라프트 다중벽 탄소나노튜브/폴리우레탄 복합체의 전기 전도성 및 분산 특성)

  • Yun, Sung-Jin;Im, Hyun-Gu;Kim, Joo-Heon
    • Applied Chemistry for Engineering
    • /
    • v.21 no.5
    • /
    • pp.500-504
    • /
    • 2010
  • The PU-g-MWNTs/PU film was synthesized by simple blending method to fabricate composites which have excellent mechanical and electrical properties. PU-g-MWNTs based composite revealed much enhanced dispersity than pristine MWNTs composite because of interfacial interaction related with interfacial compatibility between polymer matrix and PU on the MWNTs surface. The electro-conductivity of composite was measured as a function of PU-g-MWNTs concentration. The results were correlated with percolation threshold theory. As a result, the critical concentration and exponent of electro-conductivity behavior was equal to 0.78 wt% and 0.945.

Preparation of Polycarbonate/Polyaniline Conducting Composite and Their Electrical Properties (Polycarbonate/Polyaniline 전도성 복합체의 제조 및 전기적 성질)

  • Lee, Wan-Jin;Kim, Yong-Ju
    • Applied Chemistry for Engineering
    • /
    • v.10 no.2
    • /
    • pp.287-292
    • /
    • 1999
  • The conducting composites were prepared by solution blending of polyaniline (PANI) as a conducting polymer and polycarbonate (PC) as a matrix in chloroform. Also the composites film was prepared by solution casting method. The PANI was protonated with alkylbenzenesulfonic acids, such as camphorsulfonic acid (CSA) or dodecylbenzenesulfonic acid (DBSA). The electrical conductivity of composites prepared by solution casting was enhanced compared with that of compression molding. The electrical conductivity, tensile strength and morphology were observed as a function of the amount of protonating agent as well as PANI complex content. In general, as the PANI complex content was increased, the electrical conductivity increased. In the case of the composite film containing 25 wt % of PANI complex doped with DBSA, the electrical conductivity exhibited 3.18 S/cm.

  • PDF

A Study on the Preparation of Nylon6,6/Polypyrrole Conducting Composite (Nylon6,6/Polypyrrole 전도성 복합체의 제조에 관한 연구)

  • Lee, Wan-Jin;Kim, Hyo-Yong
    • Applied Chemistry for Engineering
    • /
    • v.10 no.2
    • /
    • pp.281-286
    • /
    • 1999
  • The conducting composites were prepared by blending polypyrrole (PPy) as a conducting polymer and nylon6,6 as a matrix. In chemical polymerization of PPy, the oxidizing agent was $FeCl_3$ and dopant was alkylbenzenesulfonic acid, such as camphorsulfonic acid (CSA) or dodecylbenzene sulfonic acid (DBSA). The electrical conductivity and mechanical properties were measured for the amount of dopant and PPy complex, and these morphology observed. When it was doped with DBSA having long alkyl chain and added the PPy complex of 25 wt %, the electrical conductivity was increased up to 0.64 S/cm.

  • PDF

Mechanical Properties and Biodegradability of HDPE/TPS Blends (HDPE/TPS블렌드의 물성 및 생분해도)

  • 이상일;홍경민;서석훈;신용섭;김봉식;신부영
    • Polymer(Korea)
    • /
    • v.26 no.1
    • /
    • pp.145-151
    • /
    • 2002
  • Thermoplastic starch(TPS) was prepared from mixing starch and glycerol by twin extruder. The blends were then prepared from high density polyethylene(HDPE) and TPS. Mechanical properties, thermal properties, and morphology of the blends were investigated. Their biodegradability was also studied by using aerobic composting method(ISO14855). Tensile strength, modulus and elongation at break decreased as the content of TPS increased. In particular elongation at break decreased rapidly even at the lower content of TPS. The melting temperatures of the blends were not changed, which showed that HDPE and TPS were immiscible. The morphology of the fractured surface of blend films was investigated by scanning electron microscopy(SEM). It was found that phases were separated. After composting for 45days, the biodegradability of the blends increased as the content of TPS increased.

A Stduy of Design and Simulation for 3Dimension Fashion (3차원 의상 설계 시뮬레이션에 관한 연구)

  • Kim, Ju-Ri;Lee, Hyun-Chang
    • Proceedings of the Korean Society of Computer Information Conference
    • /
    • 2010.07a
    • /
    • pp.23-26
    • /
    • 2010
  • In this paper, we propose a new method for the design and implementation of a web-based 3D fashion shopping mall. Web 3D shopping mall is implemented by using a Web3D authoring tool, ISB, which provides easy mouse operation. 3D human models and cloth item model are designed by low polygon modeling method of 3D MAX. The designed 3D human models and cloth item model are exported to XML file. Finally, 3D human models and cloth item model are displayed and animated on the Web by using ActiveX control based on DirectX. We also implemented textile palette and mapped it to clothes model by using alpha blending during simulation.

  • PDF

Characteristics and Pot Test according to Blending of PVA/Algin (PVA와 Algin의 블렌딩에 따른 특성과 토양분해)

  • Cho, Hyung-Jae;Oh, Se-Young;Lee, Ki-Chang;Jung, Duck-Chea;Kim, Yong-Yeul;Hwang, Seong-Hee
    • Journal of the Korean Applied Science and Technology
    • /
    • v.16 no.1
    • /
    • pp.25-31
    • /
    • 1999
  • Algin is known as biodegradable natural polymer from marine plants. PVA/Algin blend films were prepared by solution blending method for the purpose of useful biodegradable polymer. Characteristics properties of PVA/Algin blend films such as DSC, Elongation, Tensile strength and Morphological change by SEM were determined. Tensile strength and Elongation were rapidly reduced as increasing the blend ratio of Algin. PVA/Algin blend films were found that phase separation was occured as more than 25wt% increasing the blend ratio of Algin. Blend films were observed to be less partially compatibility than 10wt% increasing the blend ratio of Algin by DSC, mechanical properties and SEM. Also, PVA/Algin blend films at the laboratory soil test(Pot Test) were completely degraded in months with four kinds of soils by microorganisms.

A Study on Friction-induced Surface Fracture Behaviors of Thermoplastic Polyurethane (TPU)/Rubber Blends (열가소성 폴리우레탄 (TPU)/고무 블렌드의 마찰에 의한 표면 파괴 거동)

  • Jeon, Jun-Ha;Park, Sang-Min;Um, Gi-Yong;Bea, Jong-Woo
    • Journal of Adhesion and Interface
    • /
    • v.14 no.3
    • /
    • pp.121-127
    • /
    • 2013
  • In this work, the thermoplastic polyurethane (TPU) was melt-blended with EPDM, NBR and BR to form TPU/Rubber blend films, their composition and friction-induced surface fracture relationship was investigated. TPU/EPDM and TPU/BR blends exhibited the improved friction-induced surface fracture, especially the effect of BR was excellent. With addition of more than 10 wt% BR, TPU/BR blends exhibited the improved friction-induced surface fracture. The increase of the soft segment with increasing BR content, which was confirmed by scanning electron microscopy (SEM) analysis enabled us to estimate the improved friction-induced surface fracture.