• Transactions of the Korean Society of Mechanical Engineers
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• v.19 no.6
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• pp.1501-1509
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• 1995

It is known that the heat and mass transfer characteristics in the absorber are most sensitive of the temperature boost of all the heat exchangers and the development of a more efficient absorber should be highly important. This paper describes absorption experiments made with different inside tube diameters, tube length and tube shapes. The purpose of this study is to acquire basic knowledge about heat and mass transfer in a falling film type absorber with vertical inner tubes. Heat and mass transfer were measured for water vapor absorption into a Lithium Bromide-water solution flowing down an absorber of vertical inner tubes. As a result, insert spring tube compares bare tube and heat transfer improved by order of insert spring tube P2(pitch 20 mm) and P1(pitch 10 mm).

• Transactions of the Korean Society of Mechanical Engineers
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• v.19 no.1
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• pp.231-239
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• 1995

This paper describes a computer simulation of the triple effect, water-lithium bromide absorption cooling cycles. The performance of the absorption systems is investigated through cycle simulation to obtain the system characteristics with the cooling water inlet temperature, the working solution concentrations, the ratio of the amount of the weak solution to the high, middle and low temperature generators, and the temperature difference of each solution heat exchanger. The efficiency of different cycles has been studied and the simulation results show that higher coefficient of performance could be obtained for the parallel cycle of constant solution distribution rate. As a result of this analysis, the optimum designs and operating conditions were determined based on the operating conditions and coefficient of performance.

• Journal of the Korean Society of Marine Environment & Safety
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• v.13 no.4
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• pp.51-54
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• 2007

Surfactants can be used as a cosmetics and chemical dispersants. The variation of critical micelle concentration(CMC) with temperature for hexadecyl pyridinium bromide over the range $40^{\circ}C$ to $60^{\circ}C$ has been measured by drop methods. Thermodynamic quantities for micellization of hexadecyl pyridinium bromide in water have been calculated by polynominal equation.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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• v.33 no.3
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• pp.29-32
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• 2004

이중효용 흡수냉동기의 고효율화 방안과 당사(한국 캐리어)에서 개발한 흡수식 냉동기를 소개 하고자 한다. 흡수냉동기는 1777년 영국의 NAIRNE에 의해 흡수냉동기 이론을 발표한 이후 1945년 미국 CARRIER사가 냉매로서 물, 흡수제로서 리튬브로마이드(LiBr)를 이용한 일중 효용 흡수냉동기가 세계 최초로 상용화되면서 공조용 및 산업용 냉방기기로서 보급되기 시작하였다. 이러한 흡수식 기술은 일본에서 이중효용 흡수냉동기 및 냉온수기를 개발하면서 공조용 및 산업용 냉. 난방기기로서 널리 보급되기 시작하였으며, 최근에는 고 효율 이중효용 흡수냉동기 및 냉온수기(COP 1.2-l.3)를 개발하여 제작. 판매하고 있으며 또한 삼중효용 흡수냉온수기(COP 1.6)를 개발하고 있다. 그리고 세계 흡수냉동기 시장은 일본 및 중국을 중심으로 고 효율 흡수냉동기 시장으로 재편되고 있다. 그러나, 우리나라에는 아직 일본기술에 의존한 표준 COP 이중효용 흡수냉동기 및 냉온수기(COP 1.01)를 제작 판매하고 있는 실정이다. 따라서 본 고에서는 이중효용 흡수냉동기의 고효율화 방안과 당사(한국 캐리어)에서 개발한 흡수식 냉동기를 소개하고자 한다.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.4 no.4
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• pp.332-341
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• 1992

An absorption heat pump cycle has been modeled and simulated to analyze the system performance of water-cooled, series-flow, double-effect absorption heat pump, which can be applied to a direct gas fired cooling system with the medium range of cooling capacity (15RT level). Effect of absorption cooling system parameters, such as concentration difference, inlet temperature of cooling water, 1st generator temperature, leaving temperature differences of condenser and evaporator and efficiency of solution heat exchanger, has been investigated in the view of system cooling performance.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.8 no.2
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• pp.288-298
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• 1996

The gas-fired absorption refrigeration system to utilize treated sewage is available for environmental protection and energy conservation. Simulation analysis on the double-effect absorption refrigeration cycles with parallel or series flow type has been performed. The working fluid is Lithium Bromide and water solution. The main purpose of this study is evaluating the possibilities of effective utilization of treated sewage as a cooling water for the absorber and condenser. The efficiency of a couple of cycles has been studied and simulation results show that higher coefficient of performance could be obtained for parallel flow type. The other purpose of the present study is to determine the optimum designs and operating conditions based on the operating constraints and the coefficent of performance in the paralledl flow type.

• Journal of the Korean Chemical Society
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• v.16 no.5
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• pp.284-289
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• 1972

Rates of the reactions of m-and p-ring-substituted thiobenzamides with benzyl bromide in acetone have been determined by an electric conductivity method. The Hammett rule has been adopted for these reactions. It has been observed that an electron-attracting substituent accelerates the reaction while an electron-donating substituent retards the reaction, and a mechanism which accounts for the observed kinetics has been postulated. The activation energies and entropies of activation for these reactions have also been calculated.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.20 no.2
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• pp.670-679
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• 1996

A numerical study for vapor absorption into LiBr-H$_{2}$O solution film flowing over horizontal circular tubes has been carried out. The momentum, energy and diffusion equations, which are parabolized by the boundary- layer approximation, are solved simultaneously for various mass-flow rates and inlet conditions. The results for the velocity, temperature and concentration fields, as well as the heat and mass flux at the free surface are presented. The effects of inlet conditions, i.e., flow rate, temperature and concentration, on the absorption process are also examined and discussed.

• Journal of the Korean Graphic Arts Communication Society
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• v.19 no.1
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• pp.17-27
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• 2001

플라티늄포르피린 핵과 주위에 8, 16, 32 그리고 64 개의 벤질 단위를 갖는 새로운 덴드리머를 압력 감지형 페인트에 사용할 발광체로 합성하였다. 플라티늄포르피린 핵을 갖는 제 1 세대의 덴드리머는 Lindsey형 합성법을 이용하여 제조하였으며, 제 2 세대에서 제 4 세대까지의 플라티늄포르피린 핵을 갖는 덴드리머는 플라티늄 테트라키스(3,5-디히드록시페닐)포르피린을 적합한 덴드론 브로마이드와 Williamson 에테르 합성법에 따라 알킬화반응시켜 제조하였다. 이러한 에테르 연결의 생성 반응들은 $K_2$CO$_3$와 18-크라운-6를 사용하여 아세톤 용매에서 질소 기류 하에서 6$0^{\circ}C$에서 수행하였을 때 가장 좋은 결과를 주었다. 그리고 이렇게 합성한 덴드리머들을 $^1$H-NMR, $^{13}$C-NMR, Mass spectrum 이용하여 구조를 확인하고, 그리고 UV-VIS spectroscopy를 이용하여 분광학적인 특성을 조사하였다.

• Journal of the Korean Society of Marine Environment & Safety
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• v.14 no.2
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• pp.145-148
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• 2008

Cationic surfactant can be used as cosmetics and chemical dispersants. The variation of critical micelle concentration (CMC) with temperature over the range $40^{\circ}C$ to $60^{\circ}C$ for N-octadecyl pyridinium bromide was measured by drop methods. Thermodynamic quantities such as free energy, enthalpy, entropy and heat capacity for micellization of N-octadecyl pyridinium bromide in water were calculated by fourth-degree polynominal equation In the result, free energy change was decreased generally by the increment of temperature.