• Economic and Environmental Geology
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• v.34 no.2
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• pp.167-173
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• 2001

Through alkaline hydrothermal activation processes, Na-A type zeolite was synthesized as a single phase with funnel-glass waste from a television tube factory. The autoclaving was performed in a closed teflon vessel in the range of 80~95$^{\circ}$C. The silica-rich solution as a starting material was hydrothermally synthesized with quartz in IN NaOH by heating 350uC under the pressure of 1,500 atm. $NaAlO_2$ was made from NaOH and Al(OHh by heating 95$^{\circ}$C for 2-3 hours and the molar ratios of it were $Na_2O/Al_2O_3$ = 1.4 and $H_2O/Na_2O$=8. The equi-dimensional A type zeolite (1-2 11) was formed by the simple mixing of the silica-rich solution, glass waste and $NaAlO_23$ for 1-3 hours-heating at $80^{\circ}C$. The characterization of the reaction product shows Na-A as a single phase. The synthesized zeolite has cuba-dodecahedral form and $Ca^{2+}$ ion exchange capacity of the Na-A was in the range of 215-220 mequiva1entilOO g.

• Journal of the Korean Professional Engineers Association
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• v.34 no.2
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• pp.167-173
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• 2001

Through alkaline hydrothermal activation processes, Na-A type zeolite was synthesized as a single phase withfunnel-glass waste from a television tube factory. The autoclaving was performed in a closed teflon vessel in therange of 80~95"C. The silica-rich solution as a starting material was hydrothermally synthesized with quartz in INNaOH by heating 350"C under the pressure of 1,500 atm. NaA102 was made from NaOH and Al(OH)3 by heating95"c for 2~3 hours and the molar ratios of it were Na20/A1203=1.4 and H20Ha20=8. The equi-dimensional Atype zeolite (1 ~2 U) was formed by the simple mixing of'the silica-rich solution, glass waste and NaA102 for I~3hours-heating at 80"C. The characterization of the reaction product shows Na-A as a single phase. The synthesizedzeolite has cube-dodecahedral form and Ca2+ ion exchange capacity of the Na-A was in the range of 215~220mequivalent/100 g.20mequivalent/100 g.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.1
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• pp.163-170
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• 2019

In recent years, various types of industrial wastes are rapidly increasing with the development of high-tech industries. Specially, high-density waste glass of CRT TV containing heavy metals are buried or disposed of due to reprocessing costs and environmental pollution problems. Thus, more basic research is needed to recycle waste such as CRT waste glass such. In this study, the fundamental properties and radiation shielding performance of mortar specimens substituted CRT waste glass as a fine aggregate were analyzed and their application to shielding materials was evaluated. According to the results, the bulk density of mortar specimen replaced with CRT waste glass was increased and the compressive strength and flexural strength were decreased. Meanwhile, the CRT waste glass substitute specimen containing a large amount of lead component showed a higher shielding performance than the general mortar specimen. Especially, the linear attenuation coefficient of CRT waste glass in $122KeV{\cdot}^{57}Co$ of the low energy field was 2.5 times higher than that of normal specimen.