• Proceedings of the Korean Nuclear Society Conference
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• 1996.05c
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• pp.367-372
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• 1996

석탄화력발전소의 산업부산물인 fly ash를 이용한 폐흡착재의 붕규산유리고화가 능성을 분석하였다. 폐흡착재는 기체상의 세슘이나 루테늄 등을 포집한 후에 발생되는 필터류 등의 고체폐기물을 말하며 본 실험에서는 CsNO$_3$와 fly ash를 몰비로 1.5 : 1 되게 섞어 1200 $^{\circ}C$에서 1시간 가소 시킨 후에 생성되는 pollucite를 모의폐흡 착재로 사용하였다. 폐흡착재를 무게비 15 ~ 30 %로 fly ash, SiO$_2$, $Na_2$CO$_3$, B$_2$O$_3$와 혼합한 후 1150 $^{\circ}C$에서 3시간 용융시켜 붕규산유리화시켰다. 제조된 붕규산유리고화체의 침출성을 평가하기 위하여 2일동안의 soxhlet 침출실험을 수행하였다. 한편 폐흡착재의 붕규산유리고화과정을 알아보기 위하여 붕규산유리고화체의 원료물질에 대하여 유리화과정과 동일한 조건하에서 TG/DTA분석을 수행하였다.

• Applied Chemistry for Engineering
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• v.27 no.4
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• pp.371-379
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• 2016

In this article, the foamed body of glass was manufactured from the waste borosilicate glass produced by wet pulverization process without additional pretreatment which can be used as a recycling method for waste LCD panel glass. Each 100 g of pulverized waste borosilicate glass with the size of less than 270 mesh were mixed with 0.3 weight fraction of carbon and 1.5 weight fraction of $Na_2CO_3$, $Na_2SO_4$ and $CaCO_3$ and let them foamed for 20 minutes at $950^{\circ}C$ to manufacture the foamed body having the density of less than $0.3g/cm^3$. Additionally, adding $SiO_2$ or $H_3BO_3$ to the mixture enabled the foamed body to have efficient formation of open pores which showed the possibility for producing the foamed body with new functionalities such as sound absorption.

• Proceedings of the Korean Nuclear Society Conference
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• 1995.05b
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• pp.781-786
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• 1995

석탄화력발전소 산업부산물인 Fly ash를 이용한 고준위방사성폐기물의 붕규산 유리고화 가능성을 분석하였다. Fly ash SiO$_2$, NaNO$_3$, B$_2$O$_3$에 DUPIC 핵연료 제조공정으로부터 발생되는 모의 scrap waste를 20 wt% 혼합하여, l15$0^{\circ}C$ 에서 3시간 용융시켜 붕규산유리화시켰다. 또한 붕규산유리고화체의 침출성을 평가하기 위하여 2일동안의 soxhlet 침출실험결과 양호한 내침출성을 보였다. 또한 고체폐기물의 안정화물질로 fly ash를 사용할 경우 fly ash 함량을 57%까지 첨가하여도 붕규산유리고화체의 제조가 가능함을 확인하였으며, fly ash의 첨가로 인한 유리화원료 재료비를 30% 까지는 절감시킬 수 있을 것으로 예상된다.

• Journal of the Korean Chemical Society
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• v.41 no.5
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• pp.251-255
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• 1997

Fluorescence spectra and life time of $Eu^{3+}$ ion in borosilicate glass medium are measured. Electronic transitions of $Eu^{3+}$ ion in borosilicate glass medium are found to come from $5D0{\rightarrow}7FJ$(J=0, 1, 2, 3, 4) transitions of SL coupling system in $f^b$ electrons configuration. From the number of Stark sublevels in spetra, crystal field for $Eu^{3+}$ ion is also found to have the symmetric character of low symmetry order, $n{\leq}2$. The fraction and the number of components of life times were varied depending on the composition of $Eu^{3+}$ in borosilicate glasses, from which the binding condition between the $Eu^{3+}$ ion and anionic oxygen of borosilicate glass can be deduced.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.3
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• pp.269-275
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• 2016

In this study, the mechanical properties and the neutron shielding rate of concrete with the borosilicate glass and the amorphous boron steel fiber were investigated. The measures of this investigation includes air contents, slump loss, compressive strength, static modulus of elasticity, compressive toughness, flexural strength, flexure toughness and neutron shielding rate. As a result, the neutron shielding rate of the concrete with borosilicate glasses increased even though the compressive strength and flexural strength decreased in comparison with that of plain concrete. Also, the mechanical toughness and the neutron shielding rate of the concrete with amorphous boron steel fiber increased in comparison with that of plain concrete.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.1 no.1
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• pp.41-46
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• 2003

To understand the long-term leach behavior of a borosilicate Waste glass in a repository, the leaching experiment with three kinds of simulated borosilicate waste glasses has been carried out since the middle of 1997. The five years results indicate that a boron would be applied as an indicator of a long-term leaching of their borosilicate waste glasses and that their long-term leach rates have a tendency to be close to about 0.03g/$m^2$-day even though their compositions and their ratios of the surface area to the volume of leachate are different.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2003.11a
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• pp.266-269
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• 2003

To understand the long-term leach behavior of a borosilicate waste glass in a repository, the leaching experiment with three kinds of simulated borosilicate waste glasses has been carried out since the middle of 1997. The five years results indicate that a boron would be applied as an indicator of a long-term leaching of their borosilicate waste glasses and that their long-term leach rates have a tendency to be close to about $0.03g/m^2-day$ even though their compositions and their ratios of the surface area to the volume of leachate are different.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2002.05a
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• pp.157-158
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• 2002

유해폐기물 및 모의 방사성폐기물 소각재에 붕규산유리 계통의 기본유리매질을 혼합하여 고온에서 용융시켜서 제조한 유리 고화체를 대상으로 침출실험후의 미세구조 및 표면조성의 변화, 침출된 시료의 표면에서 고화매질 성분별 함량과 두께에 따른 농도 기울기 및 결정질 화 등을 평가하여 유리고화체의 침출거동에 따른 표면변화 특성을 고찰하였다.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.11a
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• pp.155-156
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• 2017

Borosilicate glass was incorporated to improve the neutron shielding capability of concrete. Boron is a typical neutron shielding material, and it is contained in borosilicate glass. However, borosilicate glass causes alkali-silica reaction, which damages the concrete. Therefore, studied to reduce the expansion due to alkali-silica reaction and to improve the neuton shielding capability. The measurement of the expansion due to the alkali-silica reaction was based on ASTM C 1260. Experimental results show that the expansion due to alkali-silica reaction is reduced when borosilicate glass powder incorporated. In addition, the neutron shielding capability was significantly improved when the fine aggregate replaced with borosilicate glass.

• Applied Chemistry for Engineering
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• v.27 no.6
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• pp.612-619
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• 2016

In this research, an alumino-borosilicate foamed glass with sound absorption property was prepared using the waste borosilicate glass obtained from the recycling process of waste liquid crystal display (LCD) panel. A 100 g of pulverized waste borosilicate glass with the particle size of under 325 mesh, was mixed with 0.3 g (wt/wt) of graphite, each 1.5 g (wt/wt) of $Na_2CO_3$, $Na_2SO_4$ and $CaCO_3$ as a foaming agent, and 6.0 g (wt/wt) of $H_3BO_3$ and 3.0 g (wt/wt) of $Al_2O_3$ as a pore control agent. Following mixture was under the foaming process for 20 minutes at a foaming temperature of $950^{\circ}C$. The result yielded the foaming agent with 45% of the opened porosity and 0.5-0.7 of the sound absorbing coefficient. This alumino-borosilicate foamed glass with the sound absorption property showed excellent physical and mechanical properties such as density of $0.21g/cm^3$, bending strength of $55N/cm^2$ and compression strength of $298N/cm^2$ which can be ideally used as sound absorption materials with heat-resisting and chemical-resisting property.