• Analytical Science and Technology
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• v.25 no.6
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• pp.382-387
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• 2012

Ethylene oxide ($C_2H_4O$, EtO) is used as a raw material for the production of ethylene glycol and other industrially important material such as ethanolamines and also used as a disinfecting agent. It is applied for gas-phase sterilization of thermally sensitive medical equipment, and for processing of storage facilities as a mixture with fluorinated hydrocarbon. In this perspective, accurate determination of the mole fractions of components in the liquefied gas mixture is required for the quality control and safety of production and use. Each component of the liquefied gas mixture has different chemical and physical properties such as vapor pressure and boiling point. Therefore, we can suppose that analytical results can be different according to the introduction method for the gas phase of upper layer, or for the liquid phase of lower layer in gas cylinder. In this study, we designed a new on-line sample injection device for the liquefied gas mixture in liquid or gas state, and applied to the analysis of liquefied gas mixture of ethylene oxide and fluorinated hydrocarbons by GC/AED (gas chromatograph-atomic emission detector). We studied performance of AED, and effect of sample introduction and selected wavelength to the accuracy and repeatability of analytical results.

• Applied Chemistry for Engineering
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• v.16 no.3
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• pp.379-384
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• 2005

Polyurethane foams (PUFs) were prepared from polymeric 4,4'-diphenylmethane diisocyanate (PMDI), seven polyols with different functionalities and OH values, silicone surfactant, two catalysts, and three blowing agents. Chlorofluorocarbon (CFC-11), hydrochlorofluorocarbon (HCFC-141b) and hydrofluorocarbon (HFC-365mfc) were used as blowing agents. The effect of gelling and blowing catalysts on basic properties and cell structure of PUF with HCFC-141b was investigated. The cell size of the PUF decreased with an increase in the amount of catalyst from 0 to 2 pph (parts per hundred polyol). In the case of gelling type catalyst, the compressive strength increased from 11.9 to $12.66kg_f/cm^2$ with an increase in the amount catalyst from 0 to 2 pph but the density did not change significantly. The gelling time, density, and compressive strength of the PUF with three different blowing agents were measured. There was no detectable change in their properties. However, the cell structure of PUF with HCFC-141b was not uniform as in the other systems.

• Proceedings of The Korean Society of Agricultural and Forest Meteorology Conference
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• 2001.06a
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• pp.167-170
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• 2001

대기오염 물질 중에는 아황산가스(SO$_2$), 산화질소(NOx), 불화수소(HF), 탄화수소(HC), 오존 (O$_3$)등 여러 가지 종류가 있으나 이러한 대부분의 대기오염 물질들은 식물체내에 흡수되어 세포내에서 활성산소(activated oxygen)를 발생시키게 되는데 이때 발생되는 활성산소에는 superoxide radicals(O$_2$), 과산화수소($H_2O$$_2$), 수산기(OH$^{-}$) 및 singlet oxygen(O$_2$) 등으로 생리적, 생화학적 과정 및 세포내의 구조조직에 부정적인 영향을 미치게되어 식물의 생장을 감소시킨다.(중략)

• Microbiology and Biotechnology Letters
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• v.17 no.1
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• pp.51-55
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• 1989

The conjugally transferred TOL plasmid or NAH plasmid was stably maintained and expressed in n-alkane assimilating Pseudomonas putida KCTC 2405. However, these plasmids were not able to coexist in this strain because of incompatibility. The incompatibility of TOL and NAH plasmid was bypassed using CAM::TOL* plasmid, which was constructed by the transposition of only tol gene without incompatibility system in TOL plasmid into CAM plasmid. p. putida 3SK capable of growing on m-toluate, naphthalene, camphor, and n-alkane(C8-C24) was constructed by the conjugal transfer of NAH plasmid into n-alkane assimilating p. putida SK carrying CAM:: TOL* plasmid. CAM::TOL＊ plasmid in p. putida 3SK was stable on the selective media but unstable on the nonselective media.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.3
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• pp.258-266
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• 2000

Experimental investigation and cycle simulation of a capacity modulation of a heat pump system using a hydrofluorocarbon (HFC) refrigerant mixture, R32/134a as an alternative to R22, have been done. In the cycle simulation, the refrigeration system was operated by assigning the temperatures of the external heat transfer fluids with the heat exchangers generalized by an average effective temperature difference. Heating capacity, cooling capacity, and coefficient of performance (COP) of the system were investigated at several operating conditions. Experimental apparatus which had a refrigeration part and a composition changing part was built, and the performance of the heat pump system filled with R32/134a mixture was investigated. A gas-liquid separator was used in the experiment to change the composition by collecting the vapor and the liquid Phase separately, The mass fraction of the charged refrigerant in the heat pump system was 40/60 and 70/30 by weight percentage. The composition of the refrigerant with initial composition of 40/60 varied from 29/71 to 41/59 in the refrigeration cycle. For the refrigerant with initial composition of 70/30, the composition varied from 65/35 to 75/25.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.17 no.12
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• pp.1132-1138
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• 2005

Recently, production and use of freon substances are restrained due to depletion of ozone layer and global warming. In this aspect of environmental problems, the best solution is to use the natural refrigerant such as ammonia. Thus, this study is to find the optimal operating conditions by comparing the performance between the shell and tube type and shell and disk type heat exchangers using the ammonia refrigerant, and to verify the superiority of the shell and disk type heat exchanger that is not used in field of refrigeration and air conditioning. Finally, this study shows that the shell and disk type heat exchanger is applicable to the ammonia refrigeration system, and this system minimizes the refrigerant charge and installation space.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.17 no.4
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• pp.297-302
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• 2005

Since the use of CFC and HCFC refrigerants are to be restricted due to the depletion of ozone layer, this experiment applies the $NH_3$ gas to study the performance characteristics of $NH_3$ refrigeration system by the superheat control for improving the energy efficiency. The experiments are carried out for the condensing pressure of refrigeration system from 1,500 kPa to 1,600 kPa and for degree of superheat from $0^{\circ}C\;to\;10^{\circ}C$ at each condensing pressure. As a result of experiment, when the degree of superheat is $0^{\circ}C$ at each condensing pressure, the refrigeration system has the highest performance.

• Proceedings of the SAREK Conference
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• 2006.06a
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• pp.495-500
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• 2006

Nowadays HCFCs refrigerant are restricted because it cause depletion of ozone layer. However, natural gases such as ammonia as an organic compound, propane and propylene as hydrocarbon are easy and cheap to obtain as well as environmental. Accordingly, this experiment apply the $NH_3$ and R22 to study the performance characteristic from the superheat control and compare the energy efficiency of two refrigerants from the high performance. The condensing pressure of refrigeration system is increased from 15bar to 16bar and degree of superheat is increased from 0 to $10^{\circ}C$ at each condensing pressure. As the result of experiment, when comparing the each COP, we knew the $NH_3$ is suitable as the alternative refrigerant of the R22.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.18 no.5
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• pp.377-383
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• 2006

Recently, production and use of Freon substances are restrained due to destruction of ozone layer and grobal warming. In this aspect of environmental problems, the best solution is to use the natural refrigerant such as ammonia. Thus, this study apply the $NH_3$ and R22 to study the performance characteristic from the superheat control and compare the energy efficiency of two refrigerants from the high performance. The condensing pressure of refrigeration system is increased from 1,500 kPa to 1,600 kPa and degree of superheat is increased from 0 to $10^{\circ}C$ at each condensing pressure. As the result of experiment, when comparing the each COP, we knew the $NH_3$ is suitable as the alternative refrigerant of the R22.

• Analytical Science and Technology
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• v.30 no.5
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• pp.240-251
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• 2017

1,1,1,2-Tetrafluoroethane (HFC-134a), which is used as refrigerant in air conditioners, has been recently regulated as a greenhouse gas and is recommended for reuse by refining. It is very important to quantitatively analyze trace impurities present in the refrigerant to evaluate the criteria for reuse. In this study, trace impurities including C, H, Cl, and F, which are difficult to quantify because there are no reference materials, were quantitatively analyzed by a gas chromatograph-atomic emission detector (GC/AED); for this analysis, this was preceded by a qualitative analysis with a GC-mass selective detector (GC/MSD). In addition, the AED response was investigated using a hydrocarbon mixed reference material, which was proportional to the number of atoms in the component. Fifteen refrigerant components were detected as trace impurities in HFC-134a by qualitative analysis of trace impurities including C, H, Cl, and F in the samples. Based on the results of the qualitative analysis, quantitative analysis of trace impurities using AED showed that the highest mole fractions were for the $CHClF_2$ component ($45438.38{\mu}mol/mol$) in one sample and for the $C_2H_2ClF_3$ component ($1311.47{\mu}mol/mol$) in another sample. From this study, it has been shown that it is possible for this analytical method to be applied to the qualitative and quantitative analysis of trace compounds in refrigerants, which are difficult to quantify because of the absence of reference materials.