• Proceedings of the Korea Air Pollution Research Association Conference
• /
• 1997.04a
• /
• pp.73-74
• /
• 1997

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.12 no.3
• /
• pp.315-324
• /
• 2000

R-410A, R-407C, and four refrigerant mixtures composed of R-32, R-l34a, R-l43a, R-l52a, R-600(butane), and R-600a(isobutane) were tested in an attempt to replace R-22 used in most of the residential air conditioners. The performance evaluation was carried out in a psychrometric calorimeter test facility using a residential spilt type air conditioner under the KS rating conditions. Except for the lubricant and hand-operated expansion valve, the other parts of the air conditioner were the same with the commercial system. Performance characteristics were measured; COP, capacity, compressor power, and VCR. R-410A was shown to have 5.5% higher COP and 3.5% lower capacity than R-22. R-32/134a/600a (42.8/ 46.0/11.2 wt%) mixture have the best performance among the four refrigerant mixtures composed of hydrofluorocarbon and hydrocarbon. This inixture have 3.0% lower COP and 1.6% lower capacity than R-22.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.12 no.11
• /
• pp.1031-1037
• /
• 2000

Isothermal vapor-liquid equilibrium(VLE) data have been obtained for the systems of propane(R290)+1,1,1,2-tetrafluoroethane(R134a) and 1,1,1,2-tetrafluoroethane(R134a)+isobutane(R60A) in the temperature range of 253.15 to 323.15K. Experiments were performed in a circulation type apparatus by injecting vapor through liquid pool using a magnetic pump. Both systems form azeotropes in the temperature range of this study. The experimental results were estimated with the Peng-Robinson equation of state. When the temperature-dependent binary interaction parameter was used in the Peng-Robinson equation of state, the absolute average deviation of the measured bubble point pressures from the values correlated by the Peng-Robinson equation was 0.65% and 0.78% for R290+R134a and R134a+600a, respectively. Azeotropic compositions for both systems were presented.

• Proceedings of the Korea Air Pollution Research Association Conference
• /
• 1999.10a
• /
• pp.94-95
• /
• 1999

불소나 염소가 수소대신에 치환 되어있는 활로겐화 화합물인 염화불화탄화수소(CFCs chlorofluoro carbons)는 오존층 파괴물질 그리고 지구온난화 기체물질로 널리 알려져있다. 이러한 CFCs는 Mauna Loa, Niwot Ridge, South Pole과 같은 지구배경농도지역에서 70년대 후반부터 지속적으로 측정되어 오고 있다. 대기중 CFCs농도는 일반적으로 수백 ppt 수준으로 매우낮아 측정이 매우 어려운 것으로 알려져왔다.(중략)

• Clean Technology
• /
• v.14 no.3
• /
• pp.184-192
• /
• 2008

Fluoride-type cleaning agents such as 2,2,2-trifluoroethanol (TFEA) and hydrofluoroethers (HFEs) do not destroy ozone in the stratosphere and have low global warming potential compared to hydrofluorocarbons(HFCs) and hydrochlorofluorocarbons (HCFCs). Especially, HFEs which have no flash point are paid attention as next generation type of cleaning agents for chlorofluorocarbons (CFCs) since they are safe in handling and have excellent penetration ability compared to hydrocarbon cleaning agents with low flash point. Here, the physical properties and cleaning abilities of fluoride-type cleaning agents such as TFEA, HFE-7100, HFE-7200, HFE-476mec, HFE-449mec-f, AE-3000 and AE-3100E and silicide-type cleaning agents such as trifluoroetoxytrimethylsilane (TFES) and hexamethyldisilazane (HMDS) were measured and compared with those of ozone destruction substances such as CFC-113 and 1,1,1-trichloroethane. They were also compared with toxic methylene chloride (MC) and isopropyl alcohol (IPA) which are now being used as an alternative cleaning agents. As a result, TFEA and HFEs had lower cleaning ability for removal of various soils compared to chloride-type cleaning agents, but they showed excellent cleaning ability fur fluoride-type soils. TFES and HMDS also showed excellent cleaning ability for silicide-type soils.

• Membrane Journal
• /
• v.27 no.5
• /
• pp.389-398
• /
• 2017

The most important characteristic of the polymer electrolyte membranes (PEMs) for fuel cells, the proton conducting ability is mainly influenced by the distribution and morphology of the water channels inside the PEMs. Non-perfluorinated hydrocarbon PEMs are known to have weaker water channels than perfluorinated PEM, Nafion, and thus relatively low proton conducting ability. In this study, we used a mesoscale simulation technique to observe the water channel formation and phase separation behavior of hydrocarbon PEM, sulfonated polyimides, under the humidification condition. It was observed that the water molecules were distributed evenly through the entire hydrophilic region, and clear water clusters were formed only in the sulfonated polyimide having high sulfonation degree. In addition, it was observed that sulfonated polyimides have a difficulty in forming water channel under the low hydrated condition. These results clearly support the theories of the formation of water channels in non-perfluorinated hydrocarbon PEMs, and also well explain the tendency of proton conducting abilities of sulfonated polyimides. Thus, it is confirmed that mesoscale simulation techniques can be very effective in analyzing phase separation behavior and water channel formation in PEMs for fuel cells and elucidating the ion conducting abilities.

• Proceedings of the KSME Conference
• /
• 2004.11a
• /
• pp.1276-1281
• /
• 2004

Nowadays CFCs and HCFCs refrigerants are restricted because it cause depletion of ozone layer. Accordingly, this experiment apply the ammonia gas and not CFCs and HCFCs for refrigerant to study the performance characteristic from the superheat control and improve the energy efficiency from the high performance. The condensing pressure of refrigeration system is increased from 15.0bar to 16bar by 0.5bar and superheat temperature is increased from $0^{\circ}C$ to $10^{\circ}C$ by $1^{\circ}C$ at each condensing pressure. As the result of experiment, when the superheat temperature is $0^{\circ}C$ at each condensing pressure, the refrigeration system has the high performance.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.16 no.8
• /
• pp.756-761
• /
• 2004

Since the use of CFC and HCFC refrigerants are to be restricted due to the depletion of ozone layer, this experiment applies the NH$_3$ gas to study the performance characteristics from the superheat control for improving the energy efficiency. The experiments are carried out for the condensing pressure of refrigeration system from 14.5 bar to 16.0 bar by 0.5 bar and for superheat temperature from $0^{\circ}C$ to 1$0^{\circ}C$ by 1$^{\circ}C$ at each condensing pressure. As a result of experiment, when the superheat temperature is 1$^{\circ}C$ at each condensing pressure, the refrigeration system has the highest performance.

• Proceedings of the KSME Conference
• /
• 2004.04a
• /
• pp.1334-1339
• /
• 2004

Nowadays CFCs and HCFCs refrigerants are restricted because it cause depletion of ozone layer. Accordingly, this experiment apply the $NH_3$ gas and not CFCs and HCFCs for refrigerant to study the performance characteristic from the superheat control and improve the energy efficiency from the high performance. The condensing pressure of refrigeration system is increased from 14.5bar to 16bar by 0.5bar and superheat temperature is increased from $0^{\circ}C$ to $10^{\circ}C$ by $1^{\circ}C$ at each condensing pressure. As the result of experiment, when the superheat temperature is $1^{\circ}C$ at each condensing pressure, the refrigeration system has the high performance.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.15 no.7
• /
• pp.563-571
• /
• 2003

The forty vapor-liquid equilibrium data of the binary system, HFC125＋Propane, were measured between 273.15 and 313.15 K at 10 K interval and the composition range 0.2∼0.75, respectively. Experiments were performed in a circulation type apparatus in which the vapor phase was forced through the liquid phase. The composition at equilibrium were mea-sured by gas chromatography, and its response was calibrated using gravimetrically prepared mixtures. Vapor-liquid equilibrium data were calculated by using CSD equation of state and compared with the experimental data.