• Title/Summary/Keyword: 분해 영향 인자

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Effect of Operation Conditions on Pyrolysis of Larch Sawdust in a Bubbling Fluidized Bed (기포유동층 반응기를 이용한 낙엽송 톱밥의 열분해 특성)

  • Yoo, Kyung-Seun;Eom, Min-Seop;Lee, See Hoon
    • Applied Chemistry for Engineering
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    • v.27 no.5
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    • pp.478-482
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    • 2016
  • In this study, a bubbling fluidized bed pyrolyzer (0.076 m I.D. and 0.8 m high) was employed to investigate the fast pyrolysis characteristics of larch sawdust which is abundant in Korea. The effects of operation conditions, such as bed temperature ($350-550^{\circ}C$), fluidization velocity ratio ($U_o/U_{mf} $: 2.0-6.0) and feeding rate (2.2-7.0 g/min) on product yields and their chemical components were studied. The number of chemical compounds in the bio-oil decreased with the increasing bed temperature because of secondary pyrolysis. The effects of the Uo/Umf ratio and feeding rate on bio-oil compositions were relatively lower than those of the bed temperature.

Effect of Oxygen and Moisture on Stabilization of Municipal Solid Wastes in Landfill (폐기물매립지에 있어서 산소와 수분이 매립폐기물의 안정화에 미치는 영향)

  • Kim, Hye-Jin;Lee, Nam-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.14 no.1
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    • pp.139-150
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    • 2006
  • Landfilling is one of the most widely used methods for the final disposal of solid wastes. Landfilled wastes are degraded by residing microorganisms and the microbial degradation is affected by many factors such as moisture, oxygen, pH, alkalinity, sulphate, nutrient, temperature, and so on. Especially among these factor, oxygen and moisture within aerobic landfill play a major role in microbial degradation. In this study, 1) the effects of oxygen on the velocity of waste degradation and 2) the effect of moisture on the degradation of municipal solids waste (MSW) in aerobic condition were investigated. It was found that the BOD and CODcr concentration from the leachate of aerobic lysimeters dropped faster by 80 days after the start of the test compared to those from the anaerobic lysimeters. To see the effect of moisture, four aerobic lysimeters filled with MSW and four different levels of moisture (20, 30, 40, and 50%) were installed. From this test, higher moisture in MSW produced higher $CO_2$ concentration, meaning moisture was effective for the microbial degradation. thus, we concluded that higher moisture level in the aerobic landfill might help early-stabilization microbial degradation.

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A Study on the Soybean Curd(Tofu) made from Defatted Soybean Flour (탈지 대두분을 이용하여 제조한 두부의 품질 특성에 영향을 미치는 인자)

  • Kim Jin-Hee;Woo Eun-Yeol;Kim Kang-Sung;Kim Myung-Hee
    • The Korean Journal of Food And Nutrition
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    • v.19 no.1
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    • pp.22-27
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    • 2006
  • This study was carried out to determine the optimum conditions for making soybean curd(or tofu) from defatted soybean flour.. Heating soymilk above $80^{\circ}C$ for at least $5{\sim}10\;min$ was necessary for soybean protein to form aggregates during subsequent coagulation process with glucono-${\delta}$-lactone(GDL). For maximum yield of tofu, with water content of approximately 80%, extra addition of 20 g of oil and 5 g of GDL per 425 g of soybean flour was needed. Maintaining soymilk temperature around $75^{\circ}C$ for 5 min was necessary when GDL was used as the coagulant.

Influence of soil organic matter and moisture on the persistence of the herbicide mefenacet in soils (제초제 Mefenacet의 토양 중 분해에 미치는 토양유기물과 토양수분에 의한 영향)

  • Kim, Sung-Min;Cho, Il-Kyu;Kyung, Kee-Sung;Lee, Jae-Koo
    • The Korean Journal of Pesticide Science
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    • v.7 no.3
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    • pp.182-187
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    • 2003
  • In order to elucidate a degradation characteristics of herbicide mefenacet in soil, the persistence in soils was studied under laboratory conditions for $90\sim120$ days at $28^{\circ}C$. Mefenacet residues were determined from the two soils which pre-treated by sterilization and flooding, respectively. Non-sterilized upland soil was used as a control. When 70 days elapsed from application time, $55\sim63%$ of mefenacet applied were dissipated in control soils. However, $32\sim33%$ of mefenacet applied were dissipated in the sterilized soils and $33\sim35%$ was dissipated in the flooded soils. 까 lese results indicated that the degradation of mefenacet was assumed to be due to microorganism, especially aerobic microbes. In order to elucidate the influence of water content on the persistence of mefenacet in soil, water content in soils was adjusted to 20, 50, and 80% of the water-holding capacity(Field capacity, WHC). The half-life of mefenacet in soil containing 20% and 50% of WHC were 82 and 73 days, respectively, after incubation for 90 days. However, the half-life in soil containing 80% of WHC was shortened to 61 days. These results indicated that degradation of mefenacet in soil was influenced by the activity of soil microorganism, organic matter content and water content.

Predictors of Failed Closure of Patent Ductus Arteriosus with the First Course of Indomethacin in Preterm Infants (미숙아 동맥관 개존에서 인도메타신 1차 투여 후 폐쇄 실패의 예측 인자)

  • Lee, Mong-Young;Lim, Dong-Hee;Park, Kyu-Hee;Ha, Gi-Su;Lee, Jang-Hoon;Choi, Byung-Min;Hong, Young-Sook;Yoo, Kee-Hwan;Lee, Joo-Won
    • Neonatal Medicine
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    • v.17 no.1
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    • pp.75-83
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    • 2010
  • Purpose : This study was performed to determine the predictors of failed closure of a patent ductus arteriosus (PDA) following the first course of indomethacin in symptomatic preterm infants. Methods : Forty three of 43 preterm infants, admitted to the neonatal intensive care unit diagnosed with PDA and treated with indomethacin at the Korea University Medical Center between January 1990 and October 2007, ware studied. The perinatal risk factors affecting the failed closure of PDA were retrospectively assessed. Results : The failed PDA closure group included 16 (37%) out of 43 infants three of whom underwent surgery. The closure group included 27 (63%) out of 43 infants. In the failed closure group, the Apgar scores (1 min, 5 min) were significantly higher (P<0.05) and antenatal steroid administration was significantly lower (P<0.05). In addition, dopamine administration was significantly lower (P<0.05) and the mean postnatal age at diagnosis was significantly lower (P<0.05). Multiple logistic regression for the prediction of failed PDA closure found only antenatal steroid administration (OR 0.092, CI 0,010-0.826, P=0.0331) as an associated factor. Conclusion : In patients with antenatal steroid administration the failed PDA closure rate was significantly lower. Therefore, antenatal steroid administration can be considered as an important factor for the closure of PDA in preterm pregnancies.

STUDY ON KOMPSAT SATELLITE MISSION LIFETIME FACTORS (다목적 실용위성의 임무수명 인자에 대한 연구)

  • 장영근;백명진;최해진
    • Journal of Astronomy and Space Sciences
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    • v.15 no.2
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    • pp.459-473
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    • 1998
  • As the satellite system becomes more complex, the probability of unpredictable failures may be increased due to design inadequacy, experience deficiency, lack of problem recognition. Poor quality control, improper testing, and workmanship fault. Consequently, these problems can lead to the reduction or end of the satellite mission lifetime. This article addresses general satellite failure modes and factors influencing satellite mission life. The mission life factors of LEO sun-synchronous KOMPSAT spacecraft are investigated, in which its mission life is predicted based on these factors. Since the end of mission due to random failures is not predictable, the predictable mission life factors such as power budget, propellant budget, battery charging/discharging cycle, radiation effects payload reliability, single point failure, and redundancy are primarily investigated.

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Hydrological Modeling for Estimation of Runoff in Unmeasured Mountainous Area: Application to the Var Sub-Catchment, France (미계측 산간지역의 유량추정을 위한 수문 모델링: 프랑스 Var 소유역에 적용)

  • Ji Yun Jang
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.256-256
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    • 2023
  • 집중호우는 전 세계적으로 큰 기후변화 문제 중 하나다. 극심한 집중호우의 빈도수는 지구 온난화로 인해 지난 세기 중반 이후부터 점차 증가하고 있으며 그로인한 인적 및 물적인 피해 또한 증가하고 있다. 이러한 손상을 방지하기 위해서는 적절한 설계 홍수량을 계산하는 것이 중요하다. 최근에는 미계측지역의 유출량 추정 시 분포형 강우-유출 모델을 이용한다. 분포형 모델의 가장 큰 장점은 소유역의 분할 과정을 거칠 필요 없이 유역에서 무작위 점의 유출을 시뮬레이션 할 수 있다는 것이다. 본 연구에서는 2000년 11월 니스에 발생했던 강우를 기반으로 Var 유역의 소유역이자 미계측 지역인 프랑스 니스의 Ubac Vallone의 유출량 및 유출계수를 지형 데이터 등의 물리적 인자와 분포형 강우-유출모델인 MIKE SHE를 이용하여 추정하였다. 또한, 입력되는 인자의 상대적 중요성을 파악하기 위해 민감도 분석을 수행하였다. 본 연구에서는 각 인자에 대한 상대민감도 분석을 바탕으로, 유출량에 상대적으로 큰 영향을 미치는 인자를 제안하였다. 연구 결과, 50년, 100년 및 162년 빈도별 확률강우량에 따른 유출량을 추정하였으며, 162년의경우 총 유출량은 124,384.8m3, 최대 유출량 1.512m3/s, 유출계수 0.53으로 나타났다. 총 유출량과 첨두유량에 대한 상대 민감감도 분석 결과, 수리전도도가 1.5로 첨두유량과의 민감도가 높게 나타났으며, 대수층의 수평방향 수리전도도는 0.48로 총 유출량과의 민감도가 높게 나타났다

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A Study of Influence Factors for Immobilizing Heavy Metals in Contaminated Soil (중금속으로 오염된 토양의 고정화 영향인자에 관한 연구)

  • Hwang, An-Na;Na, Seung-Min;Khim, Jee-Hyeong
    • Journal of Soil and Groundwater Environment
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    • v.12 no.4
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    • pp.72-77
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    • 2007
  • Soil contamination by heavy metals was environmental concern due to its effect on human. In this study, monopotassium phosphate $(KH_2PO_4)$ used as phosphate source to remediate the contaminated soil with heavy metals and factors such as reaction time, initial concentration and pH of phosphate solution, species of heavy metal (lead, cadmium, zinc) and particle size were controlled. Heavy metals were removed in the order Pb > Zn > Cd and the maximum effectiveness was achieved for Pb. The removal efficiency of lead was from 95% to 100% and occurred rapidly occurred during 10 minutes. Mechanism of lead immobilization is dissolution of phosphate and the forming of a new mineral with phosphate having extremely low solubility.

Isolation and Identification of Lipolytic Enzyme Producing Pseudomonas sp. OME and Optimization of Cultural Conditions (지방분해효소 생산균 Pseudomonas sp. OME 의 분리 동정 및 배양조건 최적화)

  • Kumar, G.Satheesh;Reddy, T. Kiran;Madhavi, B.;Teja, P.Charan;Chandra, M.Subhosh;Choi, Yong-Lark
    • Journal of Life Science
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    • v.20 no.5
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    • pp.662-669
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    • 2010
  • Lipolytic enzyme-producing bacteria were isolated from edible oil mill effluents on tributyrin agar medium. The shake-flask-scale studies yielded a promising isolate and it was identified as Pseudomonas sp. An OME using various microbiological observations such as cultural, microscopic, and biochemical tests was undertaken and confirmed using PIBWIN bacterial identification software. Lipolytic enzyme production was screened with oils such as sunflower, caster, coconut, tributyrin, and olive. Amongst these, olive oil showed an increased lipase production 6.1 U/ml. In view of the highest lipolytic enzyme production with olive oil, further optimizations were carried out using olive oil as a carbon source. Lipolytic enzyme production was optimized by a conventional 'one variable at a time' approach and the significant factors were further analyzed statistically using response surface methodology (RSM). The effect of physical factors such as incubation time, temperature, initial medium pH, and nutritional factors such as concentration of olive oil and yeast extract were examined for lipase production. Lipolytic enzyme secretion was strongly affected by three variables (incubation time, concentration of yeast extract and olive oil). Therefore, the interaction of these three factors was further optimized using response surface methodology. The optimized conditions of lipase production using response surface methodology yielded a maximum of 9.62 U/ml with optimum conditions for incubation, yeast extract and olive oil concentrations were found to be 48 hr, 0.3 g. and 0.9 ml. respectively.

The Stability of Aspalatone and Aspirin in Buffered Aqueous Solution (완충 수용액중 아스파라톤 및 아스피린의 안정성)

  • 곽혜선;전인구
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1995.04a
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    • pp.130-130
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    • 1995
  • AM, SM 및 ASA는 수용액중에서 겉보기 1차반응에 따라 분해되었으며 보존온도가 높을수록 분해가 촉진되는 온도 의존성을 나타내었다. AM의 분해경로는 pH 1.22 및 pH 7.0 이상에서는 AM$\longrightarrow$ SM $\longrightarrow$ SA의 경로로 주로 분해되었으며 pH 2.01 - 6.08의 범위에서는 AM $\longrightarrow$ASA$\longrightarrow$SA의 경로로 분해되는 양상을 보였다. 또 pH가 분해에 미치는 영향을 pH-rate profile로 나타낸 결과 AM, SM 및 ASA의 최대안정 pH는 각각 4.0, 3.0, 2.0 부근이 있고 이 조건에서의 분해 반감기는 114, 168, 113 hr로 나타났다. 전체적으로 보면 pH 2.0 이하에서는 ASA가 AM 보다 약간 안정한 편이나 pH 2.0-8.0 사이에서는 AM의 분해속도가 ASA보다 현저히 낮았다. 또 AM은 pH 7.0 이상에서, SM은 pH 6.0 이상에서, ASA는 9.0 이상에서 특수염기촉매반응에 따라 분해가 이루어지는 것을 알 수 있었다. 이온강도($\mu$)의 영향으로는 pH 7.0에서 이온강도가 0.115에서 1.0으로 증가할수록 $\mu$$^{1}$2/에 대해 AM의 분해속도정수가 직선적으로 완만하게 감소되었다. 또 완충수용액 중 AM의 가수분해 억제효과를 검토하기 위해 시클로덱스트린류를 첨가하였을 때, $\beta$-시클로덱스트린과 히드록시프로필기-$\beta$-시클로덱스트린은 AM의 분해를 각각 1.6배 및 1.1배 촉진시켜 촉매적으로 작용하였으며 디메칠-$\beta$-시클로덱스트린은 약 3.2배 분해속도를 억제시켜 안정화제로 작용하였다.Zn^{2+}$, soybean trypsin inhibtor에 의해 25~50% 정도, serine proteinase inhibitor인 phenylmethylsulfonyl floride에 의해 80%정도 활성이 억제되는 특성이 있음을 규명하였다.면역환성 (immunoreactivity)이 나타났고 pyramidal cell layer (PCL)와 glia에 SOD-1이 강하게 염색되었다. APT 병용 투여로 상당수의 경련이 일어나지 않은 흰쥐는 해마의 DG에 FRA가 경미하게 염색되었고, PCL에 SOD-1도 경미하게 나타났으나, 경련이 나타난 쥐에서는 KA만을 투여한 흰쥐와 구별되지 않았다. 이상의 APT의 항산화 효과는 KA로 인한 뇌세포 변성 개선에 중요한 인자로 작용할 것으로 사료되나, 보다 명확한 APT의 기전을 검색하고 직접 임상에 응응하기 위하여는 보다 다양한 실험 조건이 보완되어야 찰 것으로 생각된다. 항우울약들의 항혈소판작용은 PKC-기질인 41-43 kD와 20 kD의 인산화를 억제함에 기인되는 것으로 사료된다.다. 것으로 사료된다.다.바와 같이 MCl에서 작은 Dv 값을 갖는데, 이것은 CdCl$_{4}$$^{2-}$ 착이온을 형성하거나 ZnCl$_{4}$$^{2-}$ , ZnCl$_{3}$$^{-}$같은 이온과 MgCl$^{+}$, MgCl$_{2}$같은 이온종을 형성하기 때문인것 같다. 한편 어떠한 용리액에서던지 NH$_{4}$$^{+}$의 경우 Dv값이 제일 작았다. 바. 본 연구의 목적중의 하나인 인체유해 중금속이온인 Hg(II), Cd(II)등이 NaCl같은 염화물이 함유된 시료용액에 공해이온으로 존재할 경우 흡착에 의한 제거가 가능하다. 한편 이같

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