• Title/Summary/Keyword: 분해 영향 인자

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Preparation of Void Latex Particles: Effects of Reaction Parameters on the Mean Particle Diameter and the Solid Content (중공 입자의 제조: 반응 인자가 평균 입자 크기와 고형분 함량에 미치는 영향)

  • Lee, Kee Jeung;Seo, Kyung Won;Mok, Young Il
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.758-762
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    • 1998
  • In preparing void latex particles by emulsion polymerization, the weight mean particle size of which is ranged $0.3{\mu}m{\sim}1.5{\mu}m$, reaction parameters were investigated in order to elucidate their effects on the size distribution and the solid content of emulsion polymer. Experimental results showed that the weight mean particle size of hydrophillic core polymer was reduced as the concentration of sodium dodecylbenzene sulfonate (SDS) increased. The size of void polymethyl-methacrylate-polystyrene composite latex particles became larger as the concentration of styrene monomer and the sodium persulfate increased. However, the size of void latex particles was reduced as the feeding rate of acrylic acid increased. The solid content of emulsion polymer was strongly dependent on the addition of stylene monomer. By increasing the concentration of styrene monomer the solid content of emulsion polymer increased linearly.

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Factors Affecting Microbial Respiration (MR) by Rapid Oxygen Uptake Rate (OUR) Monitoring (급속 OUR 모니터링을 이용한 Microbial Respiration (MR) 영향인자 평가)

  • Park, Se-Yong;Mo, Kyung;Kim, Youn-Kwon;Kim, Moon-Il
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.9
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    • pp.630-635
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    • 2011
  • As this study was estimation of factors of rapid OUR (Oxygen Uptake Rate) monitoring method. Experiment for estimating factors of optimal microorganism activity was carried out in this study. In addition to comparison and estimation of SCOD variation by OUR variation using real wastewaters. In consequence OUR value was highest when F/M ratio, pH and temperature were 0.03~0.05, 6.0~8.5 and $20{\sim}30^{\circ}C$ respectively. Oxygen consumption by nitrification was incomplete. OUR variation of SCOD was recognizable difference of degradable rate at before and after of inflection point OUR. This study used an experimental method for real time prediction of the influent of the sewage treatment plant for optimal operation is expected to be able to do.

Photocatalytic Efficiency of Anatase TiO$_2$Thin Film by Reactive Sputtering (Anatase TiO$_2$박막의 미세조직이 광촉매 효과에 미치는 영향)

  • Choe, Yong-Rak;Kim, Seon-Hwa
    • Korean Journal of Materials Research
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    • v.11 no.7
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    • pp.537-544
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    • 2001
  • Anatase $TiO_2$thin films as a photocatalyst were prepared by the reactive magnetron sputtering process. The $TiO_2$thin films were deposited on Si substrates under the various conditions : oxygen partial pressure, working pressure, sputtering time, and D.C. power. The photocatalystic degradation of $TiO_2$thin film have been studied to examine the contribution of surface morphology and crystallinity. The thin films with a good crystallinity or a rough surface showed a high photocatalytic degradation rate on phenol and E.coli 078 experiment. Compared with that of only UV radiation, the photocatalytic efficiency of $TiO_2$thin film under the UV radiation and the $O_2$ flow increased. We found that the crystallity and the morphology were the important factors on the photocatalytic efficiency of TiO$_2$thin film.

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Alalysis of flood damage type by climate change using stepwise regression model (단계적 회귀모형을 이용한 기후변화에 따른 홍수피해 유형분석)

  • Kim, Myojeong;Kim, Gwangseob
    • Proceedings of the Korea Water Resources Association Conference
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    • 2018.05a
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    • pp.394-394
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    • 2018
  • 최근 기후변화로 인하여 강수량 및 집중호우 발생 횟수의 증가에 따라 홍수의 발생 빈도 및 강도가 증가한다. 기후변화에 따른 미래의 강수량 예측은 2013년에 발간된 IPCC(Intergovernmental Panel on Climate Change) 5차 평가보고서 (AR5)를 활용하여 분석하고 있다. 기후변화 시나리오에 따라 기온 상승률 및 강수량의 증가량, 극한 강우사상의 발생 빈도 및 발생정도가 다르게 결정되며, 극한 강우사상으로 유발되는 홍수의 피해 정도가 홍수피해 유형별로 다르게 나타난다. 본 연구에서는 기후변화에 따른 미래의 홍수 피해 정도를 예측하기 위하여 홍수에 영향을 미치는 인자 및 홍수를 감소시키는 인자들을 활용하여 단계적 회귀모형을 이용하여 인명피해, 피해면적, 피해액, 발생빈도 등 홍수피해 유형 별로 현재 및 미래의 홍수피해정도를 예측 및 분석하였다. 홍수에 영향을 미치는 인자로 연평균강수량, 일최대강수량, 1시간최대강수량, 10분최대강수량, 호우일수, 인구밀도, 자산밀도, 도로현황, 시가화율 등을 사용하였고, 홍수 피해를 감소시키는 치수대책으로는 하천개수율, 하수도보급률, 양수량, 유수지용량 등을 사용하였다.

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Influences of Environmental Factors on Wheat Quality II. Effects of Regional Climatic Factors on Protein Content and Sedimentation Value of Wheat Flour (재배 환경조건이 소맥품질에 미치는 영향 II. 지역별 기상조건이 소맥분 단백질함량 및 침전가에 미치는 영향)

  • Ryu, I.S.;Shin, H.K.;Cho, C.H.;Bae, S.H.
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.22 no.2
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    • pp.65-70
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    • 1977
  • The effects of regional climatic factors on wheat quality were discussed. The most important climatic factor on wheat quality during the ripening period of wheat was air temperature during the ripening period of wheat. The protein content and sedimentation value were higher in northern parts of Korea compared to southern parts in Korea. The varietal effects of ripening temperature on protein content and sedimentation value of wheat were varied in nine tested varieties.

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Degradation Pattern and Rate of Some Pesticides in Soils -Part I. Degradation Pattern and Rate of Parathion in Soils- (토양처리(土壤處理) 농약제(農藥劑)의 분해율(分解率)에 관한 연구(硏究) -제1보(第一報). Parathion의 토양중(土壤中) 분해(分解)에 대하여-)

  • Lim, Sun-Uk;Kang, Kyu-Yung;Choi, Yong-Lak
    • Applied Biological Chemistry
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    • v.26 no.4
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    • pp.239-247
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    • 1983
  • The effects of some soil conditions on the degradation rate and decomposing pattern of parathion were investigated and the obtained results are summarized as follows: Parathion degraded more rapidly in flooded soils than in non-flooded, in wet soils than in dry soils under non-flooded soils. The degradation rates in paddy and upland soils increased at high temperature than low temperature, higher pesticide concentration than low concentration and higher soil pH level. Parathion in paddy and upland soils was more persistent under soil sterilization than under non-sterilization and degraded rapidly in glucose application. Parathion was more persistent in upland soils than paddy soils under several factors described above. The metabolites identified from the paddy and upland soils by TLC include para-oxon (Rf 0.5), aminoparathion(Rf 0.27), p-nitrophenol(Rf 0.2), p-aminophenol(Rf 0.15). Soil enzyme, acid phosphatase activities decreased more at flooded soils than non-flooded, higher pesticide concentration than low concentration and higher soil pH level and the activity in glucose application was increased. Soil enzymes, urease and dehydrogenase activity decreased more at higher pesticide concentration than low concentration. Comparing with soil enzyme activity in paddy and upland soil, the former was higher than the latter.

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Production of Yeast Extract by a Combined Method of Autolysis and Enzymatic Hydrolysis (자기소화와 효소가수분해 방법을 병용한 효모 추출물의 제조)

  • 인만진;채희정
    • KSBB Journal
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    • v.19 no.4
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    • pp.245-249
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    • 2004
  • A combined method of autolysis and enzymatic hydrolysis of baker's yeast was developed for the production of yeast extract, which is widely used as a natural food ingredient. From statistical analysis, NaCl and ethanol addition were found to be significantly effective factors in autolysis of yeast. The optimum dosages of salt and ethanol were 3% and 1%, respectively. Heat treatment and the use of cell lytic enzyme were not significantly effecting on the autolysis. Yeast hydrolysate was prepared by autolysis, followed by enzymatic hydrolysis using proteases, nuclease and deaminase. Additionally, the hydrolysate was processed by downstream process including Maillard reaction and debittering. The total dry matter yield and total nitrogen yield for the process were 76% and 59%, respectively. Compared to a process using brewer's yeast, when baker's yeast was used as a raw material, a higher recovery yield was obtained.

Production of Chiral Styrene Oxide by Microbial Enantioselective Hydrolysis Reaction (미생물 입체선택성 가수분해 반응을 이용한 광학활성 Styrene Oxide 생산)

  • 윤성준;이은열
    • KSBB Journal
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    • v.15 no.6
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    • pp.630-634
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    • 2000
  • Chiral epoxides are useful chiral synthons in organic synthesis, and various biological methods have been investigated for their production. In this work, the enantioselective resolution of racemic styrene oxide was investigated using Aspergillus niger sp. for the production of optically pure (S)-styrene oxide. The enantioselectivity and initial hydrolysis rates of the racemic substrate were highly dependent of the pH, temperature, and the volume ratio of cosolvent. Experimental sets of pH, temperature, and the volume ratio of cosolvent were investigated using a central composite experimental design, and reaction conditions were optimized by response surface analysis. The optimal conditions of pH, temperature, and the volume ratio of cosolvent were determined to be 7.78, $28.32^{\circ}C$, and 2.4%(v/v), respectively, and optically pure (S)-styrene oxide (>99% ee) was obtained at 35% yield using this microbial enantioselective hydrolysis reaction.

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Protoplast Formation of the Amylolytic Yeast and Saccharomyces cerevisiae by Snail Lytic Enzyme from Helix pomatia (Snail Lytic Enzyme에 의한 전분리용성 효모 및 Saccharomyces cerevisiae의 원형질체 형성)

  • 구영조;박완수;신동화;유태종
    • Microbiology and Biotechnology Letters
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    • v.13 no.2
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    • pp.137-144
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    • 1985
  • Studies were conducted on the conditions for preparation of yeast protoplasts utilizing Hansenula anomala var. anomala FRI YO-32 as well as Saccharomyces cerevisiae KFCC 32356 and a lytic enzyme from the snail Helix pomatia. The cell wails of the strain FRI YO-32 and S cerevisiae were found to be resistant to activity of the snail lytic enzyme if they were not treated with thiol compounds. Dithiothreitol was found to be more effective than 2-mercaptoethanol, but the latter was considered to be practical. As factors influencing the formation of yeast protoplast, it was considered to be concentration and incubation time of 2-mercaptoethanol or the lytic enzyme, growth stages in yeast cultivation, initial number of yeast cells, and concentration of osmotic stabilizer (KCI). Optimum conditions for the preparation of yeast protoplasts were determined.

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Effect of Hydrolytic Temperature on Pore Structure of Alkoxide-derived Aluminas (Alkoxide 법으로 합성한 알루미나의 동공구조에 미치는 가수분해 온도의 영향)

  • 조정미;정필조
    • Journal of the Korean Ceramic Society
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    • v.25 no.3
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    • pp.217-224
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    • 1988
  • Pore structures of Alkoxide-derived aluminas are investigated by BET Nitrogen Sorption method. Aluminas are derived from hydrolysis of aluminum isopropoxide at 3$^{\circ}$and 8$0^{\circ}C$ with stoichiometric quantities of water in use. The resulting hydrolysates are then subjected to thermal treatment for a fixed period of time from 200$^{\circ}$to 50$0^{\circ}C$ in gradual fashions. The hydrolysates obtained at 3$^{\circ}C$ increase their pore volumes with increasing heat treatment, exhibiting their pore-size distributio as twinpeaked. In contrast, the reverse is true to the hydrolysates obtained at 8$0^{\circ}C$, showing their pore size distribution as single-peaked. This suggests that the pore shapes of the former shall be slit-shaped, whilst whose as the latter shall be of a ink-bottle shape. All the evidence indicates that the hydrolytic temperatures play an important role not only in determining the pore shapes of the alumina samples, but in controlling the liberation of structural water in the alumina layers. It is also, surmized that the subsequent heat treatment may at best affect the mode of pore size distribution for the resulting alumina product(s).

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