• Title/Summary/Keyword: 분해도

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A Study on the Condensation Modeling Method for Fast Pyrolysis Gas of Biomass (바이오 매스 급속 열분해 가스의 응축 모델링 기법에 관한 연구)

  • Park, Hun Chae;Choi, Hang Seok;Choi, Yeon Seok
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.107.1-107.1
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    • 2011
  • 최근 석유, 가스, 석탄을 비롯한 화석연료의 다량 사용으로 기후변화, 대기오염 등의 환경문제 및 자원 고갈의 우려 때문에 바이오매스는 중요한 화석연료 대체 에너지 자원으로써 큰 관심을 받고 있다. 바이오매스 자원을 에너지로 전환하는 방법 중 하나인 급속 열분해 공정은 산소가 없는 상태에서 바이오매스를 열적으로 분해하여 액상 상태의 생성물을 회수하는 공정으로, 증기상의 열분해 가스를 응축하여 회수하게 된다. 바이오매스의 급속 열분해에 관한 연구는 주로 바이오매스의 종류와 열분해 조건에 따라 회수되는 바이오 원유의 수율 및 물리 화학적 특성에 관한 연구가 수행되고 있으나, 열분해 가스의 응축에 관한 연구는 응축에 수반되는 복잡한 물리적 현상 때문에 미진하다. 따라서 본 연구에서는 바이오매스의 급속 열분해를 통해 생성되는 증기상의 열분해 가스의 응축 현상을 모사 할 수 있는 모델링 기법에 대해 연구하였다. 급속 열분해 공정을 통해 생성되는 바이오 원유는 수백개의 화합물로 구성되어 있으며, 동일한 바이오매스를 사용한 경우라도 공정조건에 따라 바이오 원유에 포함된 화합물은 달라진다. 따라서 본 연구에서는 바이오 원유의 주요 화합물인 water, propanal, butanal, pentanal, phenol, guaiacol, coniferyl alcohol, formic acid, acetic acid, propanoic acid, butanoid acid를 대상으로 열분해 가스의 응축을 모사하였다. 본 연구에서는 응축 모델링 기법의 검증을 위해 실험결과와 비교하여 정확성을 검증하였으며, 본 연구의 결과를 활용하여 응축 조건 변화에 따른 급속 열분해 가스의 응축률을 예측하고, 이를 이용한 응축 열교환기 설계에 유용하게 사용될 수 있을 것으로 판단된다.

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Decomposition of gas-phase benzene by $TiO_2$ coated alumina balls (이상화티탄이 코팅된 알루미나볼에 의한 기상벤젠의 분해)

  • Lee, Nam-Hee;Jung, Sang-Chul;Cho, Duc-Ho;An, Jong-Il;Hwang, Jong-Sun;Kim, Sun-Jae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05b
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    • pp.144-148
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    • 2003
  • 알루미나볼 위에 Titanium tetraisopropoxide(TTIP)를 원료로, 화학기상증착법으로 제조된 $TiO_{2}/Al_{2}O_{3}$ 볼을 이용하여 벤젠의 기상 광 분해 실험을 실시하였다. 기상분해 과정의 연속적 측정을 위하여 순환식의 반응장치를 자체 제작하였으며, PID(Photo Ionization Detector)방식의 VOCs meter를 이용하여 광조사에 의한 벤젠의 분해율을 실시간으로 측정하였다. 기상의 벤젠과 $TiO_2/Al_{2}O_{3}$ 볼의 원활한 흡착을 위해 30분간 암반응 시킨 후 광분해율을 측정한 결과 광조사에 의한 분말표면에 흡착된 VOCs의 탈착에 의한 초기 농도증가 현상이 공통적으로 측정되었으며, 흡착 면적이 작을수록 농도 증가 또한 낮게 측정되었다. 또한 최적조건을 기준으로 실시한 분해 실험 결과 60ppm이상의 고농도 영역에서는 VOCs의 분해가 비교적 느리게 진행되었지만, 60ppm이하의 저농도 영역에서는 급속한 VOCs의 분해가 측정되었다. 마찬가지로 반응 표면적이 넓을수록, 광원이 많을수록 그리고 광분해에 사용된 자외선 램프의 강도가 클수록 광반응에 의한 벤젠의 분해율이 증가하였다.

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Ultrastructural Studies on the Autolysis of Coprinellus congregatus (먹물버섯의 자가분해 과정에 대한 미세구조 연구)

  • Choi Hyung-Tae;Cho Chung-Won
    • Korean Journal of Microbiology
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    • v.41 no.4
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    • pp.312-315
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    • 2005
  • Coprinellus congregatus, known as an inky cap, is autolysed into ink soon after the maturation of the mushrooms. Electron microscopy was used to examine the ultrastructural changes associated with the autolysis as an initial step to understand the role of hydrolytic enzymes in this process. During the early stages of maturation of the mushrooms, most of cytoplasm of hymenial and subhymenial tissues seemed to be transported to the developing basidiospores. The depletion of cytoplasm within the tissues and the maturation of the basidiospores may initiate the degradation of the cell walls of the tissues. Both hymenial and subhymenial tissues seemed to degraded at the same time. This study suggested that the critical steps in the autolysis of mushrooms is not the degradation of the cytoplasm, but the degradation of the cell wall by hydrolytic enzymes such as chitinases.

New Simple Decomposition Technique for Polarimetric SAR Images (완전편파 SAR영상의 새로운 영상 분해 기법)

  • Lee, Kyung-Yup;Oh, Yi-Sok
    • Korean Journal of Remote Sensing
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    • v.26 no.1
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    • pp.1-7
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    • 2010
  • This paper proposes a new decomposition technique for polarimetric synthetic aperture radar (SAR) images. This new decomposition technique is based on the degree of polarization (DoP) and co-polarized phase-difference (CPD) of the measured polarimetric backscattering coefficients. This decomposition technique is compared with the existing three- and four-component decomposition techniques with the ALOS PALSAR full polarimetric L-band data acquired in 2009. It is shown that the new decomposition technique is better or comparable to the existing techniques for the study areas such as sea, bare soil, forest, and urban area.

Change of Paralytic Shellfish Poison Components during Bacterial Detoxification (마비성패류독의 생물학적 제독 -2. 해수에서 분리한 Enterobacter sp. CW-6를 이용한 마비성패류독의 분해-)

  • PARK Mi Jung;LEE Hee Jung;LEE Tae Seek;KIM Ji Hoe;LEE Tae Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.33 no.6
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    • pp.550-553
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    • 2000
  • Optimum temperature for paralytic shellfish poison (PSP) detoxofication of Enterobacter sp. CW-6 isolated from sea water and changes of contents and ingredients composition of PSP during bacterial detoxification process were investigated. Enterobacter sp. CW-6 detoxicated $61.5{\~}67.7{\%}\;and\;87.4{\~}96.8{\%}$ of initial PSP toxicity ($25.0{\~}28.5\;nmole/g$) after $5{\~}12$ days at 30 and $35^{\circ}C$, identified as optimal growth temperature, respectively. The detoxification rate of Enterobacter sp. CW-6 for crude PSP with initial concentration of 38.2 nmole/g after 8 and 12 days at $30^{\circ}C$ in the Marine broth was 88.4 and $92.7{\%}$, respectively. During bacterial detoxification process using crude toxin solution, temporary increasement of STX group was detected and identified that was derived from GTX2, 3 group. The detoxification rate of Enterobaoter sp. CW-6 on purified GTX1 and 4 with initial concentration 47 nmole/g and 37 nmole/g were more than $90{\%}$ after 12 days in the marine broth at $30^{\circ}C$. Enterobacter sp. CW-6 also showed a detoxification activity on purified GTX2 and 3, and the detoxification rate for the initial concentration 25.6 nmole/g after 12 days was $66.4{\%}$.

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BTXS Compounds Biodegradability by Pseudomonas sp. Isolated from a Bioreactor (미생물반응기에서 분리한 Pseudomonas 속 세균의 BTXS Compounds 분해 특성)

  • Cho, Young-Cheol;Jang, Hyun-Sup;Hwang, Sun-Jin
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.6
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    • pp.678-683
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    • 2007
  • We isolated a toluene-degrading bacterium, TDB-4, from a bioreactor which designed to remove volatile organic compounds (VOCs) from the contaminated air. Based on the results of 16S rRNA gene analysis, it was classified as Pseudomonas sp. The toluene degradability was estimated in the variable toluene and bacterial concentrations. The bacterial growth and degradation rate was higher in the samples supplied with 50 ${\mu}mole/vial$ of toluene than with 10 ${\mu}mole/vial$. It was decreased, however, in the samples with 100 ${\mu}mole/vial$, indicating that toluene inhibit the growth or degradation activity of TDB-4 at high concentration. When the degradation ability of other compounds was examined, TDB-4 can degrade other VOCs such as styrene, benzene, and xylene. These results will be helpful to optimize the operating conditions to improve the efficiency of a bioreactor in detoxification of VOCs.

Nucleic Acid Degrading Enzymes of Barley Malt (맥아의 핵산분해효소)

  • Lee, Won-Jong
    • Korean Journal of Food Science and Technology
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    • v.21 no.1
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    • pp.1-8
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    • 1989
  • Ten cultivars of malting barley grown at four locations were malted and assayed for six enzymes involved in the degradation of nucleic acids. Among these enzymes were deoxyrinonuclease, ribonuclease, phosphodiesterase, 3'- and 5'- nucleotidases and phosphomonesterase. Activities of all enzymes in five-day malts were significantly affected by variety and location of growth. The average levels of ribonuclease, deoxyribonuclease, 3'-nucleotidase and 5'-nucleotidase of 80 five-day malts were 11.2, 5.7, 5.6 and 1.2 units per gram of malt, respectively. Six-rowed barley malts contained higher levels of deoxyribonuclease, phosphodiesterase and 3'-nucleotidase than those of two-rowed barley malts, while two-rowed barley malts contained significantly higher ribonuclease levels than those of six-rowed barley malts.

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Rheological Properties of Dough with Whole Wheat Flour (전립분 첨가 반죽의 물리적 특성)

  • 김영호;최광수;손동화;김정호
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.25 no.5
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    • pp.817-823
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    • 1996
  • The rheological prouerties of dough were evaluated the dough added whole wheat flour during breadmaking. From the farinogram, water absorption of the dough was decreased as the amount of coarse whole wheat flour was increased. While water absorption of the dough was increased as the amount of fine whole wheat flour was increased. Arrival time and development time of the dough with coarse whole wheat flour were longer than those of fine whole wheat flour. As the amount of whole wheat flour was increased, the weakness was increased. Weakness of coarse whole wheat flour was higher than that of fine whole wheat flour. From the extensograph, extension and resistance to extension were decreased with increasing the amount of whole wheat flour. Resistance to extension of coarse whole wheat flour was higher than that of fine whole wheat flour. From the amylograph, as the amount of whole wheat flour increased, maximum viscosity was decreased gradually. Though the amount of coarse whole wheat flour and fine whole wheat flour was increased up to 30% and 50%, respectively, external characteristics of bread was remained in normal. As the amount of whole wheat flour was increased, the value of whiteness was decreased.

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Synergistic Effect of Acetylalginate Esterase and Alginate Lyase on the Degradation of Acetylalginate from Pseudomonas aeruginosa ATCC 39324 (P. aeruginosa ATCC 39324 생산 아세틸알긴산의 분해반응에서 아세틸알긴산 아세틸분해효소와 알긴산 분해효소의 상승효과)

  • Kim, Hee Sook
    • Journal of Life Science
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    • v.23 no.12
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    • pp.1420-1427
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    • 2013
  • A novel acetylalginate esterase (AcAlgE) gene was previously cloned and characterized from Sphingomonas sp. MJ-3. In this study, the synergistic effects of MJ-3 AcAlgE, and KS-408 alginate lyase on the degradation of acetylalginate from Pseudomonas aeruginosa were investigated by using high-field 1H-NMR and an FPLC-equipped peptide column. The alginate lyase coupled assay of AcAlgE showed that degradation of high molecular weight acetylalginate was more difficult than degradation of acid hydrolyzed acetylalginate. The degradation of acetylalginate by alginate lyase was easier after AcAlgE was used to remove the acetyl group from acetylalginate. This result showed that the recombinant AcAlgE enhanced the degradation of acetylalginate by alginate lyase.

Influence of Some Pollutants and Fertilizers on Degradation of Oxadixyl in Soil (몇 가지 오염물질과 비료의 처리가 살균제 Oxadixyl의 토양중 분해에 미치는 영향)

  • Moon, Young-Hee;Kim, Yong-Hwi;Kim, Young-Seok
    • Korean Journal of Environmental Agriculture
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    • v.16 no.4
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    • pp.341-346
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    • 1997
  • The degradation of fungicide oxadixyl in soil amended with manure, chemical fertilizers, heavy metals and detergent was studied. The degradation of oxadixyl in the soil was slow, but became to be fast after the lag phase of about 14 days. The half-life was 10.5 days. The degradation rate was accelerated largely by the amendment of manure. Potassium also promoted the degradation rate but nitrogen and phosphate did not. The heavy metals inhibited the degradation rate, in order of Ni, Cd, Cr, Cu, and Zn. The degradation rate was declined greatly with the addition of synthetic detergent. The microbial biomass and the respiration rate in the soil were increased by the amendment of manure and chemical fertilizers, but decreased by the addition of heavy metals and cleaner. The degradation rate of oxadixyl was positively correlated with the microbial biomass and the respiration rate.

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