• Journal of the Korean Chemical Society
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• v.38 no.11
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• pp.819-826
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• 1994

This study described a simple, rapid and cost effective analytical technique for the ultra-trace analysis of dioxins in environmental samples. Liquid-Liquid extraction methods were used for the initial extraction and enrichment of the analyte. Subsequent clean-up procedures were achieved by using strong cation exchanger, silica and Florisil cartridges. Extracts were analysed by HRGC/HRMS-SIM. The efficiency of these analytical methods was tested by recovery and selectivity for elimination of interferences such as phenols, pesticides and PCBs in each step. The mean recovery of 1,2,3,4-TCDD spiked at 10 ppt in sea water was about 92(${\pm}$1.6)%. This analytical method was applied to Kwangyang sea water and 4.5pg/L of 2,3,7,8-TCDD was determined.

• The Journal of Natural Sciences
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• v.1
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• pp.47-59
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• 1987

The thermal decomposition mechanism of BaTiO($$C_2$$O_4$)_2$ $4H_2$O has been investigated employing TG, DTG, and DTA techniques. The intermediate compounds and the gaseous products of decomposition were examined by IR spectrometer and X-ray analyser. The decomposition proceeds through five steps. The first step which is the dehydration of the tetrahydrate is followed by the decomposition of oxalate groups. During the second decomposition, half a mole of carbon monoxide is evolved. The oxalate groups are completely destroyed in the range $260~460^{\circ}C$, resulting in the formation of a carbonate which retains free carbon dioxide in the matrix . the final decomposition of the carbonate takes place between $650~750^{\circ}C$ and yields $BaTiO_3$.

• Korean Journal of Animal Reproduction
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• v.20 no.2
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• pp.119-126
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• 1996

This study was carried out to determine the optimal condition for successful and efficient c cryopreservation of zygotes, 1-cell embryos, using EFS40 which was 40% (v/v) ethylene glycol diluted in DPBS medium containing 30% Fic-oll (w/v) and 0.3 M sucrose. After mouse zygote produced by IVF was vitrified by two freezing methods, the post-warming survival rates of 1-cell zygotes were assessed as cleavage to the 2-cell stage and development into the hatching blastocysts at 5 day. In the one-step method, when embryos were directly exposed to the vitrification solution at 25$^{\circ}C$ for 1 min., survival and development rates of zygotes were 85.5% and 31.9% In the two-step method, embryos were equilibrated with a dilute 20% EG for 1, 3, 5 min. before 1 min. exposure to EFS40, re-spectively. However, the rates of development (17.7, 3.3, 0%) were lower than that of one-step method. The highest survival rate (95.9%) was obtained by one-step method which exposes embryos in EFS40 for 30 sec. In this condition, 63. 8% of cleaved 2-cell developed into hatching blastocysts. In the cell number of Total and ICM using differential labelling technique, there are no significant differences in the cell number of Total and ICM between blastocysts devel oped in vitrified-thawed embryos (63.2${\pm}$16.9, 1 13.5${\pm}$4.0) and control balstocysts (54.0${\pm}$15.2, 1 12.3${\pm}$4.6). Therefore, these results show that mouse zygotes can be successfully cryopreserved by a simple vitrification method although developmental rates of vitrified embryos were reduced. In conclusion, this proposed vitrifi cation procedures can be useful in the cryopreservation of mouse IVF zygotes.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.46 no.12
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• pp.102-107
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• 2009

As technology gets developed, medical equipments are also modernized and leading-edge systems, such as PACS become popular. Many scientists noticed importance of medical image processing technology. Technique of region segmentation is the first step of digital medical image processing. Segmentation technique helps doctors to find out abnormal symptoms early, such as tumors, edema, and necrotic tissue, and helps to diagnoses correctly. Segmentation of white matter, gray matter and CSF of a brain image is very crucial part. However, the segmentation is not easy due to ambiguous boundaries and inhomogeneous physical characteristics. The rate of incorrect segmentation is high because of these difficulties. Fuzzy-based segmentation algorithms are robust to even ambiguous boundaries. In this paper a modified Fuzzy-based segmentation algorithm is proposed to handle the noise of MR scanners. A proposed algorithm requires minimal computations of mean and variance of neighbor pixels to adjust a new neighbor list. With the addition of minimal compuation, the modified FCM(mFCM) lowers the rate of incorrect clustering below 30% approximately compared the traditional FCM.

• Journal of KIISE:Software and Applications
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• v.32 no.7
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• pp.625-635
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• 2005

In this paper, we propose a hybrid approach for segmenting the lungs efficiently and automatically in chest CT images. The proposed method consists of the following three steps. first, lungs and airways are extracted by two- and three-dimensional automatic seeded region growing and connected component labeling in low-resolution. Second, trachea and large airways are delineated from the lungs by two-dimensional morphological operations, and the left and right lungs are identified by connected component labeling in low-resolution. Third, smooth and accurate lung region borders are obtained by refinement based on image subtraction. In experiments, we evaluate our method in aspects of accuracy and efficiency using 10 chest CT images obtained from 5 patients. To evaluate the accuracy, we Present results comparing our automatic method to manually traced borders from radiologists. Experimental results show that proposed method which use connected component labeling in low-resolution reduce processing time by 31.4 seconds and maximum memory usage by 196.75 MB on average. Our method extracts lung surfaces efficiently and automatically without additional processing like hole-filling.

• Proceedings of the Korean Nuclear Society Conference
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• 1996.05a
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• pp.269-274
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• 1996

월성원자력발전소 2호기와 같은 CANDU 6형 원자로의 반응도제어기구 설치대에는 여러 반응도제어기구가 삽입되기때문에 원자로심으로부터의 방사선흐름현상으로 인한 방사선피폭이 예상될 수 있는 위치이다. 좁고 긴 반응도제어기구 도관에서의 방사선 흐름으로 인한 반응도제어기구 설치대에서의 방사선량을 예측하기 위해 몬테 칼로 MCNP 코드를 1차원 각분할법 코드인 ANISN과 연계하여 사용하였다. 월성원자력2호기의 상단차폐해석을 위한 ANISN 계산, 도관의 방사선흐름을 평가하기 위한 MCNP 계산, 그리고 반응도제어기구 설치대에서의 방사선량율 평가를 위한 MCNP 계산등 3단계 계산 기법의 적응이 시도되었다.

• Journal of the Korean Chemical Society
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• v.55 no.3
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• pp.341-345
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• 2011

The Schiff base cobalt(II) complex, bis[4-chloro-2-((E)-(isopropylimino) methyl) phenol]cobalt(II), has been prepared and characterized by single-crystal X-ray diffraction analyses. The phenomenological, kinetic and mechanistic aspects of the cobalt (II) complex have been studied by TG/DTG techniques. On the basis of the experimental data, the kinetic parameters such as activation energy, pre-exponential factor and entropy of activation were computed, and then the most probable mechanism function was estimated as $g({\alpha})={\alpha}^2$ 2. Hence the rate controlling process at all stages of decomposition is onedimensional diffusion (Parabolic model).

• Proceedings of the KSME Conference
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• 2001.06e
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• pp.410-415
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• 2001

An analytical and numerical examination of second-order fractional-step methods and boundary condition for the incompressible Navier-Stokes equations is presented. In this study, the compatibility condition for pressure Poisson equation and its boundary conditions, stability, and numerical accuracy of canonical fractional-step methods has been investigated. It has been found that satisfaction of compatibility condition depends on tentative velocity and pressure boundary condition, and that the compatible boundary conditions for type D method and approximately compatible boundary conditions for type P method are proper for divergence-free velocity for type D and approximately divergence-free for type P method. Instability of canonical fractional-step methods is induced by approximation of implicit viscous term with explicit terms, and the stability criteria have been founded with simple model problems and numerical experiments of cavity flow and Taylor vortex flow. The numerical accuracy of canonical fractional-step methods with its consistent boundary conditions shows second-order accuracy except $D_{MM}$ condition, which make approximately first-order accuracy due to weak coupling of boundary conditions.

• Proceedings of the KSME Conference
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• 2001.06e
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• pp.33-38
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• 2001

Bifurcation of unstable symmetric flow patterns to stable asymmetric ones in laminar sudden-expansion flow has been numerically investigated. Computations were carried out for an expansion ratio of 3 and over a range of the flow Reynolds numbers by using numerical methods of second-order time accuracy and a fractional-step method that guarantees divergence-free flowfields at all times. The critical Reynolds number above which bifurcation of pitchfork type to asymmetric flow pattern takes place is lower in a flow with a higher expansion ratio, in agreement with the previously reported results. The bifurcation diagrams show that the bifurcation takes place at a Reynolds number, $Re_c = 86.3$, higher than the value that has been reported. The lower critical Reynolds number may be due to deficiencies in their computations which employed SIMPLE-type relaxation methods rather than the initial-value approach of the present study. Characteristics of the flow development during the transition to asymmetric stable flow have been investigated by using spectral analysis of the velocity signals obtained by the simulations.

• Proceedings of the Korea Water Resources Association Conference
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• 2016.05a
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• pp.64-64
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• 2016

하천은 인간에게 용수의 이용 및 하천호안의 휴식처로써의 이용을 통해 직접적인 영향을 주고, 하천구조물의 심미적 영향, 랜드마크로써의 역할을 통해 간접적인 영향을 준다. 또한, 하천은 하천생태계에 서식하는 동 식물에게 영향을 준다. 그러나 하천유사로 인해 통수능이 감소하고, 하천구조물 주변에 침식을 야기할 뿐만 아니라, 댐과 저수지에 유사의 퇴적으로 저수용량의 감소시킨다. 그러므로 이를 예측하는 것은 경제적, 환경적으로 중요하다. 하상변동의 모의를 위해 기존의 2차원 모형은 만곡흐름에서 유동의 helical flow를 고려하지 않아 예측이 부정확하였다. 본 연구에서는 천수방정식을 이용한 하상변동 수치모의에 helical flow의 영향을 고려하였다. 하천과 같은 천수영역에서의 흐름 및 하상변동을 해석하기 위하여 수심평균 된 Navier-Stokes equations인 천수방정식을 이용하였다. 지배방정식은 곡선 좌표계에서 유한체적법으로 차분하였고, 비엇갈림격자를 사용하였다. 지배방정식의 닫힘 문제를 해결하기위해 0-방정식 난류모형을 사용하였고, "time marching" 기법의 적용을 위해 계산단계분할 방법을 이용하였다. 비엇갈림격자의 사용으로 인해 검사체적의 면에서의 유속이 필요하여 pressure-velocity coupling을 사용하여 유속의 진동을 줄였다. 또한, 만곡부의 helical flow를 모의하기위해 helical flow intensity model을 도입하였다. 앞에서 계산한 흐름을 바탕으로 유사량 산정공식과 Exner 방정식을 이용하여 하상변동을 모의하였다. 흐름의 검증, helical flow의 영향에 대한 확인, 하상변동의 적용을 위해 선행연구의 실험이 사용되었다.