• Title/Summary/Keyword: 분자간-

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수정진동자를 이용한 Au 표면에서 avidin-biotin 결합 리포좀 막의 구조 분석

  • Park, Jong-Won;Han, Seong-Ung;Gwon, Jeong-Hun;Park, Jin-Yeong;Jo, Hong-Sik;Lee, Haeng-Ja;Jang, Sang-Mok
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.546-549
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    • 2000
  • Liposomes and proteoliposomes, artificial membranes, can interact with many solutes, such as drugs, peptides and proteins. Immobilization of (proteo)liposomes as supramolecular aggregates on gold surfaces have potential applications in nanotechnology and biosensors. We demonstrate a quartz crystal analyzer (QCA) method to monitor the construction of multi layers of unilamellar liposomes based on avidin-biotin binding on gold surface using quartz crystal microbalance(QCM). Thus, QCA provides an on line and efficient method to detect the protein membranes construction and have applications to biosensing system.

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Syntheses and Characteristics of Intermolecular Charge-Transfer Complex Dyes (분자간 전하이동형 기능성 색소의 합성과 물성)

  • Kim, Sung Hoon;Lee, Soon Nam;Lim, Yong Jin
    • Textile Coloration and Finishing
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    • v.4 no.1
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    • pp.21-25
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    • 1992
  • The charge-transfer(CT) complexes derived from various donors and acceptors were evaluated as coloring matter. Dyes absorbing light in the region from the visible to the near-infrared wavelengths were synthesized. In order to determine the molar ratio of the donor to the acceptor in the CT complex in the solution, the continuous variational method was applied to each system. A 1:1 correspondence between the donor and the acceptor molecules in the CT complex in the solution is established. Color development properties in paper were examined. The longer the exposure time at constant temperature, the deeper the strength of color in paper. The strength of color at high temperature was decreased, because sublimed CT dyes in paper were migrated out side of paper.

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The PSA Properties of n-Butyl Acrylate/Acrylic Acid Copolymer and Tackifier Resins with Influence of Miscibility (n-Butyl Acrylate/Acrylic Acid 공중합체와 점착부여제간의 상용성과 점착물성)

  • 민경은;김호겸;최관영;곽기호
    • Polymer(Korea)
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    • v.24 no.4
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    • pp.469-476
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    • 2000
  • The miscibility between acrylic copolymers and tackifier resins influenced on adhesion properties of PSA. PSA with high molecular weight and narrow molecular weight distribution of acrylic copolymers showed systemical modification of adhesion properties of PSA by tackifier resins only in case of miscible system. It is concluded that the investigation of the miscibility between two Components is very important to adhesion properties of PSA.

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Chemical bonding and electronic state in cuprous and cupric oxide using DV-X$\alpha$ method (DV-X$\alpha$ 분자궤도법을 이용한 CuO 및 Cu_2O$에서의 화학 결합 및 전자상태)

  • 김영하;김양수;한영희;한상철;성태현;노광수
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.220-220
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    • 2003
  • 최근, Cu기판 위에 YBaCuO$_{7-x}$ 초전도체를 입혀 초전도 선재를 제작하려는 연구가 이루어지고 있으며 이 과정에서 CuO와 Cu$_2$O가 생성된다는 보고가 있다. CuO 및 Cu$_2$O의 생성은 초전도 선재의 전기전도적 특성 및 기계적 특성에 상당한 영향을 끼칠 수 있다. 따라서 CuO와 Cu$_2$O에 대한 연구가 필요하다고 할 수 있다. 본 연구에서는 DV-X$\alpha$ 분자궤도법을 통해 CuO와 Cu$_2$O에 대한 (Cu$_{29}$ O$_{58}$ )$^{58-}$ , (Cu$_{52}$ O$_{19}$ )$^{14+}$ 모델을 이용하여 전자상태계산을 하였다. CuO, Cu$_2$O의 valence orbital level 구조 및 DOS (Density of State)를 통해 Cu원자와 O원자간의 공유결합 세기를 측정하였으며 CuO, Cu$_2$O 서로간의 차이점을 분석하였다.

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A study on the stamp-resist interaction mechanism and atomic distribution in thermal NIL process by molecular dynamics simulation (분자동역학 전산모사를 이용한 나노임프린트 리소그래피 공정에서의 스탬프-레지스트 간의 상호작용 및 원자분포에 관한 연구)

  • Yang, Seung-Hwa;Cho, Maeg-Hyo
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.343-348
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    • 2007
  • Molecular dynamics study of thermal NIL (Nano Imprint Lithography) process is performed to examine stamp-resist interactions. A layered structure consists of Ni stamp, poly-(methylmethacrylate) thin film resist and Si substrate was constructed for isothermal ensemble simulations. Imposing confined periodicity to the layered unit-cell, sequential movement of stamp followed by NVT simulation was implemented in accordance with the real NIL process. Both vdW and electrostatic potentials were considered in all non-bond interactions and resultant interaction energy between stamp and PMMA resist was monitored during stamping and releasing procedures. As a result, the stamp-resist interaction energy shows repulsive and adhesive characteristics in indentation and release respectively and irregular atomic concentration near the patterned layer were observed. Also, the spring back and rearrangement of PMMA molecules were analyzed in releasing process.

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나노튜브 임베디드 비휘발성 메모리 소자 특성 연구

  • Gang, Jeong-Won;Byeon, Gi-Ryang;Hwang, Ho-Jeong
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2007.06a
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    • pp.199-202
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    • 2007
  • 본 논문에서는 탄소나노튜브 기반 비휘발성 메모리 소자를 설계하고 분자동력학 방법을 이용하여 이중벽 탄소나노튜브 구성된 소자에 대하여 동작 특성을 분석하였다. 탄소나노튜브는 탄소-탄소 반데르발스 힘과 탄소나노튜브-금속 결합력 간의 균형점에서 국부적으로 안정화 되도록 하는 방법으로, 탄소나노튜브와 양쪽에서 간격을 두고 마주대하는 소스 및 드레인 전위를 조절함으로써 탄소나노튜브에 유도된 정전기인력으로 내부 탄소나노튜브의 움직임을 제어한다. 본 나노메모리 소자는 테라급 재기록 비휘발성 나노메모리(Rewritable Non-Volatile Nano-Memory)로 활용될 수 있으며, 2bit 뿐만 아니라 3bit 정보저장 소자로 활용될 수 있다. 분자동력학 결과는 정보저장 동안에 발생되는 탄소나노튜브와 금속전극 사이의 충돌은 메모리 소자의 동작 속도 및 비휘발성 특성에 매우 중대한 영향을 미치게 될 것을 알 수 있었다.

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Molecular Interacion of Riboflavin and Orotic Acid Derivatives (Riboflavin과 Orotic Acid Derivative와의 분자간 상호작용)

  • 유병설;이상종;정서영;김양배;김종국
    • YAKHAK HOEJI
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    • v.23 no.2
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    • pp.63-68
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    • 1979
  • Biopbysical investigation has been carried out for the interaction of riboflavin tetraacetate and an orotic acid derivative to know the binding mechanism between dihydroorotate dehydrogenase and dihydroorotic acid which are concerned with the oxidoreduction in vivo. Infrared and nuclear magnetic resonance spectra were measured for the chloroform solution of riboflavin tetraacetate, orotic acid butyl ester and its same mixture. Orotic acid butyl ester has been found to associate with riboflavin tetraacetate. They form a strong complex with each other. The complex is an 1:2 cyclic hydrogen bonded trimer through the imino and 2-C carbonyl groups of the isoalloxazine ring and the imino groups of the orotic acid derivative.

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Nanotechnology and scanning microprobe microscopy (주사형 마이크로프로브 현미경과 나노테크놀로지)

  • ;Muramatsu, H.
    • Electrical & Electronic Materials
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    • v.9 no.6
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    • pp.616-625
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    • 1996
  • 본 고에서는 최첨단 주사형 마이크로프로브현미경의 최근동향에 대해 기술하고자 한다. SNOAM의 관찰분야에의 응용이라는 관점에서 광학소자, 반도체재료, 유기박막등의 미소영역에의 광학특성의 관찰이외에 생물분야에서는 형광표식한 시료의 형상상과 형광상의 대비에서 세포나 생체고분자의 기능 해명에도 이용 가능하다고 생각된다. 또한 광가공기술에의 응용이나 기억소자 기술에의 응용도 고려되어져 금후의 응용분야에의 발전이 기대된다. 다가오는 21세기 정보화사회에서는 분자.원자를 제어하는 기술이 중심기술이 될 것으로 확신되고 있다. 그러나 현재 우리주변 기술로서 분자. 원자를 단위로 하는 평가, 분석 기술은 거의 찾을 수 없다. 따라서 주사형 마이크로 프로브 현미경은 Nano-technology로서 장래 정보화사회에 중요한 평가.분석기술의 하나로서 정착될것으로 생각된다.

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Theoretical Study of the Hydration of Collagen (Collagen의 수화에 대한 이론적 연구)

  • Lee Jong Myung;Jhon Mu Shik
    • Journal of the Korean Chemical Society
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    • v.22 no.6
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    • pp.403-411
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    • 1978
  • A theoretical study of the hydration of the model compound of collagen, poly(Gly-Pro-Pro), has been carried out using empirical potential energy functions. The optimum locations and binding energies of water molecules bound to the model compound have been determined by minimizing the interaction energy. The stabilization energy due to the presence of water in the first hydration shell has been evaluated by comparing the internal interaction energies between the different groups of the model compound in its non-hydrated and hydrated states. The different energy components contributing to the overall stabilization are determined and discussed.

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The Effect of the Collision Process Between Molecules on the Rates of Thermal Relaxation of the Translational-Rotational-Vibrational Energy Exchange (분자간 충돌과정에 따른 병진-회전-진동에너지의 이완율)

  • Heo, Joong-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.12
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    • pp.1494-1500
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    • 2004
  • A zero-dimensional direct simulation Monte Carlo(DSMC) model is developed for simulating diatomic gas including vibrational kinetics. The method is applied to the simulation of two systems: vibrational relaxation of a simple harmonic oscillator and translational-rotational-vibrational energy exchange process under heating and cooling. In the present DSMC method, the variable hard sphere molecular model and no time counter technique are used to simulate the molecular collision kinetics. For simulation of diatomic gas flows, the Borgnakke-Larsen phenomenological model is adopted to redistribute the translational and internal energies.