• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.113.2-113.2
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• 2010

세라믹 필터는 여러 종류의 분진제거 시스템에서 연소 배가스 정제를 위한 가장 적절한 소재로 알려져 있다. 현재까지 다양한 형태의 세라믹 필터가 개발되고 있는데, 캔들 타입(candle type), 튜브 타입(tubular type), 평판 타입(parallel flow type) 등이 그 예이다. 통상적으로 세라믹 캔들 필터는 가압유동층복합발전(PFBC, Pressurize Fluidized-Bed Combustion), 석탄가스화복합발전(IGCC, Integrated coal Gasification Combined Cycle), 석탄가스화연료전지복합발전(IGFC, Integrated coal Gasification Fuel cell Combined cycle)에서 고온 배가스 정제용으로 사용되고 있다. 일반적으로 IGCC나 CTL 합성가스 정제시스템의 경우에는 높은 고압(약 25기압)과 미세분진이 함유되어 있는 분위기에서 운전된다. 그러므로 이때 사용되는 초청정용 세라믹 집진필터는 고온, 고압 및 부식 환경에서 50 MPa 이상을 갖는 높은 강도와 내식성을 갖도록 개발되어야 하기 때문에 SiC(Silicon Carbide)가 가장 적절한 캔들 필터 소재로 적용되고 있다. 이에 따라 집진용 SiC 세라믹 캔들 필터를 개발하기 위해서는 고온에서 내산화성이 우수하고, 부피팽창에 의한 균열이 발생하지 않는 무기결합재의 선정 및 이를 통한 소재의 특성 최적화가 가장 중요한 부분이라 할 수 있다. 본 연구에서는 래밍성형 공정을 적용하여 1m급 탄화규소 세라믹 캔들 필터 시작품을 제조하였으며, 래밍성형 공정 이외에 정수압가압성형, 진공압출성형으로 제조되고 있는 세라믹 캔들 필터의 국내외 시장 및 그 전망을 분석하였다.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.109.2-109.2
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• 2010

세라믹 필터는 여러 종류의 분진제거 시스템에서 연소 배가스 정제를 위한 가장 적절한 소재로 알려져 있다. 현재까지 다양한 형태의 세라믹 필터가 개발되고 있는데, 캔들 타입(candle type), 튜브 타입(tubular type), 평판 타입(parallel flow type) 등이 그 예이다. 통상적으로 세라믹 캔들 필터는 가압유동층복합발전(PFBC, Pressurize Fluidized-Bed Combustion), 석탄가스화복합발전(IGCC, Integrated coal Gasification Combined Cycle), 석탄가스화연료전지복합발전(IGFC, Integrated coal Gasification Fuel cell Combined cycle)에서 고온 배가스 정제용으로 사용되고 있다. 일반적으로 IGCC나 CTL 합성가스 정제시스템의 경우에는 높은 고압(약 25기압)과 미세분진이 함유되어 있는 분위기에서 운전된다. 그러므로 이때 사용되는 초청정용 세라믹 집진필터는 고온, 고압 및 부식 환경에서 50 MPa 이상을 갖는 높은 강도와 내식성을 갖도록 개발되어야 하기 때문에 SiC(Silicon Carbide)가 가장 적절한 캔들 필터 소재로 적용되고 있다. 이에 따라 집진용 SiC 세라믹 캔들 필터를 개발하기 위해서는 고온에서 내산화성이 우수하고, 부피팽창에 의한 균열이 발생하지 않는 무기결합재의 선정 및 이를 통한 소재의 특성 최적화가 가장 중요한 부분이라 할 수 있다. 본 연구에서는 IGCC나 CTL 공정에 적용하기 위한 SiC 캔들 필터 소재 개발을 위해 래밍성형 공정으로 1m급의 탄화규소 캔들 필터 시작품을 제작하여 SiC 출발입자 크기와 무기계 결합재인 스트론튬 카보네이트의 첨가량 변화에 따른 필터 소재의 특성 평가를 수행하였다.

• Polymer(Korea)
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• v.24 no.2
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• pp.237-244
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• 2000

Phenolic resin used as a precursor of carbonized matrix for carbon-carbon composites was modified by addition of molybdenum disilicide (MoSi$_2$) in various concentrations of 0, 4, 12 and 20% by weight to improve the anti-oxidation properties of the composites. The green body was manufactured by a prepreg method and was submitted to carbonization up to 110$0^{\circ}C$. In this work, the oxidation behavior of carbon-carbon composites with MoSi$_2$ as an oxidation inhibitor was investigated at the temperature range of 600-100$0^{\circ}C$ in an air environment. The carbon-carbon composites with MoSi$_2$ showed a significantly improved oxidation resistance due to both the reduction of the porosity formation and the formation of mobile diffusion barrier for oxygen when compared to those without MoSi$_2$. Carbon active sites should be blocked, decreasing the oxidation rate of carbon. This is probably due to the effect of the inherent MoSi$_2$ properties, resulted from a formation of the protective layer against oxygen attack in the composites studied.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.3
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• pp.152-160
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• 2013

The purpose of this study is to enhance the mechanical strength of specimens containing fly ash from fluidized bed type boiler, which the recycling rate will be eventually increased. Specimens containing fly ash in a certain portion were made and aged for 3, 14, and 28 days. Specimens were carbonated under the supercritical condition at $40^{\circ}C$. The carbonation process under the supercritical condition was performed to enhance the mechanical property of specimens by filling the voids and cracks existing inside cement specimen with $CaCO_3$ reactants. The additional aging effect after the supercritical carbonation process on mechanical strength of specimens was also investigated by comparing the compressive strength with and without 7 day extra aging. Under the supercritical condition and additional 7 day aging specimens were very effective for enhancement of mechanical strength and compressive strength increased by 44 %.

• Journal of Energy Engineering
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• v.7 no.1
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• pp.103-112
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• 1998

A high temperature fabric filter was developed and characterized in order to solve the various problems encountered in the operation of industrial fabric filters. Four kinds of dusts generated in the typical domestic industry were used for its characterization, coke dust from a steel manufacturing process, cement dust from a cement manufacturing process, fly ash from a fluidized-bed combustor, and incinerator ash from a waste plastics incinerator. The physical and chemical properties of the high temperature fabric filter were analyzed in terms of mean flow pore pressure, bubble point pore diameter, mean flow pore diameter, pore size distribution, and the changes in tensile strength and initial elastic modulus under $SO_2$ and $NO_2$ atmospheres. Pressure drop, dust penetration, and figure of merit for the fabric filter were also investigated in a bench-scale filter testing unit. The fabric filter developed in this study had good physical and chemical filter properties and showed a very applicability to typical industrial dusts treatments.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.22 no.5
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• pp.254-259
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• 2012

The mechanical property enhancement was studied using fly ash produced from fluidized bed type boiler in power plant, which contains a lot of Ca component being used to carbonate for $CO_2$ fixation in the lightweight aggregates made of cement and some portion of fly ash as a cement substitution under the supercritical condition. Specimens having various fly ash substitution rates and curing periods were carbonated under the supercritical condition at $40^{\circ}C$. The weight change rate, carbonation rate by TG/DTA analysis, 1% Phenolphthalein test, specific gravity and mechanical compression strength test were performed to observe the mechanical property enhancement of the cemented materials after carbonation under the supercritical condition and to make sure those could be classified as lightweight aggregates having specific gravity under 2.0.

• Korean Journal of Materials Research
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• v.11 no.2
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• pp.137-145
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• 2001

A new process, gelcasting in aqueous medium, to fabricate complex-shaped ceramic core has investigated. The ceramic slurry, mixture of fused silica powder and additives such as zircon and cordierite, was electrosterically stabilizes. The slip was prepared by ball milling of polydispered ceramic suspension with monomer, dimer and dispersant. The rheological behavior of slip was evaluated by viscosity measurement. It was found that the high solid loading of polydispersed ceramic slip, which has low viscosity of 50vol%, is possible to obtained. The viscosity of the slip was significantly dependent upon the amount of polymer dispersant and the formulation of monomer and dimer. The green bodies were fabricated through casting and gelation at room temperature followed by drying at $25^{\circ}C$ for 48hrs under relative humidity of 80~85%. Crack-free green body was successfully fabricated through the above process.

• Journal of the Korean Society for Heat Treatment
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• v.3 no.3
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• pp.5-12
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• 1990

This study has been conducted to establish the carburizing characteristics of low carbon alloy steels with varying amount of Ni element gas-carburized for 2 hours at $930^{\circ}C$ in an atmosphere of 94% $N_2$-6% $C_3H_8$ gas mixture with some changes in gas pressure passing through the diffusion plate in the fluidized-bed furnace. The results obtained from the experiment are as follows : (1) Optical micrograph has shown that the carburized layer consists of retained austenite and plate martensite and that retained austenite increases as the pressure of gas mixture passing through the diffusion plate as well as Ni content increase. (2) Chemical analysis has shown that carbon potential increases and carburizability is also improved due to a less degree of fluidization as the pressures of gas mixtures passing through the diffusion plate increase, resulting in, however, a severe formation of soot, and the gas pressure is necessarily regulated. (3) It has been revealed that carbon concentration hardness values at a given distance measured from the surface within the carburized case. Increase with increasing the pressure of gas mixtures passing through the diffusion plate and decrease with increasing Ni content. (4) The effective case depth has been shown to almost linearly increase as the pressure of gas mixtures passing through the diffusion plate is increased and to decrease with increasing Ni content.

• Journal of the Korean Institute of Gas
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• v.25 no.2
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• pp.42-51
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• 2021

Facilities that supply specialty gases used in semiconductor manufacturing mainly handles with hazardous and dangerous substances with flammable, toxic, and corrosive properties, and gas cabinets are mainly used as such supply facilities. The effects of the supply facilities were analyzed for each leak through the rupture disk in the gas cabinet and a leak where the leak hole. In this case, gas leaked to the outside depending on the leak area. It is a factor that creates a risk depending on the concentration of the leaked gas. Depending on the risk of leakage, all measures such as safe operation procedures should be reviewed again.

• Korean Chemical Engineering Research
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• v.50 no.5
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• pp.850-859
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• 2012

Devolatilization is an important mechanism in the gasification and pyrolysis of woody biomass, and has to be accordingly considered in designing a gasifier. In order to describe the devolatilization process of wood particle, there have been proposed a number of empirical correlations based on experimental data. However, the correlations are limited to apply for various reaction conditions due to the complex nature of wood devolatilization. In this study, a simple model was developed for predicting the devolatilization of a wood particle in a fluidized bed reactor. The model considered the drying, shrinkage and heat generation of intra-particle for a spherical biomass. The influence of various parameters such as size, initial moisture content, heat transfer coefficient, kinetic model and temperature, was investigated. The devolatilization time linearly increased with increasing initial moisture content and size of a wood particle, whereas decreases with reaction temperature. There is no significant change of results when the external heat transfer coefficient is over 300 $W/m^2K$, and smaller particles are more sensitive to the outer heat transfer coefficient. Predicted results from the model show a similar tendency with the experimental data from literatures within a deviation of 10%.