• Title/Summary/Keyword: 분산 변화점

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Effect of Herbicide Paraquat on NAD(H)-Redox-cycle (제초제 Paraquat의 NAD(H) 산화환원에 대한 영향)

  • Kim Mi-Lim;Choi Kyung-Ho
    • Journal of Life Science
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    • v.15 no.2 s.69
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    • pp.304-310
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    • 2005
  • This study was carried out to investigate the effect of herbicide paraquat (1,1-dimethyl-4,4-bipyridilium dichloride) on the electron transport system of the cell. When actively growing cells of bacteria were exposed to the 1.0 mM paraquat, more than $50\%$ of the cells were killed at 0 hour. But specific activities of superoxide dismutase (SOD) were not changed at 0 hour of paraquat treatment. Oxido-reductions of NAD (H) by the suspension of bacterial membtane, rat mithochondria and NAD-dependent dehydrogenase were accelerated by paraquat treatment.

코어-쉘 양자점을 포함한 poly(N-vinylcarbazole)층을 사용하여 제작한 비휘발성 메모리 소자의 전하 수송 메카니즘과 안정성

  • Son, Jeong-Min;Yun, Dong-Yeol;Kim, Tae-Hwan;Kim, Seong-U;Kim, Sang-Uk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.368-368
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    • 2012
  • 무기물 나노입자를 포함하는 유기물/무기물 나노복합체는 플렉시블 전자 소자에 적용이 가능하기 때문에 차세대 비휘발성 메모리 소자에 대한 응용연구가 활발히 진행되고 있다. 본 논문에서는 $CuInS_2$ (CIS)/ZnS 코어-쉘 나노 입자를 포함한 poly(N-vinylcarbazole) (PVK) 고분자 박막을 기억 매체로 사용하는 유기 쌍안정성 소자(organic bistable devices, OBD) 메모리 소자를 제작하고 전기적 성질에 대하여 관찰하고 전하 수송 메카니즘에 대하여 규명하였다. 화학적 방법으로 형성한 CIS/ZnS 코어-쉘 나노 입자와 PVK를 toluene 용매에 녹인 후 초음파 교반기를 사용하여 나노 복합 소재를 형성하였다. 하부 전극으로 indium-tin-oxide (ITO)가 증착되어 있는 유리 기판 위에 나노 복합 소재를 스핀코팅 방법으로 도포한 후 열을 가해 잔류 용매를 제거하였다. CIS/ZnS 코어-쉘 나노 입자가 분산되어 있는 PVK 나노 복합 소재로 구성된 박막위에 상부 전극으로 Al을 열증착하여 메모리 소자를 제작하였다. 전류-전압 (I-V) 측정 결과에서 저전압에서는 전도도가 낮은 OFF 상태를 유지하다 어느 특정 양의 전압에서 전도도가 갑자기 증가하여 높은 전도도의 ON 상태로 전이되는 쌍안정성이 관찰되었다. 전류의 ON/OFF 비율은 약 $10^3$이며 역방향 바이어스를 가해주었을 때 특정 음의 전압에서 전도도가 ON 상태에서 OFF 상태로 전환되는 전형적인 OBD 메모리 소자의 I-V 특성을 나타났다. 메모리 전하 수송 메커니즘 분석 결과 쓰기 과정은 thermionic emission (TE), space-charge-limited-current (SCLS) 모델과 지우기 과정은 Fowler-Nordheim (FN) 터널링 모델로 설명이 되었다. 제작된 소자에 대해 기억 시간 측정 결과는 ON과 OFF 상태의 전류가 장시간에도 변화가 거의 없는 소자의 안정성을 보여주었다. 이 실험 결과는 CIS/ZnS 코어-쉘 나노 입자가 분산되어 있는 PVK 나노 복합 소재를 사용하여 안정성을 가진 OBD 메모리 소자를 제작할 수 있음을 보여주고 있다.

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Preparation and Properties of Modified Polyethylenes: 1. Preparation and Properties of Dispersions in Water (변성 폴리에틸렌의 제조 및 물성 : 1. 제조 및 수분산 특성)

  • Lee, Jae Heung;Lee, Sang-Hun
    • Journal of Adhesion and Interface
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    • v.3 no.3
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    • pp.7-14
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    • 2002
  • Modified polyethylenes with polar side groups of -COOK, $-CONH_2$, and -COOH were prepared at a dispersion state in water by reacting poly(ethylene-co-methylacrylate) (PEMA) with aqueous solution of KOH and ammonia. Types and their contents of side groups were investigated by infrared spectroscopy, elemental analysis and atomic absorption analysis. Solution viscosity and surface tension were also measured as a function of solid contents. Stability and transparency of the dispersions were greatly affected by the content of COOK in the side groups. The stable dispersion could be prepared at a composition of COOK of 20 mole% at least. The transparency was increased with increasing the COOK contents, but decreased with increasing the amide content at a constant composition of COOK. Solution viscosities increased abruptly at a lower solid content when the COOK contents were increased, implying higher entanglement between the chains in dispersions with higher content of hydrophilic COOK group. The dispersions of higher COOK content revealed lower surface tension values.

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A Tracer Study on Mankyeong River Using Effluents from a Sewage Treatment Plant (하수처리장 방류수를 이용한 추적자 시험: 만경강 유역에 대한 사례 연구)

  • Kim Jin-Sam;Kim Kang-Joo;Hahn Chan;Hwang Gab-Soo;Park Sung-Min;Lee Sang-Ho;Oh Chang-Whan;Park Eun-Gyu
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.11 no.2
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    • pp.82-91
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    • 2006
  • We investigated the possibility of using effluents from a municipal sewage treatment plant (STP) as tracers a tracer for hydrologic studies of rivers. The possibility was checked in a 12-km long reach downstream of Jeonju Municipal Sewage Treatment Plant (JSTP). Time-series monitoring of the water chemistry reveals that chemical compositions of the effluent from the JSTP are fluctuating within a relatively wide range during the sampling period. In addition, the signals from the plant were observed at the downstream stations consecutively with increasing time lags, especially in concentrations of the conservative chemical parameters (concentrations f3r chloride and sulfate, total concentration of major cations, and electric conductivity). Based on this observation, we could estimate the stream flow (Q), velocity (v), and dispersion coefficient (D). A 1-D nonreactive solute-transport model with automated optimization schemes was used for this study. The values of Q, v, and D estimated from this study varied from 6.4 to $9.0m^3/sec$ (at the downstream end of the reach), from 0.06 to 0.10 m/sec, and from 0.7 to $6.4m^2/sec$, respectively. The results show that the effluent from a large-scaled municipal STP frequently provides good, multiple natural tracers far hydrologic studies.

Rheological Properties of Calrose Rice and Effect of Thawing Methods on Quality Characteristics of Frozen Turmeric Rice (칼로스 쌀의 유변학적 특성과 이로 제조된 냉동 강황밥의 해동방법에 따른 품질특성 변화)

  • Kim, So Yeon;Choi, Yu Ra;Kim, Kyeong Seop;Lee, Sang Jun;Chang, Yoon Hyuk
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.46 no.6
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    • pp.771-777
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    • 2017
  • This study investigated the rheological properties of Calrose rice flour dispersions as well as the effects of different thawing methods (steamer, smart oven, and microwave oven) on quality characteristics of frozen turmeric rice. Apparent viscosity, consistency index, and yield stress significantly increased at higher rice flour concentrations. Magnitudes of storage modulus and loss modulus significantly increased with elevation of rice flour concentration. Frozen turmeric rice thawed using a steamer had the highest moisture content and largest size (length, width, and thickness) among all thawing methods. The L values of turmeric rice after thawing using a steamer was significantly higher than those of other thawing methods. The a value of turmeric rice after thawing using a steamer was significantly lower than those of other thawing methods. Textural properties (hardness, adhesiveness, springiness, cohesiveness, brittleness, and chewiness) of frozen turmeric rice after thawing using a steamer were significantly lower than those of other thawing methods. Therefore, it can be concluded that frozen turmeric rice after thawing using a steamer might be desirable for improvement of texture.

A Study on The Monthly Trend of Seoul Hourly Rainfall Using BLRPM (BLRPM을 이용한 서울지점 시단위 강우의 월별 경년변화 연구)

  • Hwang, Seok-Hwan;Kim, Joong-Hoon;Yoo, Chul-Sang;Jung, Sung-Won;Yoo, Do-Guen
    • Proceedings of the Korea Water Resources Association Conference
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    • 2009.05a
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    • pp.1162-1166
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    • 2009
  • 본 논문에서는 공간상의 한 점에 대한 연속시간 강우모델로 시간단위의 통계특성을 재현하는데 유용하다고 알려진 BLRPM(Bartlett-Lewis Rectangular Pulse Model)을 이용하여, 측우기 자료를 포함하는 서울지점의 일강우 자료를 분해하고 지속시간별로 집성하여 모의된 시단위 단기 강우의 정량적 장기변화 특성을 분석해 보았다. 모의자료의 전이확률과 발생빈도 분석결과, 측우기 관측계열(CWK)에 비해 근대 우량계 관측계열(MRG)의 무강우 지속기간은 길어지고 강우지속기간은 짧아졌음을 알 수 있다. 이는 과거에 비해 근래의 강우지속기간이 짧아졌음을 의미하고, 근래 강우량의 양적증가와 같이 고려해 보면 근래의 강우강도가 과거보다 매우 높아졌음을 증명해 준다. 1960년대 전후로 구분한 자료계열(BCC와 ACC)에 대하여 지속시간별 모의 강우량의 평균과 분산의 비(증감률)를 월별로 비교한 결과, 전반적으로 9월이 증가의 정도가 가장 컸고 8월도 비교적 큰 증가 경향을 보였다. 그러나 6월은 오히려 약간 감소한 경향을 나타냈다.

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Relationship between pH and colloidal stability of three Hawaii soils (3종류의 하와이 토양의 pH와 토양분산도와의 관계)

  • Lim, Soo-Kil H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.24 no.2
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    • pp.95-101
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    • 1991
  • The results of relationships between colloidal stability and soil pH on three Hawaii's volcanic ash soils developed under the three different rainfall conditions can be summarized as follows: 1. The Hilo soil only revealed the increase of colloidal stability by becoming for from Z.P.C point to either side of pH. 2. Hilo and Kawaihae soils, however, showed the increase of colloidal stability only in the higher pH range than their Z.P.C. 3. $P_2O_5$ drying procers decreased colloidal stability kof these soils because of so called irreversible drying characteristics of amorphous materials and the decrement was in order of: Akaka>Hilo>Kawaihae expressing positive correlation with content of amorphous materials in them. 4. The difference of colloidal stability curves among three soils can easily be interpreted by DLVO theory considering 0.1N-HCl amount added to decrease their soil pH, respectively. The addition of large amount of 0.1N-HCl into Akaka and Kawaihae soils did not effectively develop the positive charge but resulted in the shrink of diffuse double layer thickness inducing large attraction forces among soil particles.

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Morphology Formation and Application of Interpenetrating Polymer Network (IPN) Materials (Interpenetrating Polymer Network(IPN)의 모폴로지 형성과 그 응용)

  • Kim, Sung-Chul
    • Polymer(Korea)
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    • v.29 no.1
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    • pp.1-7
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    • 2005
  • Interpenetrating polymer network (PN) is a mixture of network polymers. The characteristics of IPN material is the control of morphology during the IPN synthesis. By controlling the relative kinetics of chemical reaction (as well as gellation) and phase separation, the morphology of IPN can be controlled to obtain materials with nano-scale domain and also the co-continuous phase. Other important advantage is the fact that the morphology is permanent due to the presence of the physical interlocking between the networks. The combination of hydrophilic polyurethane and hydrophobic polystyrene in IPN form provides enhanced blood compatibility due to the co-existence of the hydrophilic and hydrophobic domains in nano-scale on the surface. The reaction temperature, reaction pressure and the degree of crosslinking were varied during the IPN synthesis and the morphology and blood compatibility of the resulting IPN materials were studied.

Stability Assessment of FKP System by NGII using Long-term Analysis of NTRIP Correction Signal (NTRIP 보정신호 분석을 통한 국토지리정보원 FKP NRTK 시스템 안정성 평가)

  • Kim, Min-Ho;Bae, Tae-Suk
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.31 no.4
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    • pp.321-329
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    • 2013
  • Despite the advantage of unlimited access, there are insufficient studies for the accuracy and stability of FKP that blocks the spread of the system for various applications. Therefore, we performed a long-term analysis from continuous real-time positioning, and investigated the error characteristics dependent on the size and the surrounding environment. The FKP shows significant changes in the positioning accuracy at different times of day, where the accuracy during daytime is worse than that of nighttime. In addition, the size and deviation of FKP correction may change with the ionospheric conditions, and high correlation between ambiguity resolution rate and the deviation of correction was observed. The receivers continuously request the correction information in order to cope with sudden variability of ionosphere. On the other hand, the correction information was not received up to an hour in case of stable ionospheric condition. It is noteworthy that the outliers of FKP are clustered in their position with some biases. Since several meters of errors can be occurred for kinematic positioning with FKP, therefore, it is necessary to make appropriate preparation for real-time applications.

Interannual Variability of Sea Water Temperatures in the Southern Waters of the Korean East Sea (한국 동남해역의 장주기 수온변동)

  • Ro, Young Jae
    • 한국해양학회지
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    • v.24 no.1
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    • pp.1-14
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    • 1989
  • This study analyzes the interannual periodicity by using the statistical techniques of probability, spectral analysis, empirical orthogonal function analysis (EOF), and coherency analysis. The data base for this study is the time series of 1971-1985 temperature, salinity in the southern waters of the East Sea, 1960-1986 mean sea level at Pusan and Izuhara, and 1960-1986 sea level atmospheric pressure at Pusan. The appearances of anomalous temperatures higher and lower than 15-year mean monthly average with one standard deviation are about 30% of total data. The significant interannual period for temperature, salinity and sea level fluctuation is 36.6, and 23.3 months. The empirical orthogonal function analyses show that the 1st mode of the EOFs is responsible for more than 90% of total variance of the surface temperature variations, while in near-bottom waters, the relative importance of the higher EOF modes is much greater explaining more than 30% of total variance. The coherency between normalized temperatures and salinities is significant at the interannual period of 36.6 and 21.3 months.

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