• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.36 no.1
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• pp.66-72
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• 2000

In these days, with development of industry, the use of machines and structures like ships, airplanes, bridges, power plants, and structure for construction has increased and these machines and structures are used in various corrosive environment. Especially, in case of STS 304, which is material for every kind of machine and chemical plant, it makes many problems related with corrosion and as a result of this, there are happening tremendous economic loss. Therefor, in this study, the test for polarization characteristics was carried out to study characteristics of crevice corrosion of STS 304 which is austenitic stainless steel, in NaCl environment.The main results obtained are as follows :1) Part of crevice is corroded, neighboring outside surface of crevice is passivation. 2) In polarization behavior, corrosion potential of STS 304 become more noble as the concentration of NaCl solution increased by 3.5% but the concentration increased over 3.5% that of STS 3.4 become less noble. 3) The current density under corrosion potential was high drained as concentration of NaCl solution increased by 3.5% but the concentration increased over 3.5%, the current density was low drained.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2016.11a
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• pp.143-143
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• 2016

알루미늄 합금은 내구성과 내식성이 우수할 뿐만 아니라 다양한 표면개질을 통해 그 표면 특성을 더욱 향상시킬 수 있다. 특히 Al-Mg계 5083-H321 Al 합금의 경우 가공성 및 용접성이 우수하여 선체 재료로 널리 이용되는데, 이는 선체중량의 경량화가 가능하여 연료비 절감과 빠른 선속 등 다양한 이점을 지니기 때문이다. 그러나 선속의 고속화에 따라 선체에 가해지는 유체충격이 증가하고 정압 저하에 기인하여 캐비테이션-침식 손상이 증가할 뿐만 아니라 해수환경 특성 상염소이온의 존재로 부식이 가속화되는 등 침식 및 부식의 시너지효과로 손상은 크게 증가한다. 이에 대한 방지대책으로 다양한 표면개질 기법이 제안되고 있으나 강한 충격압이 동반된 캐비테이션 침식-부식 복합 손상 환경에서는 표면처리만으로는 불가능할 수 있다. 따라서 본 연구에서는 양극산화된 5083-H321을 대상으로 캐비테이션 환경 하에서 일정 전위를 인가하여 침식-부식 손상이 최소화되는 최적전위를 규명하고자 한다. 이를 위해 먼저 분극 실험을 통해 재료의 전기화학적 거동을 바탕으로 임의의 전위를 선정하고 해당 전위를 인가한 상태에서 캐비테이션 실험을 실시하였다. 이때 분극실험과 캐비테이션-전기화학 복합실험 모두 $25^{\circ}C$의 해수에서 실시하였으며, 전기화학적 분극실험은 유효면적이 $3.24cm^2$인 시편에 2 mV/s의 분극속도로 0 ~ -3 V 까지 인가하였고, Ag/AgCl 기준전극과 백금대극을 사용하였다. 캐비테이션-전기화학 복합 실험은 정전위를 인가한 상태에서 $30{\mu}m$의 진폭으로 20분간 실시하였으며, 혼팁과 시험편 사이의 거리는 1 mm로 일정하게 유지하였다. 실험 후 표면 손상의 정량적 분석을 위해 인가된 전위별 전류밀도를 비교하고, 무게감소량을 측정하였으며, 손상특성 분석을 위해 3D현미경과 주사전자현미경(SEM)을 통해 표면을 분석하였다.

• Journal of the Korean Applied Science and Technology
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• v.35 no.4
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• pp.1206-1212
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• 2018

In this study, the polarization reversal characteristics of thin film capacitors with a thickness of 100 nm or less fabricated with ferroelectric polymer were measured and analyzed. For the fixed film thickness, polarization reversal occurred at higher coercive fields as the applied maximum electric field increased. For the fixed maximum electric field, polarization reversal occurred at the same coercive field irrespective of the thickness of the thin film. The proportional constant values between the logarithmic electric field and the logarithmic scale frequency were $0.12{\pm}0.01$ for all measurements. As a result, the ferroelectric polymer capacitors consistently exhibited polarization reversal characteristics without any size effects up to a thickness of 40 nm. This study shows the possibility of a polymer memory device that can operate at low voltage, which is useful for predicting the behavior of a low-voltage operating polymer memory device.

• Journal of the Korean Vacuum Society
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• v.18 no.1
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• pp.49-53
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• 2009

The chemical properties of SiOC film was studied for inter-layer insulator. SiOC film was formed with non polarity due to the appropriate union by the alkyl and hydroxyl group. An amorphous structure of non polarity can induce the low dielectric constant materials. The chemical properties of thin film can define the bonding structure owing to the ionic variation, and the analysis of chemical properties was researched by the carbon content using the FTIR spectra, and induced the film with non polarity. The electrical properties is the electron flow, and is always not the same as the chemical properties. The electrical properties of SiOC film with various flow rate ratios was analyzed and researched the correlation between the chemical properties. SiOC film showed the increasing of the leakage current after annealing process, and abruptly increased the carbon content at some samples. But the sample with increasing the carbon content decreased the leakage current. It means that the chemical properties is not the same as the electrical properties, and the carbon is related with the variation of the bonding structure, and does not contribute the current flow.

• Journal of the Korean Ceramic Society
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• v.42 no.4
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• pp.251-259
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• 2005

In order to characterize the influence of the reaction-site density on the cathodic polarization property of LSCF, we chose the porosity of LSCF as a main controlling variable, which is supposed to be closely related with active sites for the cathode reaction. To control the porosity of cathodes, we changed the mixing ratio of fine and coarse LSCF powders. The porosity and pore perimeter of cathodes were quantitatively analyzed by image analysis. The electrochemical half cell test for the cathodic polarization was performed via 3-probe AC-impedance spectroscopy. According to the investigation, the reduction of oxygen at LSCF cathode was mainly controlled by following two rate determining steps; i) surface diffusion and/or ionic conduction of ionized oxygen through bulk LSCF phase, ii) charge transfer of oxygen ion at cathode/electrolyte interface. Moreover, the overall cathode polarization was diminished as the cathode porosity increased due to the increase of the active reaction sites in cathode layer.

• Journal of the Korean Geophysical Society
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• v.3 no.1
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• pp.37-48
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• 2000

In order to investigate in-line ground motions caused by earthquakes, we examine the multicomponent complex trace analysis method (MCTAM) for the synthetic data and apply it to real earthquake data. An experimental result for synthetic data gives correct information on the arrival times, duration of individual phases, and approaching angles for body waves. Rayleigh waves are also easily identified with the MCTAM. A deep earthquake with magnitude of 7.3 was chosen to test various polarization attributes of ground motions. For P waves, instantaneous phase difference between the vertical and the in-line horizontal components ${\phi}(t)$, instantaneous reciprocal ellipticity ${\rho}(t)$, and approaching angle ${\tau}(t)$ are computed to be ${\pm}180^{\circ},\;0{\sim}0.25,\;and\;-30^{\circ}{\sim}-45^{\circ}$, respectively. For S waves, ${\phi}(t)$ tends to vary while ${\rho}(t)$ have values of $0{\sim}0.3\;and\;{\tau}(t)$ remains near vertical, respectively. A relatively low frequency signal registered just prior to the S wave event is interpreted as a P-wave phase based on its polarization characteristics. Velocities of P and S waves are computed to be 8.633 km/s and 4.762 km/s, and their raypath parameters 0.074 s/km and 0.197 s/km. Dynamic Poisson's ratio is obtained as 0.281 from the velocities of P and S waves.

• Composites Research
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• v.27 no.4
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• pp.146-151
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• 2014

In this study, the experimental study has been performed by varying the polarization of the electric field and impact force to check the piezoelectric characteristics of piezoelectric paint sensor. Piezoelectric paint sensor used in this study is composed of epoxy resin with a hardener and PNN-PZT powder in 1:1 weight ratio. The dimensions of the paint sensor specimen are $40{\times}40{\times}1mm^3$ and regular specimens were made using a mold. The voids are removed from the specimen in the vacuum desiccator. Both upper side and bottom side of the paint sensor were coated with silver paste for making an electrode and then dried at room temperature for a day. The poling treatment has been carried out under controlled conditions of the electric field in order to check the effect of piezoelectric sensitivities, while the poling temperature was fixed at room temperature and the poling time was set to 30 min. The piezoelectric sensitivities have been measured by comparing output voltage from paint sensor with output force from impact hammer when the impact hammer hits the paint sensor. In result, the effect of the electric field has been evaluated for the sensitivity and describe the result.

• Journal of the Microelectronics and Packaging Society
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• v.5 no.2
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• pp.59-64
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• 1998

Pt/SiO2/Si 기판구조위에 스크린인쇄법과 졸-겔법에 의해 (Pb, La)TiO3(PLT) 후막 과 박막을 도포시켜 $650^{\circ}C$후속열처리 온도에서 결정화한후 결정특성과 전기적 특성을 조사 하였다. $650^{\circ}C$ 온도에서 후속열처리된 PLT 시료의 경우 전형적인 perovskite 결정구조를 보 여주었다. SEM 단면형상으로부터 Pt 전극과 PLT막 사이에는 비교적 평활한 계면형상을 보여주었다. PLT 후막과 박막시료의 잔류분극(2Pr) 값은 약 1$\mu$C/cm2 으로각각 나타났으며 이와같이 후막 PLT시료에 비해 박막시료의 잔류분극값이 큰이유는 박막시료가 보다 양호 한 결정성을 지니기 때문이었다. 상온부근에서 후막과 박막시료의 초전계수값은 약 1.5nC/cm2.$^{\circ}C$와 4.0nC/cm2.$^{\circ}C$의 값을 각각 나타내었으며 누설전류의 크기는 약 0.3~0.8$\mu$ A/cm2의 비교적 양호한 누설전류 특성을 얻었다.

• The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.4 no.2
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• pp.46-54
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• 1990

본 연구에서는 에폭시수지에 무기물충진제 SiO2를I첨가하여 제작된 시편의 주파수 및 온도변화에 따른 유전 완화특성을 연구하였다. 연구결과로 제작된 복합재료의 유전특성은 충진제의 함량증가에 따라 유전율은 상당히 증가하였으나 유전손실의 변화는 거의 없었다. 이와같은 사실을 포함한 모든 특성들은 충진제입자가 에폭시 매트릭스에 견고하게 결합되어 있다는 사실과 Maxwell-Wagner의 계면분극이론으로 잘 설명될 수 있다. 제작된 복합재료에 대한 특성의 검토에서 충진제(SiO2)의 입자는 에폭시 매트릭스와 견고하게 결합되어 있으며 충진제 첨가효과는 전반적으로 유전완화세기에는 별 영향을 미치지 못하나 계면분극효과에 의한 유전율을 증가시키는 효과가 있다.

• Korean Journal of Materials Research
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• v.7 no.6
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• pp.479-483
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• 1997

Sol-gel법으로 제작한 여러 종류의 Zr/Ti비율을 갖고 있는 PZT박막의 전지적 특성과 신뢰성 특성을 상부 백금 전극을 sputtering으로 증착하고 Ar 기체로 반응성 이온 식각(RIE)방법으로 패턴을 형성한 후 열처리온도의 변화에 따라 조사하였다. Hysteresis loop특성을 되찾게 하였다. Zr/Ti 비율이 감소함에 따라 voltage shift가 증가하였으며 internal field가 없어지는 열처리 온도가 증가하였다. Zr/Ti비율이 감소함에 따라 초기 잔류 분극은 증가하였으나 switching 횟수가 증가됨에 따라 잔류 분극이 급속히 감소하였다.