• Journal of the Korean Geotechnical Society
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• v.21 no.2
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• pp.93-103
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• 2005

This study was performed to identify the presence of measurement distortions such as electrode polarization and to investigate the influence of soil water content on complex permittivity at low frequency. In low frequency measurement using two-terminal electrode system, electrode polarization effect was observed at frequencies less than approximately 100 HBz. The analysis for real permittivity should be performed at frequencies above 100 kHz in order to exclude electrode polarization effect in the analysis of real permittivity at low frequency measurements. For a given soil, both of real and effective imaginary permittivity of wet soil increased continuously with volumetric water content. This is evidenced by the facts that the real permittivity is proportional to the number of dipole moments per unit volume and effective imaginary permittivity is effected by the conduction due to water. However, proportional relation between real permittivity and volumetric water content is valid at upper MHz frequencies.

• Korean Journal of Materials Research
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• v.9 no.10
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• pp.1032-1036
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• 1999

The electron emission and degradation of the ferroelectric Pb($\textrm{Zr}_{0.5}\textrm{Ti}_{0.5}$)$\textrm{O}_3$ ceramics by the pulse electric field have been investigated as a function of the upper electrode diameter. Polarization increased with the decrease of the upper electrode diameter due to the increase of the volume fraction participated in the polarization reversal near the electrode edge. Simulation using ANSYS 5.3 for the electric field distribution showed that the electric field increased near the upper electrode edge of the asymmetric electrode structure. The ferroelectric volume near the upper electrode edge which contributed to the increase of the polarization and the emission charge per electrode diameter were independent on the upper electrode diameter. Polarization and dielectric constant were decreased due to the erosion of the upper electrode with repeating the emission cycles, but they were recovered by the electrode regeneration. The degradation of the ferroelectric surface resulted in the increase of the coercive field and dielectric loss.

• Journal of the Korean Chemical Society
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• v.42 no.1
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• pp.122-134
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• 1998

In this review, we describe the electrochemical properties of spinel-type lithium manganese oxides $(Li_xMn_2O_4)$ and their failure modes encountered in 4 V lithium rechargable cells. The long-term cyclability (reversibility) of spinel electrodes is determined partly by the purity, size and distribution of spinel particles, and also by the microstructure of electrode plates. A proper selection of electrolytes is another important task in cyclability enhancements. In the spinel preparation, impurity formation and cation mixing should be minimized. The carbon content in composite cathodes should also be minimized to the extent where the cell polarization does not bring about adverse effects on cell performances. The binder content should be optimized on the basis of dispersion of component materials and mechanical strength of the plates. Cathodic capacity losses arising from solvent oxidation and spinel dissolution can be mitigated by using electrolytes composed of carbonates and/or fluorine-containing lithium salts. The carbon additives may be selected after a trade-off between the cell polarization in composite cathodes and the solvent oxidation on carbon surface.

• Proceedings of the Acoustical Society of Korea Conference
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• 1992.11a
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• pp.69-76
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• 1992

섬유강화 복합재료의 동탄성계수와 감쇠특성을 규명하기 위하여 랜덤하게 분포된 무한 실린더 형상의 산란체를 가진 점탄성 매질내에서 , 축방향으로 분극되어 조화 운동을 하는 탄성파의 전파에 관하여 연구하였다. 다중 산란에 관한 이론으 이용하여 매질내에서의 파동전파 특성을 내포하는 분산관계식을 얻었다. 다중산란에 의한 실린더간의 상호작용을 수식화하기위하여 필요한 실린더의 쌍분포함수는 몬테카를로 모의 실험을 이용하여 구하였다. 수치적으로 구한 감쇠계수 및 유효전단강성을 주파수와 체적율의 함수로 제시하였다. 또한 감쇠계수의 주파수에 따른 변화에 있어서, 저주파에서는 매질의 점탄성 손실이 지배적이며, 고주파수로 갈수록 다중산란에 의한 손실이 지배적인 것으로 나타났다.

• Proceedings of the Korean Geotechical Society Conference
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• 2005.03a
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• pp.499-506
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• 2005

지반오염조사에 대한 유전상수 측정기법의 적용성을 평가하기 위하여 중금속 오염도에 따른 흙의 유전특성 변화를 분석하였다. 유전상수의 실수부와 허수부 모두 체적함수비에 따른 증가경향을 나타내었으며, 특히 MHz 범위에서 유전상수 실수부는 쌍극자모멘트에 비례하기 때문에 흙의 유전상수는 체적함수비에 따른 선형적인 증가경향을 나타내었다. 중금속 용액은 50kHz 이하의 저주파영역에서 전극 분극효과에 의해 농도 증가에 따라 유전상수 실수부가 증가하는 경향을 나타내었으나, 고주파 영역에서는 이온의 수화작용에 의한 물분자의 배향분극 발현 감소로 인하여 유전상수 실수부가 감소하였다. 유전상수 허수부의 경우에는 모든 주파수 영역에서 중금속 농도 증가에 따른 전도손실에 의하여 증가하는 경향을 나타내었다. 흙과 중금속 혼합시료의 경우 함수비가 큰 시료에서는 중금속 용액 자체의 유전특성이 그대로 발현되었으나, 함수비가 작은 시료에서는 공간전하분극의 영향이 우세하여 유전상수 실수부가 10-20%정도 증가하는 경향을 나타내었다. 유전상수 허수부의 경우에는 중금속 농도 증가에 따른 뚜렷한 증가경향을 확인할 수 있었다. 본 연구의 결과에 의하면 중금속의 오염감지에 대해서는 유전상수 실수부보다는 허수부의 적용성이 높은 것으로 나타났으며, 현장에서의 정확한 오염도 평가를 위해서는 함수비에 대한 평가가 선행되어야 할 것으로 판단된다.

• Journal of Soil and Groundwater Environment
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• v.9 no.3
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• pp.1-11
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• 2004

To evaluate the applicability of dielectric constant measurement method on the geoenvironmental investigation of subsurface contaminated by landfill leachate, the analysis on dielectric characteristics of sand containing contaminated pore water by landfill leachate was performed. The separate real and imaginary parts of dielectric constant were investigated in the frequency range of 75kHz to 12MHz. The real part of dielectric constant increased at the lower frequency wherea the real part of dielectric constant decreased at the higher frequency as the concentration of leachate increased. These results can be explained by the frequency dependence of space charge polarization and orientation polarization. The imaginary part of dielectric constant on the contaminated sand with leachate increased with their concentration for whole frequency range. These results are caused by the increase of energy loss due to the enhancement of conduction in soil with leachate concentration. The results in this study indicate that the dielectric constant measurement method has potential in evaluating the contaminated soil and pore water by landfill leachate.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.10 no.3
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• pp.378-391
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• 1999

When the time-harmonic plane wave is incident upon a high-contrast spherical cavity in a lossy medium, the incoherent shadow intensity pattern is acquired by averaging out the multi-frequency intensities of the co-polarized total electric field calculated at the measurement plane perpendicular to the propagating direction of the incident wave in the forward direction. In the spherical rotational measurement configuration, an incoherent imaging of the spherical cavity is obtained via the back-projections of the incoherent shadow intensity pattern. This imaging method is validated by imaging an air sphere in the lossy medium of ${\epsilon}_r$ = 2 and $\sigma$ = 0.001, 0.003 S/m and the conditions for obtaining better images are investigated.

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.38 no.5
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• pp.313-322
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• 2001

The effects of Zr/Ti concentration ratio in PLZT (10/y/z) thin films prepared by sol-gel method are investigated for the NVFRAM application. Rosette and pyrochlore phase are observed in PLZT (10/40/60) thin film and the (100) orientation, the grain size, and the surface roughness of PLZT thin films increase due to the increase of Ti amount in Zr/Ti concentration ratio. As Ti amount of Zr/Ti concentration ratio increases, the dielectric constants at 10KHz decrease from 600 to 400, while the loss tangents increase from 0.028 to 0.053 and the leakage current densities at 170 kY/cm decrease from 1.64$\times$10$^{-6}$ to 1.26$\times$10$^{-7}$ A/$\textrm{cm}^2$. In the results of hysteresis loops measured at $\pm$ 170 ㎸/cm, the remanent polarization and the coercive field increase from 6.62 to 12.86 $\mu$C/$\textrm{cm}^2$ and from 32.15 to 56.45 ㎸/cm, respectively, according to the change from 40/60 to 0/100 in Zr/Ti concentration ratio. Fatigue and retention properties also improve much as the Zr/Ti concentration ratio change from 40/60 to 0/100. After applying 10$^{9}$ square pulses with $\pm$5V, the remanent polarization of the PLZT (10/40/60) thin film decreases 50％ from the initial state while that of the PLZT (10/0/100) thin film decreases 30％. In the results of retention measurements of 10$^{5}$ s, the remanent polarization of the PLZT (10/0/100) thin film decreases only 11％ from the initial state, while that of the PLZT (10/40/60) thin film decreases 40%.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.9 no.3
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• pp.609-615
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• 2005

The effects of Zr/Ti concentration ratio in PLZT (10/y/z) thin films prepared by sol-gel method are investigated for the NVFRAM application. As Ti amount of Zr/Ti concentration ratio increases, the dielectric constants at 10 kHz decrease from 550 to 400, while the loss tangents increase from 0.028 to 0.053 and the leakage current densities at 170 kV/cm decrease from $1.64\times10^{-6}$ to $1.26\times10^{-7}\;A/cm^2$. In the results of hysteresis loops measured at $\pm170kV/cm$, the remanent polarization and the coercive field increase from 6.62 to $12.86{\mu}C/cm^2$ and from 32.15 to 56.45 kV/cm, respectively, according to the change from 40/60 to 0/100 in Zr/Ti concentration ratio. Fatigue and retention properties also improve much as the Zr/Ti concentration ratio change from 40/60 to 0/100. After applying $10^9$ square pulses with $\pm5V$, the remanent polarization of the PLZT (10/40/60) thin film decreases $50\%$ from the initial state while that of the PLZT (10/0/100) thin film decreases $28\%$. In the results of retention measurements of 10s s, the remanent polarization of the PLZT (10/0/100) thin film dec.eases only $10\%$ from the initial state, while that of the PLZT (10/40/60) thin film decreases $40\%$.

• Proceedings of the International Microelectronics And Packaging Society Conference
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• 2001.07a
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• pp.114-118
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• 2001

졸-겔법으로 Pt/Ti/$SiO_2$/Si 기판위에 $Bi_{3.7}$/$La_{0.75}$$Ti_3O_{12}$(BLT) 강유전체 박막을 형성하였다. As-coated BLT 박막은 $600^{\circ}C$의 후속 열처리온도에서 결정화 되었으며 전형적인 Bi 층상 페롭스카이트 결정구조를 나타내었다. 또한 후속 열처리온도를 증가함에 따라 결정성이 향상되었다. $700^{\circ}C$의 온도에서 후속 열처리된 BLT 박막의 비 유전상수($\varepsilon_{r}$)와 유전손실($\textrm{tan}\delta$)은 5KHz 주파수에서 약 402와 0.04를 각각 나타내었다 $800^{\circ}C$에서 후속 열처리된 BLT박막의 경우 5V의 인가 전압에서 잔류분극 2Pr($Pr^{+}$-$Pr^{-}$)값은 약 32.5$\mu$C/$Cm^2$을 나타내었다.