• Title/Summary/Keyword: 부식 억제효과

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Dental Caries Suppression Effect and Other Physiological Properties of Erythritol (에리스리톨의 난충치성 및 기타 생리 특성)

  • Byun, Sang-Hee;Lee, Cherl-Ho
    • Korean Journal of Food Science and Technology
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    • v.30 no.2
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    • pp.446-449
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    • 1998
  • Dental caries suppression effect and other physiological properties of erythritol were measured in comparison with those of sucrose, xylitol and sorbitol. The susceptibility test for dental caries by using Streptococcus mutans KCTC 3065 and Lactobacillus acidophillus indicated that erythritol was as effective as xylitol in suppressing dental caries. In lactic acid fermentation test, erythritol showed the least growth of bacteria among the tested sweeteners. The tolelerance test by using mice showed that diarrhea began by feeding once 1500 mg erythritol/kg b.w., 1500 mg xylitol/kg b.w. and 1000 mg sorbitol/kg b.w. respectively.

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A Study on Anti-Corrosion Effect of Powder Self Water Proof Admixture Mixed Corrosion Inhibitor for Reinforcing Steel (철근부식억제형 구체방수재의 방청효과에 관한 연구)

  • 신도철;손형호;김원화
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.409-414
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    • 2002
  • This study is intended to develop the self water proof admixture for durability concrete by anti-corrosion inhibitor. Chloride induced corrosion of reinforcement is one of the main factor which cause the deterioration of concrete structure. When the substitute anti-corrosion agents for a part of self waterproofing agent, the corrosion-proof increases for the increased water proofing capacity. And proper self waterproofing agent by cement weight in concrete was generally positive effect to concrete compressive strength, slump, freezing and thawing resistance. Also, permeability and absorption show a straight decrease when self waterproofing agent is added.

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Effect of Cathodic Protection on Erosion-Corrosion Control in Alloy Metals of Marine Bearing (舶용 베어링 합금재의 침식-부식억제에 미치는 음극방식의 효과)

  • 임우조;이진열
    • Tribology and Lubricants
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    • v.11 no.1
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    • pp.58-65
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    • 1995
  • When marine lubricating oil began to be emulsified and oxidized through ingressive water that have leaked from cooling pump seal systems, cooler, purifier system and piping system, the cavitation erosion-corrosion in alloy metals of bearings remains to the various troublesome problem at effective engine performance. Therefore, applied the cathodic protection to the control test of cavitation erosion-corrosion, and appointed the marine system oil containing 3% sea water as test environments, with different conductibility. Also, used the piezoelectric vibrator with 20 KHz, 24 $\mu$m as the cavity generation apparatus, and examined the weight loss, potential value, current density etc. in specimens with those condition. According to this testing data, investigated influence of cathodic protection on the control characteristics of cavitation erosion-corrosion, and will serve those as an elementary design data of marine bearing.

Effects of anti-corrosion of the Al alloy film by the post-etch treatment (플라즈마 식각후 처리에 의한 Al alloy막의 부식 억제 효과)

  • 김환준;이철인;최현식;권광호;김창일;장의구
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.413-417
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    • 1997
  • In this study, chlorine(Cl)-based gas chemistry is generally used to etching for AlCu films metallization. The corrosion phenomena of AlCu films were examined with XPS (X-ray photoelectron spectroscopy), SEM (Scanning electron microscopy), and TEM (Transmission electron microscopy). SF$\sub$6/ plasma treatment subsequent to the etch process prevents the corrosion effectively in the pressure of 300 mTorr. It is found that the chlorine atoms on the etched surface are not substituted for fluorine atoms during SF$\sub$6/ treatment, but a passivation layer on the surface by fluorine-related compounds would be formed. The passivation layer prevents the moisture penetration on the SF$\sub$6/ treated surface and suppresses the corrosion successfully.

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Empirical study on inhibition effect of scale and rust in tap-water line by zinc ionization device (아연 이온화 장치에 의한 상수배관 내 스케일 및 녹 생성 억제효과 실증 연구)

  • Yum, Kyung-Taek;Choi, Jung-Wook;Yang, Sung-Bong;Shim, Hak-Sup;Yu, Mee-Seon
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.6
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    • pp.465-476
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    • 2021
  • Scale and rust generation in water pipes is a common phenomenon when cast iron water pipes have been used for a long time. A physical water treatment device is known among various means for suppressing rust in a water pipe, and a zinc ionization device for putting zinc metal into a pipe and emitting the zinc cation into water is one of such devices. This research measured the amount of zinc ion generated, which is known to exhibit an effect of inhibiting rust and scale generation in a pipe, and examined the scale and rust inhibition effect of the ionization device installed for ground or building water supply. In the case of distilled water, the concentration of zinc ion increased by circulating water in the ionization device several times, and it was verified to be hundreds of ㎍/L, and in the case of discharging ground or tap water, it was verified to be tens of ㎍/L. In addition, a verification pipe was installed to confirm the change inside the pipe before and after installation of the zinc ionization device, and the internal condition of the pipe was observed 3 months to several years after installation. It was confirmed that the corrosion area of the surface of the pipe was no longer increased by installing a corrosion inhibitor, and if the pipe was already filled with corrosion products, the amount of corrosion products gradually decreased every year after installation. The phenomenon of fewer corrosion products could be interpreted as expanding the space in the pipe due to the corrosion product as Fe2O3 adhered to the inner surface of the pipe and turned into a smaller black Fe3O4. In addition, we found that scale such as CaCO3 together in the corrosion by-products gradually decreased with the attachment of the ionization device.

A Study on Protection of Stainless Steel Substrate against Corrosion in Molten Carbonate by Formation of Aluminum Diffusive Layer Using a Slurry Coating Method (슬러리 코팅법에 의한 스테인레스 스틸 표면에서의 알루미늄 확산막 제조 및 용융탄산염 내에서의 내식 특성 연구)

  • Nam S. W.;Hwang E. R.;Magtanyuk A. P.;Hong M. Z.;Lim T. H.;Oh I. -H.;Hong S. -A.
    • Journal of the Korean Electrochemical Society
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    • v.3 no.3
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    • pp.136-140
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    • 2000
  • A stainless steel separator for a molten carbonate fuel cell is usually coated with aluminum diffusive layer to protect its surface against corrosion by the molten carbonate at high temperatures. In this study, a relatively simple method was devised to form the aluminum diffusive layer on a stainless steel substrate. Slurry coating of aluminum on the substrate followed by heat treatment under reducing atmosphere at $650\~800^{\circ}C$ produced the aluminum diffusive layer of $25\~80{\mu}m$ thickness. The thickness of aluminum diffusive layer increased with increasing the temperature or duration of the heat-treatment. The corrosion resistance against molten carbonate under oxidizing atmosphere was significantly improved by aluminum diffusive layer formed by the sluny painting and heat treatment method. Moreover, the sample prepared in this study showed corrosion behavior similar to the sample with aluminum diffusive layer prepared by ion vapor deposition and heat treatment.

Anti-Corrosion Behaviour of Rebar in Cement Mortar by Electrochemical Chloride Extraction (전기화학적 염소 추출법에 의한 시멘트 모르터내의 철근 방식)

  • Nam Sang Cheol;Lim Young Chang;Cho Won-Il;Cho Byung Won;Chun Hai Soo;Yun Kyung Suk
    • Journal of the Korean Electrochemical Society
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    • v.3 no.1
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    • pp.31-38
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    • 2000
  • Anti-corrosion behaviour of rebar embedded in cement mortar containing chloride ions was investigated by electrochemical chloride extraction(ECE). $43\%$ of the initial chloride ions of the cement mortar was fixed to Friedel salts and the soluble chloride ions were successfully extracted by ECE method. Concentration profiles of the chloride ions were estimated by Fick's 2nd law with time and depth, and it was close to the real value. The corrosion potential increased to anodic direction after ECE test, and the corrosion of rebar was reduced as a result of AC impedance spectroscopy.

Effect of Sulfuric Acid Addition on the Aluminum AC Etching in HCl Solution (염산용액내에 황산 첨가에 의한 알루미늄의 교류에칭 특성)

  • Kim, Hangyoung;Choi, Jinsub;Tak, Yongsug
    • Applied Chemistry for Engineering
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    • v.9 no.4
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    • pp.463-468
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    • 1998
  • When sulfuric acid was added in HCl etching solution, corrosion of aluminum metal was inhibited by the chemical adsorption of sulfate ions. In the presence of $SO_4^{-2}$, cyclic voltammetry showed that the protective oxide film was formed on the inner surfaces of etch pits and, pit density was increased by nucleation on both the aluminum surface and the pits inside. Structure and distribution of etch pits found in AC etching of aluminum were strongly influenced by the concentration of $SO_4^{-2}$ and the amount of cathodic pulse charging. Below $0.8mC/cm^2$ of cathodic pulse charging, oxide films formed inside actively dissolving pits indicated the higher resistance to pit nucleation as the concentration of $SO_4^{-2}$ increases. However, the structural change of oxide films occurred above the $0.8mC/cm^2$ charging and the effect of $SO_4^{-2}$ was minimized, and it resulted in the rapid formation of etch pits.

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Service Life Prediction and Cost Estimation of Repaired Concrete Structures Under Marine Environment (염해 환경 하 보수된 콘크리트 구조물의 사용수명 예측 및 보수 비용 평가)

  • Shim, Hyun Bo;Ann, Ki Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.1
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    • pp.226-234
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    • 2011
  • The service life of concrete structures exposed to a marine environment can be extended by controlling the amount of chloride in cover concrete. Patching is one of the appropriate maintenance techniques for chloride contamination. Chloride-contaminated cover concrete is removed and replaced with sound one. It can provide less risk of corrosion of steel, so that the structure can be maintained for required service life. In this study, a quantitative assessment of the service life subjected to the chloride attack is proposed to determine the effective repair options such as repair depth, repair material and timing of repair. The Crank-Nicolson based finite difference formulation from Fick's second law is proposed to predict the profiles of chloride ion in a repaired concrete structure, considering ingress of chloride from outer and redistribution of residual chloride from the substrate concrete. Therefore, the repair application times and maintenance cost for the target service life can be estimated. Finally, the numerical examples are presented to ensure its applicability.

The Effects of Scale Growth Inhibition on Water Pipe using Frequency Driver (Frequency Driver를 이용한 냉온수관의 스케일 방지억제효과)

  • Jang, Mi-Jeong;Sung, Il-Wha
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.4
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    • pp.258-266
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    • 2011
  • Scale induced by hardness materials in water must be controled because of it can be result in remarkable damages of pipeline as well as water quality deterioration. Especially hot water system is one of scale management required facility as scale formation can be accelerated by temperature. The scale control performance of frequency driver (FD) was tested instead of existing methods such as chemical, physical and electromagnetic methods which needs chemicals and electric power. Three kinds of pipe coupons were submerged in test water with 500 mg/L of hardness for 33 days and XRD and SEM were analysed for comparing scale formation characteristics of these coupons. Calcite ($CaCO_3$) which came from hardness of water was formed on only cast iron pipe coupon and this coupon showed higher corrosion rate than copper and stainless steel pipe coupon. Hot water circulating system connected cast iron pipe with and without FD was operated with 300 mg/L of hardness water at $50^{\circ}C$ for monitoring of scale formation and water quality with and without FD. XRD showed that FD leaded to magnetite ($Fe_3O_4$) scale which is good scale for preventing corrosion than calcite and SEM image also indicated the scale control effect of FD. Scales of 16% on pipe joint, 14% on pipe length, and 42% on heat exchanger decreased with FD comparing scales of those parts without FD. From the results of water quality, FD reduced crystallization of hardness material without chemical reaction in water and it can indicate that FD is safe and proenvironmental technology for scale reduction.