• Title/Summary/Keyword: 부식진행

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Experimental Studies on the Corrosion of Reinforcement Steel in Reinforced Concrete with Corrosion Inhibitors (방식재를 사용한 철근 콘크리트의 철근부식에 관한 실험적 연구)

  • Y.S Chung;G.H Han;Lee, G.G.;J.W. Jang;Park, E.K.
    • Magazine of the Korea Concrete Institute
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    • v.9 no.6
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    • pp.175-183
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    • 1997
  • 경제성장에 따른 항만구조물의 건설 및 유지관리에 관한 관심이 급격히 고조되고 있다. 이러한 항만구조물은 해양환경에 노출되어 콘크리트에 매입된 철근의 부식을 야기시키는 요인에 접해있다. 한편, 콘크리트 내부의 염분침투는 매입철근의 부식을 가속화시켜 콘크리트 구조물의 내구성에 상당히 큰 피해를 입힐 수 있다. 본 연구의 목적은 여러 가지 방식제를 사용함과 동시에 물/시멘트을 달리한 실험변수를 이용한 시험체에 대한 부식평가 및 매입철근의 적절한 부식방지 기법의 개발에 있다. 해양환경 조건을 simulation한 해수 및 담수 순환장치를 이용한 실내 시험체의 철근 부시도 평가 및 항만현장에 직접 거치된 시험체 등 다양한 조건하의 2년간의 실험이 현재 진행 중에 있다. 40주에 걸쳐 간헐 침투되는 해수조건에서 60개의 콘크리트 시험체의 철근 부시도 평가결과를 기초하여 180여개의 콘크리트 시험체를 새로이 제작하여 Half-Cell Test를 통한 Instant-Off Potential, Current Method를 통한 Corrosion current, Chloride Content 및 시험 종료후 시험체를 파쇄하여 부식된 철근의 무게측정등을 통하여 거동 및 부식을 예측.평가하고 이를 통한 부식방지기법을 개발하고자 한다.

플라즈마 공정용 산화막 코팅부품의 신뢰성평가에 관한 연구

  • Song, Je-Beom;Lee, Ga-Rim;Sin, Jae-Su;Lee, Chang-Hui;Sin, Yong-Hyeon;Kim, Jin-Tae;Gang, Sang-U;Yun, Ju-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.151-151
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    • 2013
  • 최근 반도체 및 디스플레이 산업에서의 플라즈마 공정의 중요성은 점점 증대되고 있다. 특히, 반도체/LCD 제조공정에서의 Dry Etch공정은 디스플레이용 유리 위에 형성된 산화막, 금속입자, 박막, 및 Polymer와 같은 불순물들을 플라즈마를 이용하여 제거하는 공정이다. 플라즈마 공정을 진행하는 동안 몇 가지 문제점들이 이슈가 되고 있다. Etch공정에서는 활성 부식가스를 많이 사용하고 장시간 플라즈마에 노출되기 때문에, 진공부품들은 플라즈마에 의해서 물리적인 이온충격(Ion Bombardment)과 화학적인 Radical 반응에 의한 부식이 진행된다. 부식영향에 의해 챔버를 구성하고 있는 부품에서 균열이 발생하거나 오염입자들이 떨어져 나오게 된다. 발생한 오염입자들은 산업용 플라즈마 공정에서 매우 심각한 문제가 되고 있다. 본 연구에서는 산화막의 부식 저항특성을 측정할 수 있는 평가방법에 대하여 고찰하였고, 표준화된 데이터로 비교분석할 수 있도록 평가기준과 규정화된 피막평가방법을 연구하였다. 또한, 산화막의 특성에 따른 플라즈마 상태, 오염입자 발생 등 플라즈마 공정을 진단하여 부품재료의 수명을 예측하고, 신뢰성 있는 평가방법에 관한 연구를 하였다.

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Corrosion Resistance Behaviour of Al-Mg Alloy Films according to Mg Contents Prepared by PVD Method (PVD법에 의해 제작한 Mg 함량 별 Al-Mg 합금막의 부식 및 방식 거동)

  • Lee, Seung-Hyo;Im, Gyeong-Min;Kim, Hye-Min;Jeong, Jae-In;Yang, Ji-Hun;Lee, Myeong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2013.05a
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    • pp.148-148
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    • 2013
  • 본 연구에서는 스퍼터링(sputtering)에 의해 Mg 함량을 달리하여 제작한 Al-Mg 합금막의 열처리 유 무별 부식 및 방식 거동을 확인하고자 내식성 평가 및 분석을 실시하였다. 내식성 평가는 염수분무시험을 통해 이루어졌으며, 염수분무시험 후 생성된 부식생성물은 SEM, EDS, XRD 평가 기법을 이용하여 초기 중기 후기 단계로 나누어서 분석을 실시하였다. 이상의 결과를 통해서 부식 진행 단계 별로 내식성에 미치는 부식생성물의 영향을 확인할 수 있었으며, Mg 함량에 따른 열처리 유 무 별 Al-Mg 합금막의 방식 메커니즘을 규명할 수 있었다.

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EIS monitoring on corroded reinforcing steel in cement mortar after calcium electro-deposition treatment (칼슘 전착처리 후, 시멘트 모르타르 속 철근의 부식속도에 대한 EIS 모니터링)

  • Kim, Je-Kyoung;Kee, Seong-Hoon;Yee, Jurng-Jae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.7
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    • pp.1-8
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    • 2019
  • The primary purposes of this study are to understand a fundamental effects of electro-deposition on reinforcing steel in saturated Ca(OH)2 electrolyte, and evaluate the corrosion rates of rebars under cyclic 3wt.%NaCl immersion and dry corrosion environment. The three cement mortar specimens with cover thickness 5, 10 and 30mm, were prepared in the experiment. To monitor the corrosion rates of rebars in mortar, the three cement mortar specimens were exposed to 110 wet-drying cycles(8-hour-immersion in 3wt.%NaCl and 16-hour-drying in a room temperature) in the laboratory. During the wet-dry cycles, the polarization resistance, Rp, and solution resistance, Rs, were continuously measured. The instantaneous corrosion rates of rebars on the effect of electro-depositing with sat. Ca(OH)2 electrolyte were estimated from obtained R-1p and degrees of wetness were estimated from Rs values. From the experimental results, the corrosion rates of rebars were greatly accelerated by wet/dry cycles. During the mortars exposed to drying condition, the large increases in the corrosion rates were showed at all rebar surfaces in three mortar specimen, attributed from the accelerated reduction rates of dissolved oxygen in drying process. However, the corrosion rates on rebar surface electrochemically deposited with sat. Ca(OH)2 electrolyte showed the clear decreases, caused by calcium deposits in the porous rust layer.

Evaluation of Load-Carrying Capacity Loss due to Corrosion in Thin-Walled Section Steel Members (판폭두께비가 큰 휨부재의 부식발생에 따른 구조성능평가에 관한 연구)

  • Chung, Kyung Soo;Park, Man Woo
    • Journal of Korean Society of Steel Construction
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    • v.21 no.6
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    • pp.619-626
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    • 2009
  • The use of thin-walled flexural members has proven to be a practical way to achieve the lowest cost in the construction of prefabricated long-span, low-rise building frames in steel. On the other hand, most of these structures are subjected to corrosion due to environmental exposure, which can reduce their carrying capacity. Corrosion damage is a serious problem for these structures as it causes thickness loss. That is, the class of a section (plastic, compact, non-compact, or slender) may change from one to another due to the loss of thickness of the compression flange and web due to corrosion. In this study, the effects of corrosion on thin-walled members in long-span steel frames were evaluated with regard to the moment-rotation curve, initial stiffness, maximum load capacity, stiffness in the post-maximum capacity, and energy absorption.

The metal corrosion caused by museum indoor air pollutants (박물관 실내 대기오염물질에 의한 금속 부식 영향)

  • Kang, Dai-Ill
    • Journal of Conservation Science
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    • v.22
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    • pp.5-14
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    • 2008
  • The effect of air pollutants coming from internal museum materials such as wood-based products and cements on metal corrosion have been investigated. The Oddy test and the Chamber test was employed as a corrosion test. The metal pieces after the Oddy test had different corrosion types caused by the internal museum materials. The most effective wood based product was 18T HS(E0) and 9mm plywood(F0,E0). Iron(Fe) and copper(Cu) also bronze of the Chamber test had corrosion caused by Formic acid, Acetic acid, and Acetaldehyde. The packing materials in high humidity had caused more corrosion on the surface of the metal pieces than in low humidity.

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Prediction of Concrete Corrosion using Electrodchemical Technique (전기화학적인 콘크리트 부식의 예측)

  • 이종권;박지환
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.3 no.2
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    • pp.80-83
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    • 2002
  • The effect of chloride content on the corrosion of reinforced bar in concrete was studied. The mixing ratio of the concrete was 1 : 1.78 : 5.35 : 4.73 (water : content : ballast : sand). The studied chloride content was in the range of 0∼3.5 wt%. The corrosion potentials were measured in every week for two years. The copper-copper sulfate electrode (CSE) was employed as a reference electrode. After two years, the corroded structure was examined and compared to measured corrosion potential. Any visible difference was founded in the specimen located indoor and outdoor. The chloride concentration enhanced rusting and reinforced bar, shifting the potential to active range. The results showed good argument with Van daveer criteria. In 3.5 wt% chloride, the potential shifted belong -350 mV after 58week. Specimen in 1.75 wt% chloride, showed the potential between -200 mV∼-350 mV. However those in free chloride solution maintained above -200 mV for the studied period. It can the concluded that the chloride enhanced corrosion of rebar in concrete and the electrochemical potential can be a promising corrosion monitoring technique.

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A Study on the Temporal Correlation of Long-term Exposure Test and Accelerated Corrosion Test of Rebar (장기폭로 시험과 철근 부식 촉진시험의 시간적 상관성에 관한 연구)

  • Lee, Min-Woo;Park, Sang-Soon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.4
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    • pp.307-313
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    • 2014
  • Recent interest in the increased structural performance and durability evaluation of this concrete structure in a salt damage environment is increasing. The most secure and reliable method of accelerated corrosion test is a method to carry out the rebar corrosion monitoring can be exposed directly to the marine test site exposure. However, long-term exposure testinghas the disadvantage that a long period is necessary. So, a lot of research on RC of salt damage environment have beenpromoted as alternatives to replace this. However, accelerated corrosion test, in the short term only is appropriate and is but an accelerated test method to evaluate the critical chlorine concentration, there is a difficult problem that you still get the answer. It is one of the correlation problems accelerated test correspond to a certain period of exposure environment. Therefore, in this study, to clarify the differences rebar corrosion beginning, through the actual corrosion accelerated test in corrosion time and laboratory test chamber of the structure of the marine environment results in both environments, it is an object of correlation coefficient derived.

A Probabilistic Corrosion Rate Estimation Model for Longitudinal Strength Members of Tanker Structures (유조선 종강도부재의 확률론적 부식속도 예측모델의 개발)

  • Jeom-Kee Paik;Young-Eel Park
    • Journal of the Society of Naval Architects of Korea
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    • v.35 no.2
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    • pp.83-93
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    • 1998
  • The twin aims of the present study are to develop a PC program for the statistical analysis of the measured cohesion data and to suggest a probabilistic corrosion rate estimation model for longitudinal members of tanker structures. A data analysis for the corrosion rate statistics(i.e., mean, standard deviation) as a function of the corrosion parameters is established for various structural member categories/locations of interest. Development of the computer program is focused on possible operation together with future addition of more corrosion data as they become available. To investigate the influence of the corrosion protection scheme a series of the corrosion analysis varying the life of coating are carried out and several different corrosion models as a function of time are suggested depending on the coating life.

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Evaluate the Concrete mix by Type Accelerated Corrosion Test and Chloride Penetration Analysis with Artificial Seawater Cyclic Wet and Dry Condition (인공해수 건습반복조건에 따른 콘크리트배합별 부식촉진시험법과 염화물 침투해석평가)

  • Park, Sang-Soon;Kim, Min-Wook
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.3
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    • pp.211-218
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    • 2013
  • Cyclic wet and dry conditions in the marine environment structures corrosion is known to be the fastest rising. For that reason, accelerated corrosion test methods for the reproduction of tidal environment has been actively conducted. However, many studies have estimated threshold value for steel corrosion or concentrated in chloride penetration analysis. In this study, cyclic wet and dry conditions to reproduce the structure of the environment in accelerated corrosion and chloride penetration test analysis was performed. Corrosion was determined by the result of reinforcement corrosion monitoring based on galvanic potential measurement and half-cell potential method. Accelerated corrosion test results for each formulation was different corrosion periods, the order OPC> FA> BS> High-strength concrete. FEM durability interpretation program DuCOM was conducted under the same conditions as in accelerated corrosion test. The experimental RCPT tests demonstrated the validity of the result.