• Title/Summary/Keyword: 부식조건

Search Result 528, Processing Time 0.027 seconds

Corrosion Behavior of Mg-aSn-bZn Alloy Extrusions (Mg-aSn-bZn 합금 압출재의 부식거동)

  • Im, Chang-Dong;U, Sang-Gyu;Yu, Bong-Seon
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2015.05a
    • /
    • pp.37-37
    • /
    • 2015
  • 합금 조성 및 열-기계적 처리 조건에 따라 제2상의 종류, 분율, 크기 등이 변화하였으며, 이러한 미세조직적 인자의 변화에 따라 부식거동이 변화하였다. 또한 부식환경에 따라 부식거동에 영향을 미치는 여러 인자들의 상호작용이 변화하였으며 이로 인하여 서로 다른 부식환경에서 합금 조성에 따른 부식거동의 차이가 발생하였다.

  • PDF

Numerical Analysis of the Bests Protective Condition Estabilishment in the Power Plant Condenser (발전소 복수기의 최적 방식조건 설정에 관한 수치해석 연구)

  • Kim, Jang-Sun;Kim, Ui-Hyeon;Kim, Jong-Yeong
    • Korean Journal of Materials Research
    • /
    • v.6 no.4
    • /
    • pp.401-411
    • /
    • 1996
  • 전기방식법중의 하나인 음극방식법은 많은 해수설비를 갖추고 있는 발전소에 적용되고 있는 설비지만 운용의 측면에서는 적절하지 못한 방식조건으로 많은 문제점이 노출되고 있다. 본 연구에서는 설비지만 운용의 측면에서는 적절하지 못한 방식조건으로 많은 문제점이 노출되고 있다. 본 연구에서는 해수설비중의 하나인 발전소 복수기의 음극방식설비를 해석 대상으로 하여 가장 많이 사용되는 희생양극 재질인 Zn 양극을 입구측 파이프, 수실벽 및 천장등 여러위치에 부착한 경우 전위분포 및 전류밀도분포를 구하여 최적방식조건을 찾아보았다. 또한 전류밀도값을 Faraday 법칙을 이용부식속도로 환산하여 galvanic 부식정도와 방식정도를 평가하였다. 그 결과 희생양극을 galvanic 부식이 심하게 일어날 것으로 예상되는 위치에 부착하면 방식효과가 가장 크게 나타남을 알 수 있었다.

  • PDF

The metal corrosion caused by museum indoor air pollutants (박물관 실내 대기오염물질에 의한 금속 부식 영향)

  • Kang, Dai-Ill
    • Journal of Conservation Science
    • /
    • v.22
    • /
    • pp.5-14
    • /
    • 2008
  • The effect of air pollutants coming from internal museum materials such as wood-based products and cements on metal corrosion have been investigated. The Oddy test and the Chamber test was employed as a corrosion test. The metal pieces after the Oddy test had different corrosion types caused by the internal museum materials. The most effective wood based product was 18T HS(E0) and 9mm plywood(F0,E0). Iron(Fe) and copper(Cu) also bronze of the Chamber test had corrosion caused by Formic acid, Acetic acid, and Acetaldehyde. The packing materials in high humidity had caused more corrosion on the surface of the metal pieces than in low humidity.

  • PDF

On the Etching Condition of Cellulose Nitrate Solid State Nuclear Track Detector (SSNTD) (Cellulose Nitrate 고체비적검출기(固體飛跡檢出器)의 부식조건(腐蝕條件))

  • Myung, Dong-Bum;Jun, Jae-Shik
    • Journal of Radiation Protection and Research
    • /
    • v.12 no.1
    • /
    • pp.26-33
    • /
    • 1987
  • An experimental study for an optimum etching of commercialized cellulose nitrate SSNTD, CA 80-15 and LR 115-1 for detecting alpha particles, was carried out. Alt-hough ordinary etching condition of the detectors has been recommended by the producer, a remarkable discrepancy in etching tine was found. The detectors were irradiated with a $0.1{\mu}Ci\;^{241}Am$ alpha source under a known geometrical arrangement. Analysis on the track size as functions of etching time and etchant concentration and comparative examination of theoretically predicted number of tracks per unit area with that recorded on the detectors were made, including a study on the variation of detection efficiency with the effective energy of the incident alpha particles.

  • PDF

Changes in Corrosion Progress and Ultimate load of Tendon Under 20% and 40% of Ultimate Loading Conditions (파괴하중의 20% 및 40% 인장조건에서 텐던 부식 진행 및 파괴하중 변화)

  • Ryu, Hwa-Sung;An, Gi Hong;Hwang, Chul-Sung;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.21 no.4
    • /
    • pp.47-52
    • /
    • 2017
  • PSC (Prestressed Concrete) structures have been used widely for its engineering advantage with using total concrete area as effective compressive section. However tendon inside is exposed to such a high tensile stress that and more attentions should be paid for corrosion control. This work is for changing corrosion current and ultimate strength in tendon with increasing prestressing force in a constant corrosive condition. With increasing prestressing force, corrosion current, corrosion amount, and ultimate load are changed linearly. When prestressing force increases from 20.0 % to 40.0 %, corrosion current increases to 124.4 % and 168.0 % and ultimate load decreases to 87.8 % and 78.4 %, respectively. With inducing constant electrical potential, increasing corrosion current and reduction of strength are evaluated to be linearly related with increasing prestressing load.

Environmental Effect on Corrosion Behaviour of Zr-2.5Nb Alloy (Zr-2.5Nb 합금의 부식거동에 미치는 부식 매질 효과)

  • Ju, Gi-Nam;Gwon, Sang-Cheol;Kim, Yeong-Seok
    • Korean Journal of Materials Research
    • /
    • v.8 no.1
    • /
    • pp.3-9
    • /
    • 1998
  • 40$0^{\circ}C$ H$_{2}$O, D$_{2}$O및 $O_{2}$분위기에서 Zr-2.5Nb합금의 부식거동을 분석하였다. Martensitic $\alpha$'-Zr상이나 $\alpha$-Zr과 $\beta$-Zr상의 Zr-2.5Nb합금인 경우, 부식분위기에 매우 민감하여, $O_{2}$속에서 가장 큰 부식속도를 보였다. 반면, $\alpha$-Zr나 $\beta$-Zr상의 경우, 부식 매질에 따른 별다른 차이없이 높은 부식저항성을 보였다. 이러한 Zr-2.5Nb 합금의 미세조직 및 부식 매질에 따른 부식거동변화는 Zr-2.5Nb 합금의 음극 지배 부식반응의 관점으로 해석되었으며, 이들 결과를 이용하여 CANDU 형및 RBMK 형 Zr-2.5Nb 압력관의 가동조건 차이를 설명할 수 있었다. Zr-2.5Nb 합금의 모든 조직에서 주로 단사정 ZrO$_{2}$산화물이 형성되었으며, 산화물내 정방정 ZrO$_{2}$비율은 산화물 두께가 증가함에 따라 감소하였다.

  • PDF

A Study on the Temporal Correlation of Long-term Exposure Test and Accelerated Corrosion Test of Rebar (장기폭로 시험과 철근 부식 촉진시험의 시간적 상관성에 관한 연구)

  • Lee, Min-Woo;Park, Sang-Soon
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.2 no.4
    • /
    • pp.307-313
    • /
    • 2014
  • Recent interest in the increased structural performance and durability evaluation of this concrete structure in a salt damage environment is increasing. The most secure and reliable method of accelerated corrosion test is a method to carry out the rebar corrosion monitoring can be exposed directly to the marine test site exposure. However, long-term exposure testinghas the disadvantage that a long period is necessary. So, a lot of research on RC of salt damage environment have beenpromoted as alternatives to replace this. However, accelerated corrosion test, in the short term only is appropriate and is but an accelerated test method to evaluate the critical chlorine concentration, there is a difficult problem that you still get the answer. It is one of the correlation problems accelerated test correspond to a certain period of exposure environment. Therefore, in this study, to clarify the differences rebar corrosion beginning, through the actual corrosion accelerated test in corrosion time and laboratory test chamber of the structure of the marine environment results in both environments, it is an object of correlation coefficient derived.

The Corrosion Behavior of Hydrogen-Charged Zircaloy-4 Alloys (수소 장입된 Zircaloy-4 합금에서의 부식거동)

  • Kim, Seon-Jae;Kim, Gyeong-Ho;Baek, Jong-Hyeok;Choe, Byeong-Gwon;Jeong, Yo-Hwan
    • Korean Journal of Materials Research
    • /
    • v.8 no.3
    • /
    • pp.268-273
    • /
    • 1998
  • Standard Zircaloy-4 sheets, charged with 230-250ppm hydrogen by the gas-charging method and homogenized at $400^{\circ}C$ for 72hrs in a vacuum, were corroded in pure water and aqueous LiOH solutions using static autoclaves at $350^{\circ}C$. Their corrosion behaviors were characterized by measuring their weight gains with the corrosion time and observing their microstructures using an optical microscope and a scanning electron microscope. The elemental depth profiles for hydrogen and lithium were measured using a secondary ion mass spectrometry(S1MS) to confirm their distributions at the oxidelmetal interface. The normal Zircaloy-4 specimens corroded abruptly and heavily at the concentration of Li ions more than 30ppm in the aqueous solution. This is due to accelerations by the rapid oxidation of many Zr- hydrides formed by the large amount of absorbed hydrogen, resulting from the increased substitution of $Li^{+}$ ions with $Zr^{4+}$-sites in the oxide as the Li ion concentration increased. The specimens that had been charged with amounts of hydrogen greater than its solubility corroded early with a more rapid acceleration than normal specimens, regardless of the corrosion solutions. At longer corrosion times. however, normal specimens showed a rather accelerated corrosion rate compared to the hydrogen-charged specimens. These slower corrosion rates of the hydrogen-charged specimens at the longer corrosion times would be due to the pre-existent Zr-hydride in the matrix, which causes the hydrogen pick- up into the specimen to be depressed, when the oxide with an appropriate thickness formed.

  • PDF

Influence of Starvation and Humic Acid on Soil Microbial 2- Hydroxypyridine Metabolism (토양 미생물의 2-hydroxypyridine 대사에 미치는 기아상태와 부식산의 영향)

  • 황선형
    • Journal of Korea Soil Environment Society
    • /
    • v.4 no.1
    • /
    • pp.13-23
    • /
    • 1999
  • In this research, 3-hydroxypyridine(2-HP) metabolic ability of starving Arthrobacter crystallopoietes cell and the effect of humic acid on the metabolism of this starving cell were evaluated. 2-HP metabolic ability of exponential phase cell (acclimated cell) was much higher than that of lag phase cell (unacclimated cell) during starvation period. After 3 days of starvation, 2-HP half-life of the acclimated cell was 14 hours and that of the unacclimated cell was 46.5 hours. Humic acid enhanced the stability of 2-HP monooxygenase of starving co]1 and, after 2 days of starvation, the residual activity rate of this enzyme of the microbial cell starved in humic acid solution was 12% while the rate for control condition was 1.5%. After 14 days of starvation, 2-HP half-life for control condition was 43 hours and that for humic acid condition was 1.25 hour.

  • PDF

A Study on Particle Size Distribution at High Pressure (고압에서 입자크기 분포 연구)

  • Ku, Hee-Kwon;Park, Byung-Gi;Kim, Jong-Yung;Jeong, Eun-Sun
    • Proceedings of the KAIS Fall Conference
    • /
    • 2008.11a
    • /
    • pp.347-349
    • /
    • 2008
  • 발전소 물/증기 순환계통의 주요 기기인 증기발생기/보일러는 금속산화물과 각종 불순물이 축적되면 전열관이 손상되므로, 증기발생기/보일러 내부로 최소의 슬러지가 유입되고, 증기발생기 내부에서 금속산화물 입자가 형성되는 것을 억제하기 위해 수질관리를 하고 있으며, 증기발생기 내부에 존재하는 슬러지를 배출하기 위해 Blowdown 및 Sludge Lancing 등의 물리적 방법을 이용하는 기술이 개발되어 있다. 그러나 이러한 관리에도 불구하고 슬러지 성분인 금속산화물 농도는 운전 조건에 따라 매우 다르며(불순물 잠복 및 방출 현상), 아직까지 잠복현상에 대한 기본적인 메커니즘은 완전히 규명되고 있지 않다. 본 연구에서는 물/증기 순환계통 부식생성물의 물성 평가를 하기 위해 순환계통 기기들과 배관 부식생성물의 대부분인 철분이 부식에 가장 큰 영향을 미치기 때문에, 수화학 조건 및 금속합금 종류에 따라 생성되는 부식생성물을 철분을 중심으로 하여 실험하였고, 또한 부식생성물은 온도에 의해서도 영향을 많이 받기 때문에 다양한 온도에서도 부식생성물 생성 실험을 하였다.

  • PDF