• Title/Summary/Keyword: 부식인자

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Time-dependent characteristics of chloride diffusion coefficient of concrete (콘크리트 염소이온 확산계수의 시간 의존적 특성)

  • Choi, Sung;Lee, Kwang-Myong;Shin, Kyung-Joon;Bae, Su-Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.545-548
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    • 2008
  • As the corrosion of reinforcing bar in concrete structures exposed to chloride attack is one of main factors to determine the remaining service life, marine concrete structures have to be designed to protect the chloride penetration. Among the durability design methods such as deterministic method and probabilistic method, design method based on the probabilistic theory has been widely studied. However, the most essential material, data of the material properties related to chloride diffusion, are still insufficient. In this paper, the probabilistic distribution of chloride diffusion coefficients and aging coefficients are derived by the experiment and analysis for the chloride coefficients of concrete containing pozzolans, which are generally used in marine structures.

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Optimum design and performance of marine sea water pump with impeller using CFRP (CFRP 임펠러를 사용한 선박용 해수펌프의 최적설계와 성능특성)

  • Jeong, Seon Yong;Rhi, Seok Ho;Seo, Hyoung Seock;Lee, Kye Bock
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.11
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    • pp.7878-7884
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    • 2015
  • Marine sea water pump with impeller using carbon fiber block was developed to prevent the impeller corrosion by the salinity. A numerical analysis was carried out in order to optimize the impeller and volute design for marine sea water pump and to investigate the sensitivity of the related parameters(impeller thickness, surface roughness) using CFD commercial code. The impeller thickness is limited because of the weight. Since the impeller using the carbon fiber lights, the thickness which has a maximum efficiency can be used. The results show that the surface roughness leads to an 7% reduction in pump efficiency.

A Study on Water Quality Prediction for Climate Change Using Watershed Model in Andong Dam Watershed (유역모형을 이용한 기후변화에 따른 안동댐 유역의 미래 수질 예측)

  • Noh, Hee-Jin;Kim, Young-Do;Kang, Boo-Sik;Yi, Hye-Suk
    • Proceedings of the Korea Water Resources Association Conference
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    • 2012.05a
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    • pp.945-945
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    • 2012
  • 본 연구에서는 낙동강 수계의 안동댐 유역을 대상지역으로 선정하여 미래 기후변화 시나리오에 따른 댐 유역의 수환경 영향을 예측해 보고자 하였다. 특히 미래기후에 대한 수환경 평가는 기후자료를 입력 값으로 요구하는 강우-유출모형을 이용하거나 유량 이외에 유사, 영양물질과 같은 수질인자를 동시에 모의할 수 있는 유역모형을 이용하여 평가하는 것이 일반적이다. 이를 위해 선행연구로 IPCC(Intergovernmental Panel on Climate Change)에서 제공하는 AR4 시나리오의 RCM 자료를 ANN(Artificial Neural Network)기법을 이용하여 안동댐 유역의 총 4개 기상관측소에 대한 과거 20년(1991~2010) 실측자료를 바탕으로 미래 강수 및 습도 그리고 온도에 대해 상세화 하여 미래 기후 시나리오를 생산하였다. 또한 안동댐 유역 단위의 수질을 예측하기 위해 토양과 토지이용 및 토지관리 상태에 따른 수문-수질 모의가 가능한 유역모형인 SWAT(Soil and Water Assessment Tool)을 이용하였다. 과거의 기상자료와 수질자료를 이용하여 유역모델의 검 보정을 실시하였으며 모형의 보정 및 검증결과에 따른 적합성과 상관성을 판단하기 위해 결정계수($R^2$)와 평균제곱근오차(Root Mean Square Error, RMSE)를 사용하였으며, 모형의 효율성 검증으로는 Nash and Sutcliffe(1970)가 제안한 모형효율성계수(NSE)를 사용하였다. 최종적으로 기후 시나리오에 대해서 전망된 지역상세기후를 유역모형의 입력자료로 이용하여 안동댐 유역의 미래수문 및 수질을 예측하고자 하였다.

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Variables of Electrolytic Nickel Plating for RPV Cladding Repair (압력용기 클래드 보수용 전해니켈도금 인자 관계 연구)

  • Kim, Min-Su;Hwang, Seong-Sik;Kim, Dong-Jin;Lee, Dong-Bok
    • Corrosion Science and Technology
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    • v.18 no.4
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    • pp.148-153
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    • 2019
  • Pure nickel with a thickness of 1 mm was plated on type 304 stainless steels and low alloy steels (JIS G3131 SPHC) by electrolytic plating method in a circulating plating bath. Plating performance, mechanical properties, and surface characteristics were evaluated in terms of pretreatment process, anode material, pH, current density, and flow rate of the plating solution. Addition of hydrochloric acid during pre-treatment process improved the adhesion performance of plating. To improve plating efficiency, it is desirable to use S-nickel rather than electrolytic nickel. The use of S-nickel was also confirmed to be desirable for maintaining the pH and concentration of the plated solution. The defect of the plating using S-nickel anode produced pit on the surface. However, it is believed that proper control can be obtained by increasing the flow rate. Internal stress and hardness values of electrolytic nickel plating according to current density need to be carried out with further studies.

Statistical Evaluation of Factors Affecting IASCC of Austenitic Stainless Steels for PWR Core Internals (오스테나이트계 스테인리스강 노내 구조물의 조사유기응력부식균열 영향 인자에 대한 통계적 분석)

  • Kim, Sung-Woo;Hwang, Seong-Sik;Kim, Hong-Pyo
    • Korean Journal of Metals and Materials
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    • v.47 no.12
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    • pp.819-827
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    • 2009
  • This work is concerned with a statistical analysis of factors affecting the irradiation-assisted stress corrosion cracking (IASCC) of austenitic stainless steels for core internals of pressurized water reactors (PWR). The microstructural and environmental factors were reviewed and critically evaluated by the statistical analysis. The Cr depletion at grain boundary was determined to have no significant correlation with the IASCC susceptibility. The threshold irradiation fluence of IASCC in a PWR was statistically calculated to decrease from 5.799 to 1.914 DPA with increase of temperature from 320 to $340^{\circ}C$. From the analysis of the relationship between applied stress and time-to-failure of stainless steel components based on an accelerated life testing model, it was found that B2 life of a baffle former bolt exposed to neutron fluence of 20 and 75 DPA was at least 2.5 and 0.4 year, respectively, within 95% confidence interval.

Identifying Factors Affecting Surface Roughness with Electropolishing Condition Using Full Factorial Design for UNS S31603 (UNS S31603에 대하여 완전요인설계를 이용한 전해연마조건에 따른 표면 거칠기의 유효인자 산출)

  • Hwang, Hyun-Kyu;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.21 no.4
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    • pp.314-324
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    • 2022
  • The objective of this investigation was to indentify major factors affecting surface roughness among various parameters of electropolishing process using the design of an experiment method (full factorial design) for UNS S31603. Factors selected included electrolyte composition ratio, applied current density, and electrolytic polishing time. They were compared through analysis of variance (ANOVA). Results of ANOVA revealed that all parameters could affect surface roughness, with the influence of electrolyte composition ratio being the highest. As a result of surface analysis after electropolishing, the specimen with the deepest surface damage was about 35 times greater than the condition with the smallest surface damage. The largest value of surface roughness after electropolishing was higher than that of mechanical polishing due to excessive processing. On the other hand, the smallest value of surface roughness after electropolishing was 0.159 ㎛, which was improved by more than 80% compared to the previous mechanical polishing. Taken all results together, it is the most appropriate to perform electrolytic polishing with a sulfuric acid and phosphoric acid ratio of 3:7, an applied current density of 300 mA/cm2, and anelectrolytic polishing time of 5 minutes.

Theoretical Analysis of Critical Chloride Content in (Non)Carbonated Concrete Based on Characteristics of Hydration of Cement (시멘트 수화 특성 및 탄산화를 고려한 콘크리트의 임계 염소이온량에 대한 해석 기법)

  • Yoon, In-Seok
    • Journal of the Korea Concrete Institute
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    • v.19 no.3
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    • pp.367-375
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    • 2007
  • Critical chloride content for corrosion initiation is a crucial parameter in determining the durability and integrity of reinforced concrete structures, however, the value is still ambiguous. Most of the studies reporting critical threshold chloride content have involved the experimental measurement of the average amount of the total chloride content at arbitrary time. The majority of these researches have not dealt with this issue combined with carbonation of concrete, although carbonation can significantly impact on critical threshold chloride content. Furthermore, the studies have tried to define the critical chloride content within the scope of their experimental concrete mix proportion at arbitrary time. However, critical chloride content for corrosion initiation is known to be affected by a lot of factors including cement content, type of binder, chloride binding, concentration of hydroxyl ions, and so on. It is necessary to define the unified formulation to express the critical chloride content for various mix proportions of concrete. The purpose of this study is to establish an analytical formulation of the critical chloride content of concrete. In this formulation, affecting factors, such as mix proportion, environment, chemical evolution of pore solution with elapsed time, carbonation of concrete and so on are taken into account. Based on the Gouda's experimental results, critical chloride content is defined as a function of $[Cl^-]$ vs. $[OH^-]$ in pore solution. This is expressed as free chloride content with mass unit to consider time evolution of $[OH^-]$ content in pore solution using the numerical simulation programme of cementitious materials, HYMOSTRUC. The result was compared with other experimental studies and various codes. It is believed that the approach suggested in this study can provide a good solution to determine the reasonable critical chloride content with original source of chloride ions, for example, marine sand at initial time, and sea water penetration later on.

The Outcome of Conventional External Beam Radiotherapy for Patients with Squamous Cell Carcinoma of the Esophagus (식도의 편평상피세포암 환자에서 외부방사선치료의 결과)

  • Jang, Ji-Young
    • Radiation Oncology Journal
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    • v.26 no.1
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    • pp.17-23
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    • 2008
  • Purpose: The best treatment for advanced esophageal cancer is chemoradiotherapy followed by surgery. In spite of the advance of multimodality therapy, most patients with esophageal cancer are treated with radiation therapy alone. This study reports the outcome of the use of conventional external beam radiotherapy alone for the treatment of esophageal cancer. Materials and Methods: Between January 1998 and December 2005, 30 patients with squamous cell carcinoma of the esophagus were treated with external beam radiotherapy using a total dose exceeding 40 Gy. Radiotherapy was delivered with a total dose of 44-60 Gy(median dose, 57.2 Gy) over $36{\sim}115$ days(median time, 45 days). Thirteen patients(43.3%) had a history of disorders such as diabetes, hypertension, tuberculosis, lye stricture, asthma, cerebral infarct, and cancers. Four patients metachronously had double primary cancers. The most common location of a tumor was the mid-thoracic portion of the esophagus(56.7%). Tumor lengths ranged from 2 cm to 11 cm, with a median length of 6 cm. For AJCC staging, stage III was the most common (63.3%). Five patients had metastases at diagnosis. Results: The median overall survival was 8.3 months. The survival rates at 1-year and 2-years were 33.3% and 18.7%, respectively. The complete response rate $1{\sim}3$ months after radiotherapy was 20%(6/30) and the partial response rate was 70%(21/30). Sixteen patients(53.3%) had an improved symptom of dysphagia. Significant prognostic factors were age, tumor length, stage, degree of dysphagia at the time of diagnosis and tumor response. Cox regression analysis revealed the aim of treatment, clinical tumor response and tumor length as independent prognostic factors for overall survival. Twenty-eight patients had local failure and another four patients had metastases. Three patients were detected with double primary cancers in this analysis. A complication of esophageal stricture was observed in three patients(10%), and radiation pneumonitis occurred in two patients(6.7%). Conclusion: The prognosis of esophageal cancer remains poor, in spite of advances in radiotherapy techniques. Radiotherapy is one of the main treatment modalities for the relief of dysphagia and treatment related complications are minimal. It is expected that the addition of chemotherapy or another systemic modality to radiotherapy will improve tumor control and increase the survival rate in advanced esophageal cancer.

Modeling of Chloride Ingress in Reinforced Concrete Structures (철근 콘크리트 구조물의 염소이온 침투 모델)

  • Koo, Hyun-Bon;Kim, Eui-Tae;Lee, Kwang-Myong
    • Journal of the Korea Concrete Institute
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    • v.15 no.1
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    • pp.25-34
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    • 2003
  • The degradation of reinforced concrete (RC) structures due to physical and chemical attacks has been a major issue in construction engineering. Deterioration of RC structures by chloride attack followed by reinforcement corrosion is one of the serious problems. An objective of this study is to develop a form of mathematical model of chloride ingress into concrete. In order to overcome some limits of the previous approaches, a chloride ingress model, consisting of chloride solution intrusion through the capillary pore and chloride ion diffusion through the pore water, was proposed. Moreover, the variability of chloride ion diffusivity due to the degree of hydration of cement, relative humidity in pore, exposure condition, and variation of chloride binding, was considered in the model. In order to verify the proposed model, the results predicted by the proposed model were compared with analysis results of Life-365, a computer program for predicting the service life of reinforced concrete structures exposed to chlorides. In conclusion, the proposed model would be promising to predict the chloride ion profile and to estimate the service life of RC structures.

Flexural Strength Analysis of RC T-Beams Strengthened Using Fiber Sheets (섬유시트로 보강된 T형 철근콘크리트보의 휨 강도 해석)

  • Park, Tae-Hyo;Lee, Gyu-Chul
    • Journal of the Korea Concrete Institute
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    • v.15 no.2
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    • pp.234-245
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    • 2003
  • Most of the concrete bridge structures are exposed to damage due to the excessive traffic loading and the aging of the structure. The damage of concrete causes the further deterioration of the function in the concrete structure due to corrosion of the reinforced bars and decohesion between the concrete and the reinforced bar. The quick rehabilitation of the damaged concrete structures has become of great importance in the concrete structural system in order to avoid the further deterioration of the structures. Recently fiber sheets are used for strengthening the damaged concrete structures due to its many advantages such as its durability, non-corrosive nature, low weight, ease of application, cost saving, control of crack propagation, strength to thickness ratio, high tensile strength, serviceability and aesthetic. However, the lack of analytical procedures for assessing the nominal moment capacity by the fiber sheet reinforcement leads to difficulties in the effective process of decisions of the factors in the strengthening procedure. In this work, flexural strengthening effects by fiber sheets bonded on bottom face of the member are studied for the reinforced concrete T beam. In addition, auxiliary flexural strengthening effects by U-type fiber sheets bonded on bottom and side faces of the member to prevent delamination of the bottom fiber sheet are theoretically investigated. The analytical solutions are compared with experimental results of several references to verify the proposed approach. It is shown that the good agreements between the predicted results and experimental data are obtained.