• Title/Summary/Keyword: 부식모델

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Corrosion Mechanism of Zr-based Alloys in LiOH Solution (Zr합금의 LiOH 용액에서 부식기구 연구)

  • Jeong, Yong-Hwan
    • Korean Journal of Materials Research
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    • v.6 no.2
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    • pp.188-196
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    • 1996
  • LiOH 용액에서 핵연료피복관용 Zr합금의 부식이 가속되는 현상을 규명하기 위하여 autoclave를 이용하여 순수물, 다른 농도의 Li 용액 및 여러 가지 알카리 수산화물 조건에서 부식시험을 실시하였다. LiOH 용액에서 부식이 가속되는 현상은 용액 내에 Li 농도가 2.2ppm 이상에서부터 일어나기 시작하며 30ppm 이상에서는 급격한 가속 현상이 일어난다. 부식반응 동안에 발생되는 수소 흡수현상은 220ppm Li에서는 물에 비해 약 2배의 높은 수소흡수율을 나타내며 산화막은 주로 수소화물이 모여 있는 지역에서 우선적으로 성장한다. Li가속 부식기구와 관련하여 본 연구 결과는 지금까지 다른 연구자들이 제안한 부식 기구들과는 일치하지 않았다. LiOH 용액 내에서는 수소흡수와 수소화물 형성이 가속되고 이로 인해 산화막의 성질이 비보호성의 산화막으로 변함으로서 부식은 가속된다는 새로운 모델을 제시하였다.

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Lifetime Reliability Based Life-Cycle Cost-Effective Optimum Design of Steel Bridges (생애 신뢰성에 기초한 강교의 LCC최적설계)

  • Lee, Kwang Min;Cho, Hyo Nam;Cha, CheolJun;Kim, Seong Hun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.1A
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    • pp.75-89
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    • 2006
  • This paper presents a practical and realistic Life-Cycle Cost (LCC) optimum design methodology of steel bridges considering time effect of bridge reliability under environmental stressors such as corrosion and heavy truck traffics. The LCC functions considered in the LCC optimization consist of initial cost, expected life-cycle maintenance cost and expected life-cycle rehabilitation costs including repair/replacement costs, loss of contents or fatality and injury losses, road user costs, and indirect socio-economic losses. For the assessment of the life-cycle rehabilitation costs, the annual probability of failure which depends upon the prior and updated load and resistance histories should be accounted for. For the purpose, Nowak live load model and a modified corrosion propagation model considering corrosion initiation, corrosion rate, and repainting effect are adopted in this study. The proposed methodology is applied to the LCC optimum design problem of an actual steel box girder bridge with 3 continuous spans (40 m+50 m+40 m=130 m), and various sensitivity analyses of types of steel, local corrosion environments, average daily traffic volume, and discount rates are performed to investigate the effects of various design parameters and conditions on the LCC-effectiveness. From the numerical investigation, it has been observed that local corrosion environments and the number of truck traffics significantly influence the LCC-effective optimum design of steel bridges, and thus realized that these conditions should be considered as crucial parameters for the optimum LCC-effective design.

Evaluation of Bond Strength of Deformed Bars in Pull-out Specimens Depending on Stirrups Spacing, Rebar diameter and Corrosion Rate (스터럽간격, 철근직경 및 부식률에 따른 인발 실험체의 부착강도 평가)

  • Seong-Woo Ji;Hoseong Jeong;Cha-Young Yoon;Jae-Yeon Lee;Kang Su Kim
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.3
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    • pp.47-57
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    • 2023
  • In this study, pull-out tests were performed to investigate the effects of stirrup spacing, rebar diameter, and corrosion rate on bond strength of deformed bars in reinforced concrete. Twelve pull-out specimens with different stirrup spacing, rebar diameter, and corrosion rate were prepared following the RILEM RC6 guidelines. The test results showed that the bond strength of specimens with stirrups increased when the corrosion rate was less than 3%, whereas it decreased when the corrosion rate was more than 3%. On the other hand, the bond strength of specimens without stirrups decreased as the corrosion rate increased. The effect of rebar diameter was less significant compared to those of stirrup spacing and corrosion rate. A bond strength model for pull-out specimens was proposed considering stirrup ratio and corrosion rate, and the model showed the lowest error among the previous models.

An Evaluation on the Mechanical Performance of a Corroded Rebar as the Corrosion Pattern of Rebar in Concrete (콘크리트중에서의 철근부식형태에 따른 부식철근의 역학적 특성에 관한 연구)

  • Kim, Hyung-Rae
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.393-396
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    • 2008
  • The purpose of this paper is to find out quantitatively the relationship between the surface shape and the mechanical properties of corroded reinforcement. Three-dimensional measurements were carried out on the surface shape of variously corroded reinforcements and parameters expressing the characteristics of the shape, which included the maximum decrement of sectional area of reinforcement, its distribution along the axis. It was investigated that which parameters could correspond to the mechanical properties of corroded reinforcement and it was confirmed that the maximum decrement of sectional area of reinforcement could express the mechanical properties most appropriately. Finally, this paper proposes a constitutive model of corroded reinforcement for analyzing the structural behavior of reinforced concrete structures considering the localized corrosion of by finite element method.

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Life-Cycle Cost-Effective Optimum Design of Steel Bridges Considering Environmental Stressors (환경영향인자를 고려한 강교의 생애주기비용 최적설계)

  • Lee, Kwang Min;Cho, Hyo Nam;Cha, Cheol Jun
    • Journal of Korean Society of Steel Construction
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    • v.17 no.2 s.75
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    • pp.227-241
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    • 2005
  • This paper presents a practical and realistic Life-Cycle Cost (LCC) optimum design methodology for steel bridges considering the long-term effect of environmental stressors such as corrosion and heavy truck traffics on bridge reliability. The LCC functions considered in the LCC optimization consist of initial cost, expected life-cycle maintenance cost, and expected life-cycle rehabilitation costs including repair/replacement costs, loss of contents or fatality and injury losses, road user costs, and indirect socio-economic losses. For the assessment of the life-cycle rehabilitation costs, the annual probability of failure, which depends upon the prior and updated load and resistance histories, should be accounted for. For the purpose, Nowak live load model and a modified corrosion propagation model, which takes into consideration corrosion initiation, corrosion rate, and repainting effect, are adopted in this study. The proposed methodology is applied to the LCC optimum design problem of an actual steel box girder bridge with 3 continuous spans (40m+50m+40m=130m). Various sensitivity analyses are performed to investigate the effects of various design parameters and conditions on the LCC-effectiveness. From the numerical investigation, it has been observed that local corrosion environments and the volume of truck traffic significantly influence the LCC-effective optimum design of steel bridges. Thus, these conditions should be considered as crucial parameters for the optimum LCC-effective design.

원전 출력감발 운전에 따른 방사성 부식생성물 거동 분석

  • 성기방
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.11a
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    • pp.103-109
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    • 1996
  • 고리 원자력 1호기 14주기(‘95년도) 운전기간 중 증기발생기 세관 열전달 용량 저하로 전출력 운전 기간동안 정격출력보다 15% 감발 운전한 경험이 있었는데, 이 기간중 냉각재내 방사성 부식생성물(CRUD) 농도가 약 80% 감소됨을 발견하였다. 이때 출력감소 비율보다 많은 CRUD 감소현상 규명을 위해 냉각재 수질관리인자와 EPRI 피복재 부식모델인 PFCC코드를 사용한 피 복재 산화물 두께변화 등을 비교한 결과, 운전중 용출되는 방사성 부식생성물은 핵연료 표면의 피복재 산화물에 흡착된 Co핵종이 피복재 산화물 이탈시 함께 거동하는 것으로 확인되었으며, 피복재 산화물 이탈은 산화막 두께 및 열유속에 주로 의존함이 밝혀졌다. 따라서 냉각재내에서 방사성 부식 생성물의 생성률 저감을 위해서는 정상운전시 핵연료 표면의 산화막 증가를 억제할 수 있는 수질 조건을 도출하고 그에따른 운전을 통해 원전 작업자의 방사선 피폭량 저감 및 방사성폐기물의 발생을 줄일 수 있을 것으로 여겨진다.

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Crack Width Prediction in Concrete Bridges Considering Bond Resistances affected by Corrosion (부식에 의한 부착저항감소를 고려한 콘크리트 교량의 균열폭 예측)

  • Cho, Tae-Jun;Cho, Hyo-Nam;Park, Mi-Yun
    • Journal of the Korea Concrete Institute
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    • v.18 no.4 s.94
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    • pp.543-552
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    • 2006
  • The current design for crack width control in concrete bridges is incomplete in analytical models. As one of the important serviceability limit states, the crack width be considered with the quantitative prediction of the initiation and propagation of corrosion and corrosion-induced cracking. A serviceability limit state of cracking can be affected by the combined effects of bond, slip, cracking, and corrosion of the reinforcing elements. Considering life span of concrete bridges, an improved prediction of crack width affected by time-dependent general corrosion has been proposed for the crack control design. The developed corrosion models and crack width prediction equation can be used for the design and the maintenance of prestressed and non-prestressed reinforcements by varying time, w/c, cover depth, and geometries of the sections. It can also be used as the rational criteria for the maintenance of existing concrete bridges and the prediction of remaining life of concrete structures.

Review of Research on Chloride-Induced Stress Corrosion Cracking of Dry Storage Canisters in the United States (미국의 건식저장 캐니스터에서의 CISCC 연구에 대한 검토)

  • Park, Hyoung-Gyu;Park, Kwang-Heon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.4
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    • pp.455-472
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    • 2018
  • It is important to study how to manage dry storage casks of spent nuclear fuels (SNF), because wet storage spaces for SNF will shortly be at full capacity in the Republic of Korea. The US has operated a dry storage cask system for several decades, and has carried out significant studies into how to successfully manage dry storage cask for SNF. This type of expertise and experience is currently lacking in the Republic of Korea. The degradation of dry casks is an important issue that must be considered. In particular, chloride-induced stress corrosion cracking (CISCC) is known to lead to the release of radioisotopes from canisters. The U.S. Department of Energy, U.S. Nuclear Regulatory Commission, and the Electric Power Research Institute have undertaken research into the CISCC mechanism. In addition, Sandia National Laboratories (SNL) has extensively researched CISCC and how to manage it in dry storage canisters. In this review paper, the probabilistic model proposed by the SNL is analyzed and, based on this model, US-based CISCC research is reviewed in detail. This paper will inform the management of dry cask storage of SNF from light water reactors in austenite stainless steel canisters in the Republic of Korea.

Investigation on Effect of Distance Between Two Collinear Circumferential Surface Cracks on Primary Water Stress Corrosion Crack Growth in Alloy 600TT Steam Generator Tubes (Alloy 600TT 증기발생기 전열관내 일렬 원주방향 표면 일차수응력 부식균열 성장에 미치는 균열 간격의 영향 고찰)

  • Heo, Eun-Ju;Kim, Jong-Sung;Jeon, Jun-Young;Kim, Yun-Jae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.3
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    • pp.269-273
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    • 2015
  • The study investigated the effect of the distance between two collinear circumferential surface cracks on the primary stress corrosion crack (PWSCC) growth in alloy 600TT steam generator tubes using a finite element damage analysis based on the PWSCC initiation model and macroscopic phenomenological damage mechanics approach. The damage analysis method was verified by comparing the results to the previous study results. The verified method was applied to collinear circumferential surface PWSCCs. As a result, it was found that the collinear cracks showed earlier coalescence and penetration times than the a single crack, and the times increased with the distance. In addition, it is expected that penetration may occur before coalescence of two cracks if they are more than a specific distance apart.