• Polymer(Korea)
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• v.29 no.1
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• pp.19-24
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• 2005

Polymer blends containing polypropylene (PP) with compatibilizers were prepared using twin screw extruder. Physical properties were investigated using universal test machine (UTM) and Izod impact tester. In the PP/acrylonitrilebutadiene-styrene (ABS) blends, mechanical strength was increased with the addition of PP-g-styrene acryloritrile (PP-g-SAN) compatibilizer, and the ductility was increased with the addition of ethylene-ethyl acrylate-maleic anhydride (E-EAMAH-g-SAN) compatibilizer. For the PP/ABS/ polycarbonate (PC)/Nylon-6,6 blends, impact strength was increased with the addition of ethylene glycidylmethacrylate (E-GMA compatibilizer) up to 0.5 phr. In the case of the PP/ABS/PC/Nylon-6,6/poly(methyl methacrylate) (PMMA)/poly(oxymethylene) (POM)/poly(vinyl acetate) (PVC)/poly(butylene terephthalate) (PBT) blends, mechanical properties were increased by the complex compatibilizing effects of PP-g-SAN, E-EA-MAH-g-SAN and E-GMA, respectively.

• Polymer(Korea)
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• v.29 no.3
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• pp.271-276
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• 2005

Polypropylene (PP)/montmorillonite (MMT) nanocomposites were prepared by melt mixing methods. MMT modified by dimethyl hydrogenated tallow 2-ethylhexyl ammonium (Cloisite 15A) was used. Polyolefine oligomer with telechelic OH groups was used as a compatibilizer. The degree of dispersion of MMT in the nanocomposites was measured by X-ray diffractometer and transmission electron microscope (TEM) images. MMT was well exfoliated when the contents of compatibilizer was 25 phr. The thermal stability that observed by thermogravimetric analysis (TGA) increased with the contents of MMT increased up to 5 phr. The complex viscosities and storage moduli of PP nanocomposites enhanced as the contents of compatibilizer decreased and those of MMT increased.

• Applied Chemistry for Engineering
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• v.22 no.5
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• pp.467-472
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• 2011

This study investigated illite/polypropylene (PP) composite filament formation via melt-spinning and evaluated their physical properties to prepare functional fibers using natural materials. When composite filaments were formed, the composite filaments exhibited smaller fiber diameters compared to that of neat PP filament because of the lubricant effect of illite induced by its layered structure. Moreover, fluorination effect increased interfacial affinity and dispersion in the polymer, resulting in smaller diameter of fluorinated illite/PP composite filament, which was 2/3 of the neat PP filament diameter. Addition of raw and fluorinated illite improved thermal stability of illite/PP composite filament. Raw illite/PP composite filament cannot be used for a practical application, because it broke during drawing process, whereas the fluorinated illite/PP composite filament can be used for a practical application, because it exhibited similar tensile strength of the neat PP filament and 50% increased modulus. Even with improved illite/PP interfacial affinity and illite dispersion in the polymer, illite/PP composite filament formed microcomposite, because non-expandable illite had strongly bound layers, resulting in only a little illite exfoliation and PP intercalation into illite.

• Polymer(Korea)
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• v.30 no.1
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• pp.70-74
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• 2006

Plasticized cellulose diacetate(CDA) was prepared by homogenizing cellulose diacetate(CDA), triacetin(TA) and epoxidized soybean oil (ESO) in a high-speed mixer, then the CDA mixture was mixed with ramie fiber to produce a green composite material. In DMA analysis, the glass transition temperature of plasticized CDA and the composite was observed at $85\;^{\circ}C\;and\;140\;^{\circ}C$, respectively. A composite reinforced with alkali treated ramie fiber exhibited significantly higher mechanical properties, such as $15\;^{\circ}C$ increase in tensile strength as well as $41\;^{\circ}C$ increase in Young's modulus when compared with commercial polypropylene. In the SEM image analysis, much enhanced adhesion between plasticized CDA and alkali treated ramie fiber (AIRa) was observed.

• Journal of the Korea Concrete Institute
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• v.21 no.2
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• pp.179-186
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• 2009

The peculiarity pointed out for high strength concrete is the occurrence of spalling during a fire. Recently, there are many efforts such as development of all types of spalling reducing materials and other innovative materials in various fields. Need is now to examine the adequate mixing proportions of these materials. This study intended to derive experimentally and statistically mix proportions that can represent the basic quality requirements as well as the optimal effects on the fire-resistance for 4 types of functional materials that are metakaolin, waste tire chip, polypropylene fiber and steel fiber. Here, the tests were planned through an optimal test method using an orthogonal array table with 4 parameters and 3 levels. The statistical analysis adopted the response surface analysis method. Results verified mutual complementary contribution between the materials when using a combination of the functional materials selected as parameters for the strengthening of the fire-resistance of 80 MPa-class high strength concrete. Besides, the optimal conditions of the fire-resistance strengthening materials derived through response surface analysis were a volumetric replacement of silica fume by 80% of metakaolin, a volumetric replacement of fine aggregates by 3% of tire waste chip, and an addition of 0.2% of the whole volume by polypropylene fiber without mixing of steel fiber. In such cases, the basic characteristics as well as the fire-resistant characteristics of high strength concrete were also satisfied.

• Journal of Adhesion and Interface
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• v.23 no.2
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• pp.44-52
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• 2022

Epoxy resin has the disadvantage of being easily destroyed by instantaneous impact due to its high crosslinking density despite its high glass transition temperature (T_g) and excellent properties. To compensate for this, in this study, polyol was synthesized by ring opening polymerization of propylene glycol (PPG) diamine, Jeffamine D 2000 and propylene carbonate, and urethane modified epoxy was synthesized using this. The properties of the synthesized urethane modified epoxy were confirmed by FT-IR, H-NMR. To confirm the degree of improvement in impact resistance as an adhesive, a urethane modified epoxy adhesive was prepared by mixing a digylcidyl ether bisphenol A (DGEBA) with curing agent and curing accelerator. Properties test of urethane modified epoxy were shear strength, tensile strength and impact strength. As a result, excellent results were obtained in all test when the ratio of DGEBA : urethane modified epoxy was 8:2.

• Textile Coloration and Finishing
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• v.34 no.1
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• pp.20-26
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• 2022

Centrifugal spinning is an emerging technique for fabricating micro-to-nano-fibers in recent years. To obtain fibers with the desired size and morphology, it is necessary to configure and optimize the parameters used in centrifugal spinning. In this study, it was controlled by changing the solution's concentration (7.5, 10, and 12.5 wt.%) and disk's rotational velocity (6,000, 8,000, and 10,000 rpm) to prepare centrifugal spun nano-filter. The morphological property, air permeability, and dust collection efficiency of the PVA/PP bi-layer nanoweb prepared by centrifugal spun PVA on the PP micron nonwoven substrate are studied using a field emission scanning electron microscope, an air permeability tester, and a filter tester equipment, and the analysis results indicate that it is suitable as a nano-filter when the concentration of PVA solution is 10 wt.% and the rotational velocity of the disk is 8,000 rpm. The resultant reduced diameter and uniform fibers also proved that an excellent dust collection efficiency filter could be made.

• Journal of Adhesion and Interface
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• v.17 no.1
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• pp.15-20
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• 2016

Fiber arrangement was important for fiber reinforced thermoplastic composites using injection fabrication. In this work, fiber arrangement in CF/PP was investigated to use electrical resistance (ER) method during injection times. There were 3 types of injection products of CF/PP with different ER change ratio by fiber arrangement. High ER change ratio case of injection CF/PP products had better increased tensile strength. This reason was due to the fiber arrangement of CF/PP by injection. Fractured surface and contact angle of CF/PP products were used to evaluate for injection product quality. Uniform fiber arrangement of CF/PP by injection type exhibited the uniform heat condition of melted CF/PP. Steady thermal transfer effect occurred from melted CF/PP to steel injection mold. Steady thermal transfer effect of CF/PP was transmitted to high ER change ratio of mold. Ultimately, good condition CF/PP product by injection molding method could be predicted by using ER method.

• The Korean Fashion and Textile Research Journal
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• v.20 no.5
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• pp.600-607
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• 2018

Polypropylene fibers, while having many advantages such as light weight, sweat fast drying, water-repellent, drainage, thermal insulation, anti-static property has a drawback in dyeing. In recent years, the development of dyeable polypropylene fibers has expanded its value in the textile market. The purpose of this study is to fabricate composite spun yarns using polypropylene, acrylic, rayon and wool and to analyze tensile properties, uniformity characteristics, bending properties, hairiness, and surface shape according to the degree of fineness and blended ratio. The specimens consisted of 100% polypropylene spun yarn pp30, pp40 and ppa(pp/acrylic), ppr(pp/rayon), ppw(pp/wool), 5 altogether sed in this study. The results of the study are as follows. The breaking strength of polypropylene spun yarn blended with rayon and acrylic was higher than that of 100% polypropylene spun yarn. The polypropylene spun yarn is higher the fineness been shown to decrease the breaking strength and elongation. The bending properties of polypropylene spun yarns were in the order of ppa>ppr>pp40>pp30>ppw. The unevenness of ppw, ppr, and ppa was higher than pp40 and pp30. With the exception of ppw with crimp properties, pp30 and pp40 were found to have a hairiness index greater than ppr, ppa. In the microscopic photographs of polypropylene spun yarn, pp30, which had the highest hairiness index, was found to have a thick yarn and a large number of hairs, and ppw had hairs of 3 mm or more protruding elongated outwardly.

• Journal of the Korean Wood Science and Technology
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• v.25 no.2
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• pp.33-44
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• 1997

This study was executed to examine the effects of polypropylene fiber length and process variables of the composites made from wood fiber and nonwood fiber mixed formulations. As a nonwood fiber the polypropylene with 3 denier thickness of tow condition was selected and cut into each length of 0.5, 1.0, 1.5, 2.0 and 2.5cm to mix with wood fiber. And also western hemlock wood fiber for medium density fiberboard was prepared. First, to decide an adequate polypropylene mixing fiber length, the composites of 1.0g/$cm^3$ density were made from 10% polypropylene fiber by each of five lengths and 90% western hemlock fiber mixed formulations. Thereafter as the experiments of process variable, the composites applied with adequate polypropylene fiber length(1.5cm) were made from 4 density levels (0.6, 0.8, 1.0, 1.2g/$cm^3$). 3 mixed formulations of wood fiber to polypropylene fiber(95 : 5, 90 : 10, 85 : 15), and 3 mat moisture contents(5, 10, 20%). According to the results and discussions it was concluded as follows ; The physical and mechanical properties were shown improved tendency. as polypropylene fiber length was increased in the range from 0.5 to 1.5cm, but shown decreasing tendency from 2.0 to 2.5 cm. Accordingly, it was shown that polypropylene fiber length is limited to 1.5cm or less length in mixing wood fiber and polypropylene fiber by turbulent air mixing process. As the densities of wood fiber-polypropylene fiber composites were increased, the physical and mechanical properties were clearly improved. Also they were shown significantly increasement statistically between densities respectively. In the mixed formulations, physical and mechanical properties were shown only slightly improvement, as they changed from 95 : 5 to 85 : 15 in wood fiber to polypropylene fiber. Despite of increasement of mat moisture content, mechanical properties were not improved significantly but physical properties were improved somewhat in wood fiber-polypropylene fiber composites.