• Title/Summary/Keyword: 복합 폴리프로필렌

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막결합형 혐기성 소화에서 무기분리막과 유기분리막의 막오염 특성 비교

  • 강인중;윤성훈;이정학
    • Proceedings of the Membrane Society of Korea Conference
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    • 1995.10a
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    • pp.51-51
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    • 1995
  • 혐기성 미생물의 특징은 성장 속도가 느리고 침강성이 좋지 않다는 점이다. 이 문제의 한 해결책인 막결합형 혐기성 소화는 고액분리를 완전하게 수행함으로써 미생물의 유출을 방지하여 반응조 내부에 미생물을 고농도로 유지할 수 있을 뿐만 아니라 에너지의 회수와 설비 면적의 축소 등 많은 장점이 있다. 이 막결합형 혐기성 소화의 경제성은 사용된 분리막의 투과 속도에 의해 크게 좌우된다. 분리막의 투과 속도에 영향을 미치는 인자로는 미생물 및 유입수를 비롯한 반응조 내부의 상태, 막모듈 압력 온도 막면유속 등의 운전 조건이 있다. 또한 사용되는 분리막 자체의 재질도 투과 유속에 큰 영향을 미친다. 본 연구의 목적은 관형의 지르코니아 스킨층과 탄소 소재 지지층으로 이루어진 복합 재료 분리막과 폴리프로필렌 분리막을 이용하여 막재질에 따른 막오염 특성을 비교 분석하고 효과적인 투과율 회복 방법을 확립하는 것이다.

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A Study on the Three Phase Glass Fiber/Nylon 6/Polyproylene Composites (나일론 6과 폴리프로필렌 수지에 유리섬유가 보강된삼상 복합재료에 관한 연구)

  • 서문호
    • The Korean Journal of Rheology
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    • v.10 no.2
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    • pp.57-64
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    • 1998
  • A pultrusion resin impregnation (PRI) die, which has been developed recently in our laboratory, was used to pre-pare various composite system. The continuous fiber reinforced composites of glass fiber/polypropylene(GFPP) and glass fiber/polyamide 6 (GFPA) were first manufactured by means of the PRI die and then cut into chopped pellets of predet-ermined length. These pellets and either virgin or modified thermoplastic resin were melt-mixed by a twin screw extruder to prepare GF/PA/PP and GF/PA/PPMA system. The mechanical properties of these blends were investigated and discussed in terms of their morphological observations. These preliminary results revealed that this new impregnation die could be suc-cessfully applied to produce prepregs suitavle for the final shaping process.

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A Study on the Hydrophobicity Modification and Physical Properties of Tencel Regenerated Fibers for Polypropylene Resin Composites (폴리프로필렌 수지 복합을 위한 텐셀 재생섬유의 소수화 표면개질 특성 연구)

  • Yoon, Songhyun;Kim, Mikyung;Lee, Eunsoo
    • Textile Coloration and Finishing
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    • v.33 no.4
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    • pp.258-268
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    • 2021
  • This study conducted on the introduction of recycled cellulose fibers, which are widely used in the textile industry as eco-friendly biomass materials, into polypropylene resins, which are mainly used for interior and exterior materials such as door trims and console parts of automobiles. In general, cellulose fibers can affect mechanical properties and have a lightening effect when used as a reinforcing agent. However, since cellulose fibers have hydrophilic properties and have relatively low compatibility with industrial polymer resins, they are used in combination through fiber hydrophobic surface treatment. Therefore, through this study, the reforming reaction conditions optimized in terms of hydrophobicity and workability for cellulose fibers are studied. Furthermore, polypropylene containing surface-modified cellulose fibers was prepared to compare physical properties by fiber content and study optimized content.

Impact Properties of Organic Fiber Reinforced Thermoplastic Composites (유기섬유강화 열가소성고분자 복합재료의 충격특성)

  • Im, Seung-Soon;Lee, Seung-Bae;Lee, Yong-Moo;Choi, Hyeong-Ki
    • Applied Chemistry for Engineering
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    • v.7 no.3
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    • pp.424-432
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    • 1996
  • The fiber reinforced thermoplastic composites(FRTP) were prepared with polypropylene fiber(PPF) as matrix and vinylon(VF), Aramid(KF) or nylon fiber(PAF) as reinforcing materials using the integrated fiber mixing apparatus. The composite sheets were prepared by compression molding and their impact and morphological properties were characterized. VF/PP system showed the maximum value in Izod impact strength, while KF/PP system showed the maximum value in high rate impact properties. Ductility Index(DI) order was VF/PP>KF/PP>PAF/PP. A maximum DI for VF/PP, 2.43, was obtained when the weight fraction of VF was 20%. The optimum amount of the reinforcing organic fiber was found to be 20~30%. As a result, it is concluded that VF/PP system has better interfacial adhesion properties than either KF/PP or PAF/PP.

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Optimization of Processing Conditions and Mechanical Properties in Polymer Nanocomposite (고분자 나노복합재료의 가공조건 및 물성 최적화)

  • Nam, Byeong-Uk;Hong, Chae-Hwan;Hwang, Tae-Won
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.6
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    • pp.73-80
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    • 2007
  • Nanocomposites are used as a new class of polymer system and many researchers have been interested in the clay nanocomposite because of its good mechanical properties, heat resistance, flame retardancy, and barrier property. Modified layered silicates as fillers are dispersed at a nanometer-level within a polymer matrix and then new extraordinary properties are observed. In this study, polypropylene/clay nanocomposites were prepared in a twin screw extruder by the melt compounding method. In order to increase the compatibility of PP with the clay, the MAPP was used as a compatibilizer. And organic modified clays were used as a nanometric filler during the melt extrusion. Through the analysis of SAXS, WAXS, the dispersion of clay was investigated. These nanocomposites compared with a neat polypropylene/talc composite have high modulus, low toughness, and reduced shrinkage at the stable dispersion.

Effect of Fiber Orientation on the Tensile Strength in Twisted Yarn Composites (Twisted Yarn 복합재료에서 인장강도에 미치는 섬유배향의 영향)

  • Lee, Dong-Ki;Sim, Jae-Ki;Kim, Hyuk;Kim, Jin-Woo;Lee, Jung-Ju;Lee, Ha-Wook
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.422-425
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    • 2003
  • Investigated whether fiber orientation distribution of twisted yarn composites and the fiber content are 0$^{\circ}$ and 90$^{\circ}$ direction tensile strength and some correlation. Tensile strength of 0$^{\circ}$ directions of twisted yarn composites increased changelessly being proportional the fiber content and fiber orientation function get into anisotropic in isotropic. But, tensile strength ratio by separation of fiber filament of 90$^{\circ}$ directions tensile strength decreased when tensile load is imposed for width direction of reinforcement fiber. 0$^{\circ}$ and 90$^{\circ}$ direction tensile strength ratio value of a twisted yarn composites not receive almost effect of the fiber content of fiber orientation function J = 0.4 lows. Although do, 20 wt% of the fiber content is high about 0$^{\circ}$ and 90$^{\circ}$ direction tensile strength ratio about 1.6~2 than 10 wt% from J = 0.4. Therefore. could know that effect of the fiber content is dominate.

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Effect of Textile Pattern on Mechanical and Impregnation Properties of Glass Fiber/Thermoplastic Composite (유리 섬유/열가소성 복합 재료의 기계적 및 함침 특성에 대한 직물 패턴의 영향)

  • Kim, Neul-Sae-Rom;Lee, Eun-Soo;Jang, Yeong-Jin;Kwon, Dong-Jun;Yang, Seong Baek;Yeom, Jung-Hyun
    • Composites Research
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    • v.31 no.6
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    • pp.317-322
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    • 2018
  • In various industry, the composite is tried to be applied to products and thermoplastic based composite is in the spotlight because this composite can be recycled. The use of continuous fiber thermoplastic (CFT) method increased gradually than long fiber thermoplastic (LFT). In this study, tensile, flexural, and impact test of different array types of glass fiber (GF)/thermoplastic composites were performed to compare with GF array. Impregnation property between GF mat and thermoplastic was determined using computed tomography (CT). At CFT method, thermoplastic film is not wet into GF roving and many voids are appeared into composite. This phenomenon affects to decrease mechanical properties. Plain pattern GF mat was the best mechanical and impregnation properties that distance between two roving was set closely to $100{\mu}m$.

Study on the Non-isothermal Crystallization Kinetics of Branched Polypropylene (분지형 폴리프로필렌의 비등온결정화 거동 연구)

  • Yoon, Kyung-Hwa;Shin, Dong-Yup;Kim, Youn-Cheol
    • Polymer(Korea)
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    • v.36 no.2
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    • pp.245-250
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    • 2012
  • Branched polypropylenes (PP) with long chain branch were prepared by solid state reaction with three different branching agent of 0.3 wt% content. The chemical structures, non-isothermal crystallization behavior and complex viscosity of the branched PP were investigated by FTIR, DSC, optical microscope, and dynamic rheological measurement. The chemical structure of the branched PP was confirmed by the existence of =C-H stretching peak of the branching agent at 3100 $cm^{-1}$. There was no distinct change in melting temperature in case of PP-D-0-3 and PP-F-0-3, but PP-H-0-3 indicated a decrease in melting temperature. The decrease in melting temperature was interpreted by the fact that the degradation reaction of PP was more dominant than branched reaction, and confirmed by a decrease in complex viscosity. The non-isothermal crystallization behavior of the branched PP was analyzed using by Avrami equation. The Avrami exponent of PP was 3, and the values of the branched PP with DVB and FS were below 3. The activation energy of PP calculated by Kissinger method was 25 kJ/mol, and there were no big difference in activation energies of the branched PPs compared to PP.

Curing Behaviors and Mechanical Properties of Unsaturated Polyester Hosing with Different Glycol Molar Ratios (글리콜 몰비가 다른 UPE 수지의 경화거동과 물성에 관한 연구)

  • 이상효;이장우
    • Polymer(Korea)
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    • v.24 no.5
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    • pp.599-609
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    • 2000
  • In order to improve the mechanical properties of unsaturated polyester (UPE) resins, the UPE resins with different glycol molar ratios were prepared. The effects of molar ratios of the UPE resins on the curing behaviors and mechanical properties were investigated. The microgel reaction mechanism was employed to characterize the system. It was found that the final conversion increased with increasing NPG molar ratios, and the conversion at the peak of differential scanning calorimetry (DSC) thermogram appeared to decrease with increasing NPG molar ratios. The flexural strength, tensile modulus, water resistance, and infiltration increased with increasing NPG content, but the tensile strength, tensile elongation, and flexural modulus decreased. Among the UPE resins prepared from the glycols with the molar ratios (PG/NPG) of 0.5/0.5, 0.25/0.75, those of laminated composites plates showed better mechanical properties.

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Impact and Fire Retardant Properties of Flax Fiber Reinforced Nanoclay Composites by Taguchi Method (다구치 기법을 사용한 나노클레이가 첨가된 아마섬유 강화 복합재료의 충격 거동 및 연소 특성)

  • Won, Cheon;Kim, Jin-Woo;Lee, Dong-Woo;Kim, Byung-Sun;Song, Jung-Il
    • Composites Research
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    • v.26 no.3
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    • pp.189-194
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    • 2013
  • This paper deals with the study of mechanical properties and impact energy absorbed by composites, made by using thermoplastic and thermoset as matrix, flax fiber and nanoclay as reinforcements. The nanoclay was sprayed on the fiber laminate directly after mixing with ethanol. This experiment designed by Taguchi method and have variable factors, i.e three types of fiber direction(F), three different nanoclay wt%(N) and three spray gun hole shapes(S). According to these conditions, composites were made and the optimum conditions were found to be F1N3S1, F1N2S1, F1N2S1 and F3N2S1 for thermoplastic, and F1N3S2, F1N3S2, F1N2S2 and F3N2S1 for thermoset which were matched with tensile strength, modulus, total impact absorbed energy and heat release rate respectively.