• Korean Chemical Engineering Research
• /
• v.49 no.3
• /
• pp.342-347
• /
• 2011

The effects of compatibilizers on the mechanical and rheological properties of PP/PCL and TPO/PCL blends have been studied. The thermoplastic polyolefin (TPO) consists of PP (80 wt%), EPDM (15 wt%) and Talc (5 wt%). Maleic anhydride grafted polypropylene (PP-g-MAH) and maleic anhydride grafted styrene-(ethylene-co-butene)-styrene copolymer (SEBS-g-MAH) were used as compatibilizers. In mechanical properties of PP/PCL and TPO/PCL blends, tensile strength was increased when PP-g-MAH was used as a compatibilizer, and impact strength was increased when SEBS-g-MAH was used as a compatibilizer. From the results of SEM morphology of PP/PCL blend, PCL droplet size was decreased by the addition of PP-g-MAH. From the results of rheological property, complex viscosity of the PP/PCL and TPO/PCL blends did not change appreciably when the compatibilizers were added. From the results of mechanical, morphological and rheological properties of the blends, PP-g-MAH acted as a compatibilizer to increase the tensile strength of the PP/PCL and TPO/PCL blends. While SEBS-g-MAH acted as a impact modifier to increase the impact strength of the PP/PCL and TPO/PCL blends.

• Journal of the Korean Wood Science and Technology
• /
• v.42 no.6
• /
• pp.682-690
• /
• 2014

In order to improve the thermal stability of wood plastic composites (WPC), thermal degradation behavior of WPC in this study was investigated by the addition of wood flour and fire retardant after hybridization of wood flour and ammonium polyphosphate (APP) into polypropylene (PP) matrix. Thermal degradation behavior of all formulations was analyzed with thermogravimetric analyzer under nitrogen environment at heating rate of $10^{\circ}C/min$. As the thermal degradation temperature of wood flour is lower than that of PP, char layer formed by the wood flour decreases the speed of heat transfer to PP. In addition, the char layer increases the 2nd thermal degradation temperature and decreases the 2nd thermal degradation speed. The WPC treated with APP increases the 1st and 2nd degradation temperatures. In the case of WPC with high loading level of wood flour, the 1st thermal degradation temperature and 2nd thermal degradation rate were increased by the addition of APP, and then the amount of remnants at high temperature was increased by the increase of the APP loading level. In the case of WPC treated with APP, the amount of the remnants at high temperature was increased with the increase of wood flour content from 10 wt% to 50 wt%, indicating that char formation of the APP and wood flour occurred at the same time, resulting in high thermal stability effect by the increase of wood flour content.

• Journal of the Korea Institute of Building Construction
• /
• v.10 no.4
• /
• pp.3-9
• /
• 2010

Fire resistance and material properties of high-strength concrete (W/B 21.5%, 28.5%) with OPC, BS and FA were tested in this study. Main factors of the test consisted of fiber mixing ratio and W/B. Two types of fiber (NY, PP) mixed with the same weight were used for the test. The fiber mixing ratios were 0%, 0.05%, 0.1%, and 0.2% of the concrete weight. After performing the test, Under the W/B level of 21.5% and 28.5%, the spalling was effectively resisted by using the high strength concrete with fiber mixing ratios of 0.05%~0.1%. Compressive strength, flowability and air content are similar those of the fiberless high-strength concrete with the same W/B.

• Journal of the Korean Wood Science and Technology
• /
• v.26 no.1
• /
• pp.76-86
• /
• 1998

Effects of processing variables and MAPP (maleic anhydride polypropylene) coupling agent on the properties of composite were discussed for turbulent-air-mixed woodfiber-polypropylenefiber composites. In this research, density, composition ratio, and mat moisture content were established as processing variables, and emulsified MAPP prepared by direct pressure method was incorporated as the coupling agent. And the turbulent air mixer, which was improved in function through alteration of our previous fiber mixer, was used to mix wood fibers and polypropylene fibers. At the addition level of 1% MAPP, based on oven-dried wood fiber weight, woodfiber-polypropylenefiber composites generally showed enhanced the physical and mechanical properties. And composites with low to medium densities of 0.6 to 0.8g/$cm^3$ greatly increased in these property values than with high densities of 1.0g/$cm^3$ or more by adding 1 % MAPP. Thus, MAPP addition was thought to be an effective way of enhancing properties for nonwoven web composites. At the mat moisture contents of 5 to 20%, however, the physical and mechanical properties were not enhanced by adding 1% MAPP. In the composites containing 15% polypropylene fibers, the lowest thickness swelling and water absorption values were observed at the 1% MAPP level. The addition of more than 1% MAPP had the adverse effect on the physical and mechanical properties of composites.

• Journal of the Korea Concrete Institute
• /
• v.19 no.2
• /
• pp.153-161
• /
• 2007

This paper investigates the lap splice performance of structural steel bars embedded in high performance fiber reinforced cementitious composite(HPFRCC) with various matrix ductilities. Matrix ductility is governed fiber type and fiber volume fraction. Fiber types were polypropylene(PP), polyethylene(PE) and hybrid fiber[polyethylene fiber+steel cord(PE+SC)]. The lap splice length$(l_d)$ was calculated according to the relevant ACI code requirements for reinforcing bars in normal concrete. As the result of tests, lap splice strength of HPFRCC using PE1.5 and hybrid fiber increased by up to $82{\sim}91$ percent more than that of concrete. Splice strength and energy absorption capacity of PE0.75+SC0.75 or PE1.5(fiber volume fraction 1.5%) specimen increased more than that of PP2.0(fiber volume fraction 2.0%) specimen. Therefore lap splice performance depends on fiber tensile strength and Young's modulus more than fiber volume fraction. Also, HPFRCC appear multiple crack and ductile postpeak behavior due to bridging of fiber in cementitious composite.

• Journal of the Computational Structural Engineering Institute of Korea
• /
• v.26 no.6
• /
• pp.423-430
• /
• 2013

In this research, a paramteric study to account for the effect of interfacial strength and nanotube agglomeration on the elastoplastic behavior of carbon nanotube reinforced polypropylene composites is performed. At first, the elastoplastic behavior of nanocomposites is predicted from molecular dynamics(MD) simulations. By combining the MD simulation results with the nonlinear micromechanics model based on the Mori-Tanaka model, a two-step domain decomposition method is applied to inversely identify the elastoplastic behavior of adsorption interphase zone inside nanocomposites. In nonlinear micromechanics model, the secant moduli method combined with field fluctuation method is used to predict the elastoplastic behavior of nanocomposites. To account for the imperfect material interface between nanotube and matrix polymer, displacement discontinuity condition is applied to the micromechanics model. Using the elastoplastic behavior of the adsorption interphase zone obtained from the present study, stress-strain relation of nanocomposites at various interfacial bonding condition and local nanotube agglomeration is predicted from nonlinear micromechanics model with and without the adsorption interphase zone. As a result, it has been found that local nanotube agglomeration is the most important design factor to maximize reinforcing effect of nanotube in elastic and plastic behavior.

• Polymer(Korea)
• /
• v.33 no.4
• /
• pp.358-363
• /
• 2009

Maleic anhydride-grafted polypropylene has been widely used to improve the interfacial interaction between the components in PP/polar polymer blends and PP/filler composites and to maximize the physical properties and thermal properties. In this paper. the maleic anhydride (MAH)-grafted polypropylene (co-PP) was fabricated through reactive extrusion process with di-cumyl peroxide (DCP) as an initiator. The grafting degree of MAH depending on the contents of DCP and MAH was investigated by FT-IR spectra and chemical titration. The grafting degree increased with increasing MAH concentration and also showed maximum value at 0.06 wt% of DCP concentration. Melt flow index (MFI) of the grafted copolymer was increased with increasing the contents of MAH. The DSC and TGA analysis data indicate the melting temperature and thermal degradation of PP depending on the grafting degree of MAH.