• Title/Summary/Keyword: 복합 사이클

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Electrochemical Performance of Graphite/Silicon/Carbon Composites as Anode Materials for Lithium-ion Batteries (리튬이온배터리 Graphite/Silicon/Carbon 복합 음극소재의 전기화학적 성능)

  • Jo, Yoon Ji;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.56 no.3
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    • pp.320-326
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    • 2018
  • In this study, Graphite/Silicon/Carbon (G/Si/C) composites were synthesized to improve the electrochemical properties of Graphite as an anode material of lithium ion battery. The prepared G/Si/C composites were analyzed by XRD, TGA and SEM. Also the electrochemical performances of G/Si/C composites as the anode were performed by constant current charge/discharge, rate performance, cyclic voltammetry and impedance tests in the electrolyte of $LiPF_6$ dissolved inorganic solvents (EC:DMC:EMC=1:1:1 vol%). Lithium ion battery using G/Si/C electrode showed better characteristics than graphite electrode. It was confirmed that as the silicon content increased, the capacity increased but the capacity retention ratio decreased. Also, it was shown that both the capacity and the rate performances were improved when using the Silicon (${\leq}25{\mu}m$). It is found that in the case of 10 wt% of Silicon (${\leq}25{\mu}m$), G/Si/C composites have the initial discharge capacity of 495 mAh/g, the capacity retention ratio of 89% and the retention rate capability of 80% in 2 C/0.1 C.

A study on the application of optical fiber sensors to smart composite structures (지능형 복합재 구조물에 대한 광섬유센서의 적용에 관한 연구)

  • Jang, Tae-Seong;Kim, Ho;Lee, Jung-Ju
    • Journal of Sensor Science and Technology
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    • v.5 no.6
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    • pp.15-24
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    • 1996
  • In this study, as a part of the basic study for the application of optical fiber sensors to smart composite structures, the integrity of optical fiber sensors embedded within the composite structures was examined and then the laser signal transmitted through optical fiber sensors during the deformation of host structures was investigated. Firstly, it was found that bending test could be substituted for tensile test by comparing cumulative failure distribution based on weakest link theory and introducing the correction factor. Weibull parameters were obtained through the experiments and the correction factor was found to be applied to cumulative failure distribution derived from bending test. The integrity of embedded optical fiber sensors due to the thermal effect was evaluated by the comparison of the mean tensile strengths of cured and uncured optical fibers. Secondly, relationships between stress-strain curve obtained in tensile test of composite laminate and the intensity of laser signal transmitted through embedded optical fibers were examined and the possibility of the effective damage detection using optical fiber sensors was studied.

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An Electrochemical Study on the Carbon Black Conductor Prepared by Plasma Pyrolysis of Methane (메탄 플라즈마 분해에 의해 제조된 카본블랙 도전재의 전기화학적 특성에 대한 연구)

  • Yoon, Se-Rah;Lee, Joong-Kee;Cho, Won-Ihl;Baek, Young-Soon;Ju, Jae-Beck;Cho, Byung-Won
    • Journal of the Korean Electrochemical Society
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    • v.6 no.1
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    • pp.6-12
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    • 2003
  • Plasma carbon black(PB) which prepared by plasma pyrolysis of methane was treated at 800, 1300 and $2100^{\circ}C$ under $2\times10^{-2}$ torr. Four different samples including raw PB were added to $LiCoO_2$, cathode active material of lithium secondary battery, to investigate effects of properties of plasma black as conductors on electrochemical characteristics. Based on our experimental results, PB conductors with low amount of surface functional groups and high electrical conductivity enhanced the cyclability and the initial discharge capacity. However, deterioration of rate capability and cyclability were observed (or the plasma black treated at $2100^{\circ}C$ For the plasma black conductor prepared from plasma pyrolysis, the effects of properties of carbon black on electrochemical characteristics were combined results of changes in electrical conductivity and structural properties such as agglomeration of plasma black. The conductivity of plasma black increased with treatment temperature, while dispersion of plasma black decreased. As a result, the high cyclability of cell was observed at $800^{\circ}C$ of heat treatment temperature.

Static and Fatigue Characteristics of Urethane Foam Cored Sandwich Structures (우레탄 폼 코아 샌드위치 구조물의 정적 및 피로 특성)

  • 김재훈;이영신;박병준;김덕회;김영기
    • Composites Research
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    • v.12 no.6
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    • pp.74-82
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    • 1999
  • The static and fatigue characteristics of polyurethane foam cored sandwich structures are investigated. Three types of the specimens with the glass fabric faces and the polyurethane foam core are used; non-stitched. stitched, and stiffened sandwich specimen. Especially additional structural reinforcements with the twisted polyester and glass fiber for thickness direction are made to stitched sandwich structure panel to minimize the delamination of structure which is stitched the upper and lower faces through the core and the resin is impregnated Into stitched fiber with the characteristics of low viscosity of resin at resin flow temperature and cured together with during the curing process. Bending strength of stitched specimen which is 50 mm $50{\times}50{\;}mm$ pitched is improved by 50 % as com-pared with non-stitched specimen and stiffened specimen is improved 10 times more than non-stitched structure. After fatigue testing of $10^6$cycles by 20% of ultimate load under monotonic load, the bending fatigue strength of non-stitched specimen is decreased by 27% of monotonic bending strength, 39% for stitched structure and 20% for stiffened specimen. To verify the aging effect of polyurethane form core, Ultrasonic C-scanning equipment is used to detect the damage of skin laminate alone after fatigue test. From results of UT C-scan images, there is no defect that can be damaged occurred during fatigue test. It is concluded that the decrease of bending strength for foam cored sandwich specimen is caused by the decrease of stiffness due to the aging of polyurethane foam core during fatigue cycles.

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Analysis on Reflection Characteristics of the Key Competencies Proposed by the OECD Education 2030 in the 2015 Revised Home Economics Curriculum (OECD Education 2030에서 제안된 핵심역량의 2015 개정 가정과 교육과정 반영 특성 분석)

  • Yang, Ji Sun;Yoo, Taemyung
    • Journal of Korean Home Economics Education Association
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    • v.31 no.2
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    • pp.113-135
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    • 2019
  • The purpose of this study was to analyze the characteristics reflected in the 2015 revised home economics curriculum for the key competencies presented in the OECD education 2030 project. The results indicate that first, in general, about 46.5% of the competencies could be classified into the skill, attitude and value category; 17% into the learning concept framework category; 24.2% into the competency development cycle category; and 12.5% into the complex competency category. Overall, the competencies of the OECD learning framework are found to be reflected primarily in the achievement standards(59%), followed by characteristics(16.1%), teaching-learning and assessments orientation(9.4%), content system(8%), and goals(7.6%). Second, the key competencies were reflected in the middle school curriculum, more often in the descending order of action, problem-solving, communication, respect, creative thinking, conflict resolution, empathy, critical thinking, self-regulation, and student agency. In the high school curriculum, the competencies were reflected more often in the descending order of action, empathy, problem-solving, anticipation, global competence, self-regulation, student agency, literacy for sustainable development, reflection, and critical thinking. Third, the heat map shows that the competencies corresponding to the third and fourth levels are most frequently reflected in the curriculum. Therefore, it is advisable to develop effective plans to execute and support the reflection of key competencies in the curriculum. Through this study, home economics educators are expected to understand the inter-connectivity between the key competencies emphasized by the OECD learning framework and the competencies of home economics as a practical subject, and to scrutinize how to help individual students develop their overall competencies and be prepared for the future.

Carbon Sphere/Fe3O4 Nanocomposite for Li/air Batteries (리튬/공기 이차전지용 카본미소구체/Fe3O4 나노복합체)

  • Park, Chang Sung;Park, Yong Joon
    • Journal of the Korean Electrochemical Society
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    • v.17 no.2
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    • pp.124-129
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    • 2014
  • In this article, we report the fabrication and characterization of carbon sphere/$Fe_3O_4$ nanocomposite for Li/air batteries. $Fe_3O_4$ nanoparticles are dispersed homogeneously on the surface of carbon spheres in an attempt to enhance the low conductivity of oxide catalyst ($Fe_3O_4$). The carbon sphere/$Fe_3O_4$ nanocomposite could offer wide surface area of $Fe_3O_4$ and increased carbon/catalyst contact area, which lead to enhanced catalytic activity. The electrode employing carbon sphere/$Fe_3O_4$ nanocomposite presented relatively low overpotential and stable cyclic performance compared with the electrode employing carbon sphere.

A Study of Pre-inspection for Information Security in Information System (정보시스템의 정보보호를 위한 사전점검에 관한 연구)

  • Lee, Keun-Ho
    • Journal of Digital Convergence
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    • v.12 no.2
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    • pp.513-518
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    • 2014
  • According to the development of IT technology, various new technologies are being produced. As the complexity of the information system like using the network and convergence devices is increasing, threat and vulnerability against various security problems are increasing even though new IT services provide the convenience of users' accessibility to services. In order to secure the safety of information system, the weakness is being removed through the information protection vulnerability analysis starting from information and communication service construction stage and the system is being prepared for pre-inspection activities about whether the information protection measures were established and applied. In this paper, introduction and current status of each country about advanced check-up systems in the information system are to be identified. Progress direction about the advanced pre-inspection system which is driven by Korea Internet Security Agency and its activation plan to secure the safety are to be suggested.

The Figures for the Alstom Power Pressurized Fluidized Bed Combustion Combined Cycle System (Alstom Power의 가압유동층 복합발전 시스템 특성)

  • 이윤경;주용진;김종진
    • Journal of Energy Engineering
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    • v.12 no.1
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    • pp.1-10
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    • 2003
  • Pressurized fluidized bed combustion unit is operated at pressures of 1~1.5 MPa with combustion temperatures of 850~87$0^{\circ}C$. The pressurized coal combustion system heats steam, in conventional heat transfer tubing, and produces a hot gas supplied to a gas turbine. Gas cleaning is a vital aspect of the system, as is the ability of the turbine to cope with some residual solids. The need to pressurize the feed coal, limestone and combustion air, and to depressurize the flue gases and the ash removal system introduces some significant operating complications. The proportion of power coming from the steam : gas turbines is approximately 80:20%. Pressurized fluidized bed combustion and generation by the combined cycle route involves unique control considerations, as the combustor and gas turbine have to be properly matched through the whole operating range. The gas turbines are rather special, in that the maximum gas temperature available from the FBC is limited by ash fusion characteristics. As no ash softening should take place, the maximum gas temperature is around 90$0^{\circ}C$. As a result a high pressure ratio gas turbine with compression intercooling is used. This is to offset the effects of the relatively low temperature at the turbine inlet.

The Development of Eco-friendly Fiber Materials for Transport (수송용 친환경 섬유소재 개발)

  • Bok, Jin-Seon;Lee, Hyun-Seok;Jeong, Geung-Sik;Lee, Ki-Young;Park, Chang-Seok
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.18-18
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    • 2012
  • 전 세계적으로 이산화탄소 배출량 저잠을 위해 모든 산업분야에서 연구개발의 중점을 두고 있다. 그의 일환으로 자동차 산업에서는 EU규제에 따라 리사이클이 가능한 소재 개발이 요구되고 있으며, 그중 많은 양이 사용되고 있는 PU Foam의 대체 재료 개발이 시급한 실정이다. 기존 자동차의 흡음재로 주로 사용되고 있는 PU Foam 소재는 통기성이 부족할 뿐만 아니라 연소 시 인체에 유해한 HCN Gas를 발생시키고, 한번 성형된 부품은 Recycle 및 Re-Use가 불가능하다는 단점이 있다. 또한 장시간 사용시 황변 발생과 악취가 발생하는 등으로 최근 대두되고 있는 자동차 내장재 감성품질 향상 측면에 한계를 나타내고 있다. 이러한 Low Melting 성능을 가지는 PET 부직포 소재의 한계를 극복하기 위하여 저융점 성능의 Elastic Fiber의 개발과 함께 고탄성 복합부직포 소재의 개발을 통해 높은 변형률과 우수한 복원력을 나타내는 환경친화형 열가소성 탄성체(Thermoplastic Elastomer) 개발을 추진하고 있다. 고탄성 복합부직포는 자동차 내장재 성형 시 열을 가하더라도 Elastomer 자체의 탄성 발현을 통해 초기의 Bulky성을 유지할 수 있으며, Recycle 및 Re-use가 가능하여 환경 친화적인 측면에서도 큰 장점을 갖고 있다. 자동차용 흡음 내장재뿐만 아니라 각종 수송용 차량의 경량화 및 쾌적성 향상을 위한 용도로써 자동차 내장용 PU Foam의 57% 이상을 차지하고 있는 Seat Cushion재 등의 대체가 가능하며, 다양한 산업분야에서 사용되고 있는 PU Foam의 대체로 다양한 용도 전개가 가능할 것으로 예상된다. 본 연구에서는 PU Foam의 대체 재료로 각광받고 있는 Elastic PET를 개발하여 자동차 내장재로의 적용 가능성을 검토하였다.

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Comparison of Geogrid Bonding Methods under Asphalt Overlay Layer for Reflection Cracking Retardation (아스팔트 덧씌우기 하부의 Geogrid 부착방법에 따른 반사균열 지연특성 비교)

  • Doh, Young-Soo;Kim, Bun-Chang;Ko, Tae-Young;Kim, Kwang-Woo
    • International Journal of Highway Engineering
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    • v.7 no.4 s.26
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    • pp.9-20
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    • 2005
  • This study was carried out to select most efficient bonding methods of geogrid at the interface of old concrete pavement before placing asphalt overlay layer for reflection cracking retardation. Three bonding methods, a RSC-4 emulsified asphalt, a compound and an unsaturated polyester resin (UPR) were compared in this study. Three types of asphalt mixture (AC 60-80, RLDPE 8%, PG 76-22) and a dense-graded aggregate were used for overlay asphalt pavement. A reinforcing material which consists of a woven fabric underneath a glass fiber grid was used. An expedite test method which is for simulating mixed mode (mode I and II) fracture test was performed using a wheel tracker in laboratory. Cracking development by load repetition was measured as fatigue life (number of load cycle) and expansion of specimen body were measured for each test specimen. The results showed that UPR was the best and RSC-4 the next. But considering field applicability, RSC-4 was considered as an appropriate choice for bonding reinforcing material.

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