• Title/Summary/Keyword: 복합재 구조체

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Nanofibers Comprising Mo2C/Mo2N Nanoparticles and Reduced Graphene Oxide as Functional Interlayers for Lithium-Sulfur Batteries (Mo2C/Mo2N 나노 입자와 환원된 그래핀 옥사이드가 복합된 나노 섬유 중간층이 적용된 리튬-황 전지)

  • Lee, Jae Seob;Yang, Ji Hoon;Cho, Jung Sang
    • Korean Chemical Engineering Research
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    • v.60 no.4
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    • pp.574-581
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    • 2022
  • Nanofibers comprising reduced graphene oxide (rGO) and Mo2C/Mo2N nanoparticles (Mo2C/Mo2N rGO NFs) were prepared for a functional interlayer of Li-S batteries (LSBs). The well-dispersed Mo2C and Mo2N nanoparticles in the nanofiber structure served as active polar sites for efficient immobilization of dissolved lithium polysulfide. The rGO nanosheets in the structure also provide conductive channels for fast ion/electron transport during charging-discharging and ensured reuse of lithium polysulfide during redox reactions through a fast charge transfer process. As a result, the cell assembled with Mo2C/Mo2N rGO NFs-coated separator and pure sulfur electrode (70 wt% of sulfur content and 2.1 mg cm-2 of sulfur loading) showed a stable discharge capacity of 476 mA h g-1 after 400 charge-discharge cycles at 0.1 C. Furthermore, it exhibited a discharge capacity of 574 mA h g-1 even at a high current density of 1.0 C. Therefore, we believe that the proposed unique nanostructure synthesis strategy could provide new insights into the development of sustainable and highly conductive polar materials as functional interlayers for high performance LSBs.

Characteristics of Flame Retardent and Mothproof Conservation of Microwave Heated wood (마이크로파 가열 목재의 방염·방충 복합 보존처리 특성)

  • Kim, Chong-Gun;Park, Cheul-Woo;Yoon, Tae-Ho;Lim, Nam-Gi
    • Journal of the Korean Wood Science and Technology
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    • v.41 no.3
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    • pp.234-246
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    • 2013
  • It was found that test piece heated rapidly by 3 kW microwave for 5 minutes satisfies the targeted temperature and the percentage of moisture content, and the highest rate of weight increase is obtained in case of 120 minute immersion in the mixture of phosphates and heterocyclic compounds, from the result of such analysis as: kiln drying schedule, flame retardent by flammability test, insect resistance by termites, and permeability of combined penetrant for the wood after assigning multifunctional finish by immersing conifer structural frame, which is used for the frame work of wooden house and indoor/outdoor finishing in flame retardant and insect repellent materials mixture with the remaining heat of microwave. In addition, after a test of flame retardent treated item, it was identified that every mixture of phosphates corresponds with the standards of flame retardent, and upon investigation of moritality of 7 days after putting termites, it was showed that test piece immersed in the mixture of phosphates and heterocyclic compounds has the best characteristics, showing over 96% of high moritality. From the analysis of inward permeability of combined penetrant for the wood, it was decided that excellent performance in the flame retardent and insect resistance of the wood revealed due to full penetration of combined penetrant as it was found that combined penetrant penetrated through the whole inner cells of the wood.

Analysis of Reinforcement Effect of TSL (Thin Spray-on Liner) as Supports of Tunnel by Numerical Analysis (수치해석에 의한 터널 지보재로서 TSL(Thin Spray-on Liner)의 보강 효과 분석)

  • Lee, Kicheol;Kim, Dongwook;Chang, Soo-Ho;Choi, Soon-Wook;Lee, Chulho
    • Journal of the Korean Geosynthetics Society
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    • v.16 no.4
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    • pp.151-161
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    • 2017
  • A TSL (Thin Spray-on Liner) has a higher initial strength and faster construction time than conventional cementitious shotcrete. Because of its high adhesion and tensile strength, the TSL reinforced concrete show a characteristic like composite materials. In this study, to consider an application to the conventional design method, ASD (allowable stress design), numerical study was used. In the numerical analysis, material and contact properties were adopt from previous studies. Then a thickness of concrete in the tunnel was evaluated with the TSL reinforced case by the ASD concept. In other words, bending compressive stress, bending tensile stress and shearing force of the concrete were considered to determine a thickness of concrete lining by the given boundary conditions. From the numerical analysis, there was no tendency to show by the ASD because the ASD is based on the elastic theory while the TSL typically contributes to reinforcement after yielding.

Evaluation of Beam Behavior with External Bonded L-type GFRP Plate through bending Test (L형 GFRP 외부부착 보강된 보의 휨 실험을 통한 보강 거동분석)

  • Jeong, Yeong-Seok;Kwon, Min-Ho;Kim, Jin-Sup;Nam, Gwang-sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.11
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    • pp.86-93
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    • 2020
  • The demand for maintenance in Korea infrastructure facilities constructed since the 1970s has increased significantly compared to the demand for new construction. Moreover, after the Gyeongju and Pohang earthquakes, seismic performance evaluation, repair, and retrofitting projects have been carried out. Therefore, in this study, a specimen was designed following the L-type GFRP Plate Externally Bonded Retrofit method, one among other retrofit methods. The L-type GFRP Plate was bonded to the specimen by epoxy and a washered steel nail. A four-point bending test was performed to confirm the strengthening effect of the Externally Bonded Retrofit method using an L-type GFRP Plate. The strengthening effect of the L-type GFRP plate was proven experimentally, and the behavior of the beam designed following the L-type GFRP Plate Externally Bonded Retrofit method was evaluated according to Korea's "Design Manual & Specification for Strengthening of RC Structures by Advanced Composites System". Furthermore, the effectiveness of the bonding method, a combination of epoxy and washered steel nail, was also checked. The results showed that the design, according to the guidelines mentioned above, predicted the strength of the member well, but the failure mode did not satisfy the design assumption because of unexpected damage to the GFRP plate due to the fixing method, washered steel nail.