• Applied Chemistry for Engineering
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• v.30 no.1
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• pp.81-87
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• 2019

In this study, synthetic methods and physical properties for a new class of glycidyl azide polymer (GAP) were investigated for energetic thermoplastic elastomers (ETPE). Four kinds of GAP copolymer polyols were synthesized by introducing nucleophiles such as azide, alkoxide and alkyl amine into poly(epichlorohydrin) (PECH). The GAP copolymer synthetic reaction can be evaluated as an environmental benign and efficient synthetic method due to the simultaneous one-step reaction using two kinds of nucleophiles and the complete consumption of sodium azide. The relative stoichiometric substitution ratio analysis and the progress of reaction were checked and monitored by inverse gated decoupled $^{13}C$ NMR and Fourier transform infrared (FT-IR) spectroscopy. The glass transition temperature and molecular weight were measured by differential scanning calorimetry (DSC) and gel permeation chromatography (GPC) analysis. The synthesized poly($GA_{0.8}-butoxide_{0.2}$), poly($GA_{0.7}-n-butylamine_{0.3}$), poly($GA_{0.7}-dipropylamine_{0.3}$) and poly($GA_{0.7}-morpholine_{0.3}$) had a glass transition temperature ranged from -39 to $-26^{\circ}C$.

• Journal of the Korean Geotechnical Society
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• v.31 no.1
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• pp.15-24
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• 2015

This paper presents the results of a reduced-scale physical model investigation into the effect of drilling fluid with different mix designs for bore hole collapse prevention. The bore hole collapse prevention mechanism for the bentonite based drilling fluid was first discussed together with the effect of conditioning with different additives on engineering characteristics of bentonite based drilling fluid. Reduced-scale model tests were then carried out considering field procedures for cases with a decomposed granitic soil with 20% fines and a sand with various drilling fluids with different mix designs. The results indicated that the addition of polymer to the bentonite based drilling fluid decreases the amount of drilling fluid injected, the drilling fluid infiltration thickness and increases the final depth of excavation. Also revealed is that the effect of polymer on the performance of drilling fluid is more pronounced in the decomposed granite soil with 20% fines than the sand. Practical implications of the findings from this study are discussed in great detail.

• Journal of the Korean Magnetics Society
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• v.20 no.4
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• pp.153-159
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• 2010

Magnetic properties of basic rocks samples distributed in the seaside area of Ulleung island were investigated by means of X-ray fluorescence spectroscopy (XRF), M$\ddot{o}$ssbauer spectroscopy and SQUID magnetometer. We found that samples were typical basic rock which had the total amount of iron compounds varies from 10.6 wt% to 14.5 wt% depending on the different regions by XRF. The M$\ddot{o}$ssbauer spectra and magnetic hysteresis behaviors of the samples show ferromagnetic properties due to hematite. Also, temperature dependences of magnetization at applied magnetic field of 1 T for samples show magnetic transitions at 41 K~60 K.

• Journal of Educational Research in Mathematics
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• v.24 no.4
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• pp.481-498
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• 2014

This study analyzed Japan, Taiwan, Hongkong, Finland, and China National Mathematics Curriculums to find the implications to improve Korean High school Mathematics curriculum. First, at the aspect of mathematics education goals, we can consider to select the logical thinking, the use of mathematics, and the mathematical inquiry in the cognitive domain and self-confidence, brevity, a sense of accomplishment, and the value of mathematics in the affective domain. Second, when high students consider their course, he/she should be able to select mathematics subjects according to her/his desired career and/or major. Third, I found that sine rule, cosine rule and correlation were included as compulsory contents of Japan, Taiwan and China but not Korea. Finally I suggest that we need to show and explain kindly the range of the contents and to develop the Korean mathematics curriculum model.

• School Mathematics
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• v.8 no.4
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• pp.365-377
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• 2006

This article examines the Korean classroom teachers' perceptions about the 7th national mathematics curriculum for elementary school. Elementary classroom teachers were surveyed using the researcher-made questionnaire (Teacher Perception about Mathematics Curriculum) and 143 teachers completed the questionnaire. The data collected was analyzed by a descriptive analysis. The results revealed that about 67% teachers considered the curriculum was well developed in scope and sequence. However, 43% teachers reported that the teacher's manual should provide clearer explanation instructional strategies to teach the math topics to children. 38(26%) teachers claimed the curriculum contains too much content to teach. 34(24%) of the teachers indicated some contents were developmentally too difficult for their students to understand. The most serious difficulties for the teachers in teaching mathematics was to accommodate individual student's different mathematics abilities, especially accelerated by private lessons at the after school programs.

• Water for future
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• v.21 no.4
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• pp.389-397
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• 1988

For determination of the design wves at the seven selected sites in the South Sea, a method of hindcasting the past annual largest significant waves from the records of both the wind speed at the nearby weather stations and the weather charts of typhoons are utilized. The design significant waves in deep water are determined through the extremal probability analysis for three major wave directions(SW, S, SE) at each site from the annual extremal series of wave heights. Design significant wave heights with the return period of 100 years ranged between 4.6m and 8.8m with the wave period ranging between 8.2 seconds and 12.9 seconds. Through the analysis of weather maps, both the fetches for the wind directions SW-SE along the South Coast and the relationship between the wind speed at sea and the wind speed at the nearby land weather stations for seasonal winds are determined. The wind speed at sea are found to be 0.8-0.9 times the wind speed at the land stations for $U_1$>15m/s. The ratio of the duration-averaged wind speed to the maximum wind speed varies between 0.7-0.9 as a negative exponential function for the duration ranging 2< t< 13 hours.

• Journal of the Korean Institute of Gas
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• v.9 no.2 s.27
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• pp.50-55
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• 2005

The compositional and structural properties of alkali metal ion exchanged Y-zeolites have been investigated by la number of analytical techniques and their catalytic activities were tested for NOx reduction in combination with a non-thermal plasma. The NOx conversion data for LiY, NaY, KY and CsY were measured by chemiluminiscent NOx meter in the temperature range of 100 to $350^{\circ}C$. The initial activities of the catalyst at $150^{\circ}C$ increased in the order LiY < KY < NaY < CsY in alkali series. The activity of CsY and NaY were increased and showed maximum at $200^{\circ}C$ and then decreased in the plasma reactor, as the temperature increased. The activity of KY maintained same by $200^{\circ}C$ and then decreased, whereas the activity of LiY decreased with the increasing temperature. The CsY catalyst, which showed the highest activity in alkali metal series, exhibits a NOx conversion efficiency of $80\%$ between $170{\~}220^{\circ}C$.

• Proceedings of the Korea Water Resources Association Conference
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• 2020.06a
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• pp.88-88
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• 2020

수심평균 2차원 혼합모형은 하천환경에서 다양한 용존성 오염물질의 혼합현상을 모의하기 위해 널리 활용되어왔다. 2차원 혼합모형에서 분산계수는 하천의 전단 흐름에 의해 야기되는 오염물질의 퍼짐 현상을 표현하는 중요한 인자로서 작용하기 때문에 정교한 오염물질 혼합거동을 모의하기 위해서는 적합한 분산계수를 산정하는 것이 필수적이다. 분산계수를 실험적으로 산정하는 방법으로는 크게 모멘트법과 추적법으로 나뉘며, 비정상상태의 혼합거동에 대해 종방향 및 횡방향 분산계수를 동시에 산정할 수 있는 방법은 추적법 계열의 2차원 유관추적법(2D STRP)이 유일하다. 본 연구에서는 하천에 유입된 오염물질의 2차원 혼합해석을 위한 수치모형을 개발하였으며, 개발된 모형의 수치해를 바탕으로 다양한 Peclet 수의 범위에 대해 기존연구에서 제시된 2D STRP의 적용범위 및 성능을 정량적으로 분석하였다. 분석된 정보를 바탕으로 기존 2D STRP의 한계를 극복하기 위한 개선된 2차원 유관추적법(2D STRP-i)을 개발하고, 사행하천을 모형화한 실규모 하천실험시설에서 검증하였다. 기존 2D STRP의 성능평가 결과, Peclet 수가 낮은 조건일수록 농도분포의 예측 정확도가 감소하는 경향을 보였으며, 하안 경계에 도달하는 농도가 증가할수록 부정확한 결과를 초래하는 것으로 나타났다. 본 연구에서는 기존 2D STRP의 한계를 보완하여 더욱 정확한 분산계수를 산정하고자 하안 경계면 조건을 고려한 2차원 유관추적법(2D STRP-i)을 개발하였다. 2D STRP-i는 직교-곡선좌표계 기반의 2차원 이송-분산 방정식을 바탕으로 횡방향 유속분포 및 하안 경계조건을 고려할 수 있도록 개선되었다. 2D STRP-i는 공간적으로 상이한 이송효과 및 하안경계 조건을 적절히 반영함으로써 농도분포의 예측 정확도를 개선 시키는 것으로 평가되었으며, 하안경계면에서 농도가 증가하는 구간에서 기존 2D STRP의 결과와 비교하여 더욱 정확한 농도분포 및 분산계수를 제공하는 것으로 밝혀졌다.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.28 no.5
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• pp.303-311
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• 2016

From having an experimental study of physical and consolidation characteristics of soft clay in Nakdong river lower basin, we come to the conclusion as follow. Clay minerals in Nakdong river lower basin are classified into Kaolinite and Illite. Water content($W_n$) is similarly distributed in a range of 50.4% to 92.8% in Noksan and 46.6% to 99.0% in Jangyu, and liquid limit(LL) of both areas appears lower than water content. In the case of compression index, the index of jangyu is a little higher than that of Noksan because Jangyu is in a range of 0.67 to 1.94 and Noksan in a range of 0.44 to 1.5. The second compression index of Jangyu in a range of 0.027 to 0.092 is also higher than Noksan in a range of 0.024 to 0.075. As a result of regression analysis, a relation between water content and compression index is linear, and between initial void ratio and compression index is shown to $C_c=0.80e_o-0.58$. The ratio of $C_{\alpha}/C_c$ in a range of 0.03 to 0.08 expresses a wide range.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• v.y2005m4
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• pp.377-380
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• 2005

A study of ignition characteristics of cracked JP-7 fuel with both oxygen and air has been conducted over a wide range of pressures (1-20 atm), temperatures (1200-2000 K), and equivalence ratios (0.5-1.5). Correlations of ignition delay, of the form, $\tau=Aexp(E/RT)[F]^{a}[O_2]^{b}$ are established using the Chemkin-II package and least square analysis. The effect of $C_3$ hydrocarbons in cracked JP-7 fuel is examined by comparing the ignition delays for two different cracked compositions. A comparison for ignition delay is also made with the experimental results obtained by injecting liquid JP-7 fuel in air using a shock tube apparatus.