• Proceedings of the Korean Society Of Semiconductor Equipment Technology
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• 2006.10a
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• pp.190-197
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• 2006

2파장 백색 발광층의 구성에서 청색 재료로 GDI602 또는 GDI602: GDI691(2%)을, 황색 재료로 Alq3:Rubrene(10%)를 사용하여 새로운 백색 유기발광다이오드를 제작하고 이들의 특성을 분석하였다. 제작된 소자들은 12V의 구동전압에서 GDI602/A1q3:Rubrene(10%) 발광층을 갖는 경우 약 $950\;Cd/m^2$의 휘도와 0.8 lm/W의 효율을, GDI602:GDI691(2%)/Alq3:Rubrene 발광층을 갖는 경우 약 $1800\;Cd/m^2$의 휘도와 1.2 lm/W의 효율을 나타내었다. 또한 발광 스펙트럼의 특성으로는 인가전압에 따라 중심파장의 위치는 일정하나 2파장 사이의 상대적 세기가 변화되었으며, 인가전압이 증가할 경우 CIE 색좌표가 청색 방향으로 다소 이동되었다. GDI602/ Alq3:Rubrene(10%) 발광층을 갖는 소자의 경우 9V에서 x=0.33, y=0.32로, GDI602:GDI691(2%)/Alq3:Rubrene 발광층을 갖는 소자의 경우 6V에서 x=0.32, y=0.33으로 순수 백색광에 가까운 특성이 얻어졌다.

• Journal of the Korean Applied Science and Technology
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• v.26 no.1
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• pp.24-28
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• 2009

본 논문에서는 청색 인광 발광 물질인 bis(3,5-Difluoro-2-(2-pyridyl)phenyl-(2-carboxypyridyl) iridium (III) (Flrpic)과 녹색 인광 발광 물질인 fac-tris(2-phenypyridine) irdium(III) ($Ir(ppy)_3$)와 적색 인광 발광 물질인 his(5-benzoyl-2-phenylpyridinato-C,N)iridium(III) (acetylacetonate) ($(Bzppy)_{2}Ir(acac)$)를 각각 적층하여 백색 유기 발광 다이오드를 제작하였고, 각각의 발광층 사이에 혼합된 스페이서인 4,4'-N,N'-dicarbazole-biphenyl (CBP):4,7-diphenyl-1,10-phenanthroline (BPhen)을 적층하여 그 때의 영향에 대하여 연구하였다. 최적화된 구조에서의 전력 효율은 $0.014\;mA/cm^2$에서의 19.7 lm/w를 나타내었으며, $0.127\;mA/cm^2$에서의 11.5%의 외부 양자 효율을 나타내었고, 8 V에서 Commission Internationale do I'Eclairage ($CIE_{x,y}$) coordinates (x=0.36, y=0.44)의 색좌표를 나타내었다.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.238-238
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• 2016

백색 발광다이오드(LED)는 기존 조명(백열등, 형광등)에 비하여 월등히 에너지를 절약할 수 있어 이미 상업적, 정책적으로 교체가 진행 중이다. 현재의 백색 LED를 만들기 위해서는 필연적으로 형광체를 사용해야 한다. 그러나 이 형광체에 의한 (a)Stocks 에너지변환에 의한 효율감소, (b)높은 공정비용, (c) 열적 안정성 저하를 피할 수 없다. 우리는 유기금속화학증착(MOCVD)과 선택적성장(selective-area epitaxial growth)방법을 이용하여 형광체를 쓰지 않고 3차원 구조체를 이용하여 백색 LED를 제작하여 전기구동하였고 전류의 세기를 변화하여도 지속적으로 동일한 백색광을 유지함을 보였다. 광학적 분석(cathodoluminescence)과 구조적 분석(scanning electron microscope, transmission electron microscope)을 진행하여 구조를 살피고 백색 발광의 원인을 분석하였다. 또한, 고배율 대물렌즈를 사용한 공간분해 광학적 분석실험(photoluminescence와 electroluminescence 데이터를 비교)으로부터 국소적 운반자의 주입효율을 분석하는 방법을 고안하여 실험하였다.[1] 향후 이 방법은 3차원 구조체 LED뿐 아니라 2차원 LED에도 응용하여 LED의 주입효율을 분석하는데 유용하게 사용될 수 있을 것이라 기대된다.

• Proceedings of the Korean Society Of Semiconductor Equipment Technology
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• 2007.06a
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• pp.34-38
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• 2007

청, 황 2-파장 발광층의 구성에서 청색층으로 GDI602를, 황색층으로 GD1602:Rubrene(10%)를 사용하여 2-파장 백색 유기발광다이오드(WOLED)를 제작하고 이들의 특성을 분석하였다. 실험에서는 GDI602:Rubrene (10%)-황색층의 두께를 $220\{AA}$으로 일정하게 두고, GDI602-청색층의 두께를 달리하여 소자들을 제작하였다. 제작된 소자들의 발광 스펙트럼 특성으로는 GDI602 층의 두께에 따라 중심파장의 위치는 거의 일정하나 2-파장 사이의 상대적 세기가 변화되었으며, GDI602 층의 두께가 얇아질수록 황색파장의 상대적 세기가 강해지는 것을 볼 수 있었다. GDI602 층이 $60{\AA}$인 소자는 11V, $70{\AA}$인 소자는 9V, $80{\AA}$인 소자는 8V, $90{\AA}$인 소자는 7V 에서 순수 백색광(x=0.33, y=0.33)에 가까운 발광 특성을 나타내었다. 또한 GDI602 층의 두께에 따른 효율과 휘도는 백색발광 조건에서 각각 0.51m/W와 $3650cd/m^2(60{\AA})$, 0.61m/W와 $1050cd/m^2(70{\AA})$, 0.91m/W와 $490cd/m^2(80){\AA}$, 1.61m/W와 $250cd/m^2(90){\AA}$을 나타내었다.

• Journal of the Korean Applied Science and Technology
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• v.29 no.3
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• pp.459-465
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• 2012

We had synthesized a green dopant material based on the binaphthyl group, 7,7'-(2,2'dimethoxy-1,1'-binaphthyl-3,3'-diyl) bis(4-(thiophen -2-yl) benzo[e][1,2,5] thiadiazole (TBT). We also fabricated the white organic light emitting diode (OLED) with a phosphorescent blue emitter : iridium(III)bis[(4,6-di-fluoropheny)-pyridinato -N,C2]picolinate (FIrpic) doped in N,N'-dicarbazolyl-3,5-benzene (mCP) of hole transport type host material and both TBT and bis(2-phenylquinolinato)- acetylacetonate iridium(III) (Ir(pq)2acac) doped in 1,3,5-tris(N-phenylbenzimidazole -2-yl)benzene (TPBi) of electron transport type host material. As a result, the property of white OLED using TBT, which demonstrated a maximum luminous efficiency and external quantum efficiency of 5.94 cd/A and 3.23 %, respectively. It also showed the pure white emission with Commission Internationale de I'Eclairage (CIE) coordinates of (0.34, 0.36) at 1000 nit.

• Proceedings of the Korean Vacuum Society Conference
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• 2006.02a
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• pp.139-139
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• 2006

• Journal of the Microelectronics and Packaging Society
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• v.15 no.4
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• pp.59-64
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• 2008

In this paper, white polymer light emitting diodes(WPLEDs) were fabricated and investigated the electrical and optical properties for the prepared devices. ITO(indium tin oxide) and PEDOT:PSS [poly(3,4-ethylenedioxythiophene):poly(styrene sulfolnate)] as anode and hole injection materials, PFO [poly(9,9-dioctylfluorene)] and MEH-PPV [poly(2-methoxy-5(2-ethylhe xoxy)-1,4-phenylenevinyle)] were used as the light emitting host and guest materials, respectively. The LiF(lithium flouride) and Al(aluminum) were used electron injection materials and cathode materials. Finally, the WPLED with structure of ITO/PEDOT:PSS/PFO:MEH-PPV/LiF/Al was fabricated. The prepared WPLED showed white emission with CIE coordinates of (x=0.36, y=0.35) at the applied voltage of 9V. The maximum current density and luminance were about $740mA/cm^2\;and\;900cd/m^2$ at 13V, respectively. And the maximum current efficiency was 0.37 cd/A at $200cd/m^2$ in luminance.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.19 no.4
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• pp.379-385
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• 2006

A stacked white organic light-emitting diode (OLED) having a blue/orange emitting layer was fabricated by synthesizing nitro-DPVT, a new derivative of the blue-emitting material DPVBi on the market. The white-emission of the two-wavelength type was successfully obtained by using both nitro-DPVT for blue~emitting material, orange emission as a host material and Rubrene for orange emission as a guest material. The basic structure of the fabricated white OLED is glass/ITO/NPB$(200{\AA})$/nitro-DPVT$(100{\AA})$/nitro-DPVT:$Rubrene(100{\AA})/BCP(70{\AA})/Alq_3(150{\AA})/Al(600{\AA})$. To evaluate the. characteristics of the devices, firstly, we varied the doping concentrations of fluorescent dye Rubrene from 0.5 % to 0.8 % to 1.3 % to 1.5 % to 3.0 % by weight. A nearly pure white-emission was obtained in CIE coordinates of (0.3259, 0.3395) when the doping concentration of Rubrene was 1.3 % at an applied voltage of 18 V. Secondly, we varied the thickness of the NPB layer from $150{\AA}\;to\;200{\AA}\;to\;250{\AA}\;to\;300{\AA}$ by fixing doping with of Rubrene at 1.3 %. A nearly pure white-emission was also obtained in CIE coordinates of (0.3304, 0.3473) when the NPB layer was $250-{\AA}$ thick at an applied voltage of 16 V. The two devices started to operate at 4 V and to emit light at 4.5 V. The external quantum efficiency was above 0.4 % when almost all of the current was injected.

• Korean Journal of Materials Research
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• v.16 no.4
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• pp.231-234
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• 2006

To obtain balanced white-emission and high efficiency of the organic light-emitting diodes (OLEDs), a deep blue emitter made of N,N'-diphenyl-N,N'-bis(1-naphthyl)- (1,1'-biphenyl)-4,4'-diamine (NPB) emitter and a new red emitter made of the Bis(2,4 -dimethyl-8-quinolinolato)(triphenylsilanolato)aluminum(III) (24MeSAlq) doped with red fluorescent 4-(dicyanomethylene)-2-tert-butyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H -pyran (DCJTB) were used and the device was tuned by varying the thickness of the DCJTB-doped 24MeSAlq and $Alq_3$. For the white OLED with 10 nm thickness DCJTB (0.5%) doped 24MeSAlq and 45 nm thick $Alq_3$, the maximum luminance of about 29,700 $Cd/m^2$ could be obtained at 14.8 V. Also, Commission Internationale d'Eclairage (CIE) chromaticity coordinates of (0.32, 0.28) at about 100 $Cd/m^2$, which is very close to white light equi-energy point (0.33, 0.33), could be obtained.

• Korean Journal of Materials Research
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• v.26 no.3
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• pp.117-122
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• 2016

White organic light-emitting diodes with a structure of indium-tin-oxide [ITO]/N,N-diphenyl-N,N-bis-[4-(phenylm-tolvlamino)-phenyl]-biphenyl-4,4-diamine [DNTPD]/[2,3-f:2, 2-h]quinoxaline-2,3,6,7,10,11-hexacarbonitrile [HATCN]/1,1-bis(di-4-poly-aminophenyl) cyclo -hexane [TAPC]/emission layers doped with three color dopants/4,7-diphenyl-1,10-phenanthroline [Bphen]/$Cs_2CO_3$/Al were fabricated and evaluated. In the emission layer [EML], N,N-dicarbazolyl-3,5-benzene [mCP] was used as a single host and bis(2-phenyl quinolinato)-acetylacetonate iridium(III) [Ir(pq)2acac]/fac-tris(2-phenylpyridinato) iridium(III) $[Ir(ppy)_3]$/iridium(III) bis[(4,6-di-fluoropheny)-pyridinato-N,C2] picolinate [FIrpic] were used as red/green/blue dopants, respectively. The fabricated devices were divided into five types (D1, D2, D3, D4, D5) according to the structure of the emission layer. The electroluminescence spectra showed three peak emissions at the wavelengths of blue (472~473 nm), green (495~500 nm), and red (589~595 nm). Among the fabricated devices, the device of D1 doped in a mixed fashion with a single emission layer showed the highest values of luminance and quantum efficiency at the given voltage. However, the emission color of D1 was not pure white but orange, with Commission Internationale de L'Eclairage [CIE] coordinates of (x = 0.41~0.45, y = 0.41) depending on the applied voltages. On the other hand, device D5, with a double emission layer of $mCP:[Ir(pq)_2acac(3%)+Ir(ppy)_3(0.5%)]$/mCP:[FIrpic(10%)], showed a nearly pure white color with CIE coordinates of (x = 0.34~0.35, y = 0.35~0.37) under applied voltage in the range of 6~10 V. The luminance and quantum efficiency of D5 were $17,160cd/m^2$ and 3.8% at 10 V, respectively.