• Korean Chemical Engineering Research
• /
• v.57 no.3
• /
• pp.400-407
• /
• 2019

Oxy-combustion with a circulating fluidized bed (Oxy-CFBC) technology has been paid attention to cope with the climate change and fuel supply problem. In addition, Oxy-CFBC technology as one of the methods for carbon dioxide capture is an eco-friendly that can reduce air pollutants, such as $SO_2$, NO and CO through a flue gas recirculation process. The newly developed $100kW_{th}$ pilot-scale Oxy-CFBC system used for this research has been continuously utilizing to investigate oxy-combustion characteristics for various fuels, coals and biomasses to verify the possibility of fuel diversification. The anthracite is known as a low reactivity fuel due to a lot of fixed carbon and ash. Therefore, this study aims not only to improve combustion efficiency of an anthracite, but also to capture carbon dioxide. As a result, compared to air-combustion of sub-bituminous coal, oxy-combustion of anthracite could improve 2% combustion efficiency and emissions of $SO_2$, CO and NO were reduced 15%, 60% and 99%, respectively. In addition, stable operating of Oxy-CFBC could capture above 94 vol.% $CO_2$.

• 한국신재생에너지학회:학술대회논문집
• /
• 2010.06a
• /
• pp.110.2-110.2
• /
• 2010

현재 상용가능한 연소전 $CO_2$ 포집 기술은 습식 스크러빙 방식으로 고온의 합성가스를 상온 수준으로 온도를 낮춘 후 $CO_2$를 포집해야 하고 포집된 $CO_2$의 압력이 낮아 재압축하여 저장소로 보내야 함에 따라 큰 폭의 열효율 손실이 불가피하다. 고온 고압에서 이산화탄소를 포집할수 있는 고체 흡수제를 이용할 경우 이산화탄소 포집 치 저장 추가에 따른 시스템 효율 저하를 최소화할 수 있다. 고체 $CO_2$ 흡수제는 서로 연결된 두 개의 유동층 반응기를 순환하면서 흡수탑에서는 합성가스 중의 $CO_2$를 흡수하고 재생탑에서는 고온의 수증기와 접촉하여 흡수된 $CO_2$를 다시 배출함으로써 재생된다. 따라서 건식 재생 $CO_2$ 흡수제는 유동층 공정에 응용가능한 물성과 함께 높은 $CO_2$ 흡수능과 빠른 반응성이 요구된다. 본 연구에서는 유동층 공정에 적합한 물성을 가진 연소전 $CO_2$ 포집용 고체 흡수제를 분무건조법으로 제조하였으며, 모사 합성가스를 이용하여 열중량분석기와 기포유동층반응기를 이용하여 $200^{\circ}C$ 흡수, $400^{\circ}C$ 재생, 압력 20 bar 조건으로 반응성을 측정하였다. 개발된 고체 $CO_2$ 흡수제는 열중량분석기에서는 반응 후 10-13 wt%의 무게증가를 나타내었고 기포유동층반응기에서는 8-10 wt%의 $CO_2$ 흡수능을 보여주었다. 특히 수증기의 함량이 10% 이상에서 높은 흡수능을 나타내어 수증기가 반응에 크게 작용하고 있음을 알 수 있었다.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.21 no.2
• /
• pp.188-193
• /
• 2015

It has been generally recognized that $N_2O$(Nitrous Oxide) emission from marine diesel engines has a close correlation with $SO_2$(Sulfur Dioxide) emission, and diversity of fuel elements using ships affects characteristics of the $N_2O$ emission. According to recent reports, in case of existence of an enough large NO(Nitric Oxide) generated as fuel combustion, effect of the $SO_2$ emission in exhaust gas on the $N_2O$ formation is more vast than effect of the NO. Therefore, $N_2O$ formation due to the $SO_2$ element operates on a important factor in EGR(Exhaust Gas Recirculation) systems for NOx reduction. An aim of this experimental study is to investigate that intake gas of the diesel engine with increasing of $SO_2$ flow rate affects $N_2O$ emission in exhaust gas. A test engine using this experiment was a 4-stroke direct injection diesel engine with maximum output of 12 kW at 2600rpm, and operating condition was set up at a 75% load. A standard $SO_2$ gas with 0.499%($m^3/m^3$) was used for changing of $SO_2$ concentration in intake gas. In conclusion, the diesel fuel included out sulfur elements did mot emit the $SO_2$ emission, and the $SO_2$ emission in exhaust gas according as increment of the $SO_2$ standard gas had almost the same ratio compared with $SO_2$ rate in mixture inlet gas. Furthermore, the $N_2O$ element in exhaust gas was formed as $SO_2$ mixture in intake gas because increment of $SO_2$ flow rate in intake gas increased $N_2O$ emission. Hence, diesel fuels included sulfur compounds were combined into $SO_2$ in combustion, and $N_2O$ in exhaust gas should be generated to react with NO and $SO_2$ which exist in a combustion chamber.

• Clean Technology
• /
• v.27 no.4
• /
• pp.367-371
• /
• 2021

The oxy-combustion system is one of the carbon recovery and storage technologies (CCS: Carbon capture & storage) that performs coal combustion using pure oxygen and recirculated flue gas. This is a technology that facilitates storage of carbon dioxide by generating an exhaust gas consisting of only carbon dioxide without a process of separating carbon dioxide and nitrogen when coal is burned using pure oxygen and recirculated flue gas mixture instead of a conventional air combustion system that produces carbon dioxide and nitrogen mixed exhaust gas. In this study, the characteristics of generated NO and SO₂ as atmospheric pollutants during oxy-combustion were examined using O₂/CO₂ mixed simulation gas. The reaction temperature was varied from 900 ℃ to 1200 ℃ and oxygen partial pressure was varied from 30% to 50%. The results showed that NO and SO₂ concentrations in flue gas increased as the oxygen concentration and the reaction temperature in the furnace increased. The partial pressure of CO₂ in flue gas also increased as the oxygen concentration and the reaction temperature in the furnace increased. As a results of comparing NO production of 30% O₂/CO₂ oxy-combustion with air combustion, NO in flue gas increased with reaction temperature in both experiments and NO of oxy-combustion was 40 ~ 80 ppm lower than that of air combustion.

• Journal of the Institute of Electronics Engineers of Korea TE
• /
• v.39 no.1
• /
• pp.71-76
• /
• 2002

Because the driving time is increased under the low speed by rapidly increasing of vehicles, this paper is presented a new ignition control system for improvement the fuel economy, which only some of cylinders are using under the idle status or low speed and preserving the engine rpm. is applicable to effective in fuel economy. An actual hardware was made to prove this new control system. The developed variable cylinder engine concentrated the heat neat the cylinders in idle status or low speed, so there was a problem in re-ignition. It was the reason of a lot of exhaust gas, high fuel consumption and instability of engine revolution. In this paper, in order to solve above problem to show the improvement fuel economy using the new ignition control system and valve opening period at idle status of low speed.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.15 no.6
• /
• pp.151-158
• /
• 2007

The static and dynamic behaviour of VGT and EGR systems has a significant impact on overall engine performance, fuel economy and exhaust emissions. This is because they define the state and composition of the air charge entering the engine. This work focused on the effect of the aperture ratio of VGT and EGR on the emission and flow characteristics under partial loads conditions. The investigation carried out using 2 liter PCCI 4 cylinder diesel engine with VGT and EGR. The result of this study shows that smoke increases with increasing EGR rate and NOx decreases with increasing EGR rate. It was also found that the residual gas contents greatly impact on soot emission under partial load condition. Finally, it can be concluded that VGT and EGR aperture ratio can greatly impact not only on soot and NOx but also air charging.

• Journal of Power System Engineering
• /
• v.17 no.6
• /
• pp.18-24
• /
• 2013

An experimental study was performed to investigate the characteristics of combustion pressure and exhaust emissions when the pilot injection timing and EGR rate were changed in a CRDI 4-cylinder diesel engine. The pilot injection timing and EGR rate have a significant impact on the combustion and emission characteristics of diesel engine. In this study, the pilot injection timing and EGR rate variation were conducted to 2000rpm of engine speed with torque 50Nm. Combustion pressure and heat release rate were decreased under high EGR rate conditions but increased under the pilot injection timing $20^{\circ}$(BTDC). IMEP and the maximum pressure in cylinder(Pmax) were decreased under the same injection timing with the increase of EGR rate. The NOx emission was decreased with increasing the EGR rate. On the other hand, in the same injection timing conditions, CO, HC, $CO_2$ emissions were increased with increasing the EGR rate.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.27 no.11
• /
• pp.1630-1636
• /
• 2003

Automobile companies and research institutions in leading automobile-manufacturing nations have recently been very active with research regarding the HCCI engine for use in future vehicles. Because HCCI engines take advantage of high compression ratio and heat release rate, they exhibit high efficiency found in compression ignition engines. HCCI engines also utilize a lean air/fuel ratio resulting in low emissions of NO$_{x}$ and PM (particulate matter). The objective of this research is to determine the effects of EGR rate on the combustion processes of HCCI. for this purpose, a 4-cylinder, compression ignition engine was converted into a HCCI engine, and a heating device was installed to raise the temperature of the intake air and also to make it more consistent. In addition, a pressure sensor was inserted into each of the cylinders to investigate the differences in characteristics among the cylinders. The experimental study of the effects of EGR rate on various gas emissions, engine performance, etc. should prove to be a valuable source of information for the development of the HCCI engine.e.

• Journal of Institute of Convergence Technology
• /
• v.7 no.1
• /
• pp.15-18
• /
• 2017

As emission gas regulation of deisel vehicles is strengthened to Euro-6, It becomes difficult to deal with NOx regulated value mainly by EGR without additional after-treatment system. In addition, RDE(Real Driving Emissions) test will be introduced after september 2017. Therefore, It is essential to develop the after-treatment of diesel vehicles which reduce NOx emissions. It is possible to use DOC, DPF, LNT or DOC, DPF and SCR as a after-treatment system for reducing NOx. However, It is expected that the SCR will be applied widely because LNT alone does not have sufficient NOx purification efficiency. In this study, It tried to analyze the efficiency of reducing NOx emissions during the mode test by attaching a NOx sensor to test vehicle. As a result, It was confirmed that NOx emissions was significantly reduce through the after-treatment system from engine. And the NOx reduction efficiency of SCR was about 4.5 times better than DOC, DPF.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.22 no.9
• /
• pp.1238-1246
• /
• 1998

Recently, the automobile industry has been faced with very serious problems related to the very restricted regulations of exhaust gas emissions. Therefore many researchers have been attracted to the development of oxygenated fuel for a solution to these problems. This paper deals with the effects of oxygenated fuel on exhaust emissions. An experimental study was conducted to investigate PM and $NO_X$ emission using dimethyl carbonate as an oxygenated fuel in a naturally aspirated DI diesel engine. With increased oxygenated fuel amounts. there were significant reductions in PM, HC and CO emissions mainly from depressed thermal cracking. while little increase in $NO_X$ was encountered concurrently. The effective reduction in PM with oxygenated fuel was maintained with the presence of $CO_2$. which suggested low $NO_X$ and PM obtained from the combination of using oxygenated fuel and cooled EGR. Thermal cracking and an analysis of the heat release rate were also studied in the experiment.