• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.07a
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• pp.667-670
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• 2000

The electrochemical characterization was conducted by the addition of chemically synthesized polyaniline on LiCoO$_2$electrode. From the results of XRD and SEM, the phase transition and microstructure were not found. Initial electrochemical characteristics of LiCoO$_2$electrode for lithium secondary battery were evaluated through the charge/discharge within the range of 4.3 V to 3.0 V versus Li/Li$^{+}$. Discharge capacity of LiCoO$_2$electrode without addition of Polyaniline were 160.21 mAh/g. But after addition of polyaniline, lower discharge capacities 25.7 mAh/g was found.d.

• Korean Journal of Materials Research
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• v.7 no.6
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• pp.529-535
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• 1997

Li ion전지용 LiMn$_{2}$O$_{4}$분말을 졸-겔법과 고상반응법으로 제조하여 분말의 특성과 전지의 특성을 비교하였다. 졸-겔법에 의해 제조된 LiMn$_{2}$O$_{4}$분말은 고상반응법에 의해 제조된 분말보다 낮은 온도에서 합성이 가능하고, 균질하고 작은 입자들로 구성되었으며, Li stoichiometry가 우수하여 전지의 방전용량이 크나 양이온 혼합도가 높아 전지의 내부저항이 크게 나타났다. 졸-겔법은 높은 Li stoichiometry와 균질한 입자 크기를 갖는 LiMn$_{2}$O$_{4}$분말 제조에 적당한 것으로 생각되며, 전지의 내부저항 문제는 분말의 하소온도와 냉각속도의 조절에 의해 가능할 것으로 판단된다.

• Proceedings of the KIPE Conference
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• 2015.11a
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• pp.113-114
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• 2015

본 논문은, 태양광 및 차세대 이동수단에 적용되는 리튬-이온 전지의 전기적 모델링를 수행하였다. 전지의 전기적 모델링을 통하여 충 방전 특성, 용량, 개방 전압, 내부 저항과 같은 전지의 특성을 모의함으로써, 다양한 환경에서 어플리케이션에 적용할 전지를 테스트해 볼 수 있다. 리튬-이온 전지는 LGD 18650 B4(2,600mAh) 모델을 사용하였으며, 실험과 시뮬레이션을 통하여 설계된 모델의 타당성을 검증한다.

• Proceedings of the KIPE Conference
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• 2018.11a
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• pp.45-47
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• 2018

본 논문은 High Altitude Electromagnetic Pulse (HEMP) 응용 분야에 적용되는 리튬 이온 베터리를 이용한 커패시터 충전전원 장치에 관하여 다룬다. 기존에 제안하였던 5.4 kJ/s 고전압 커패시터 충전기를 9 kJ/s 로 용량을 늘렸고, 고전압 커패시터 충전기 후단에 공진 충전 회로를 도입하여 2단 충전 구조로 펄스 방전 시 발생할 수 있는 역전압과 reflecting pulses로 부터 커패시터 충전 전원 장치를 보호한다. 제안하는 충전기의 성능은 시뮬레이션 및 기초 부하 실험을 통해 확인되었다.

• Proceedings of the KIPE Conference
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• 2020.08a
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• pp.85-87
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• 2020

고전압 커패시터는 회로 전체 안전성의 이유로 신뢰도를 유지하는 것이 매우 중요하다. 따라서 커패시터는 다양한 특성에 대해 시험이 필요하며 이때 장비가 필요하게 된다. 커패시터 시험용 특성으론 용량, 내전압, 전압 변화량, I_rms, I_peak가 있는데, 이 중 전류(I_rms, I_peak) 시험기의 경우 시중에 거의 없고, 매우 고가에 거래가 되고 있다. 이는 기존 전류 시험기가 CCCV(constant current constant voltage) 충/방전 회로를 사용하여 높은 전력을 공급하는 Power Supply가 요구되기 때문이다. 본 논문은 상기 기존 기술의 문제점을 해결하고자 공진회로를 이용하여 새로운 커패시터 전류 시험기를 설계하였고, Simulation을 통해 제안 전류 시험기의 가능성을 검토하였다.

• Proceedings of the KIPE Conference
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• 2020.08a
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• pp.359-360
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• 2020

리튬 이온 배터리가 전기 자동차의 주 동력원으로 사용됨에 따라 배터리의 잔존 수명 예측기술의 중요성이 부각되고 있다. 사용 환경에 적합한 잔존 수명 예측을 위해 전기 자동차의 주행 환경을 모사하여 충전 및 방전이 빈번하게 나타나는 UDDS 프로파일에서 범용적으로 사용할 수 있는 수명 인자를 선정하는 것이 필수적이다. 배터리의 잔존 용량과 가장 상관도가 높은 수명 인자를 선정함으로써, 인공지능 기반 예측 알고리즘의 정확도 향상을 기대 할 수 있으며, 태양광 ESS와 같은 상이한 특성의 어플리케이션에도 범용적인 적용이 가능하다.

• Korean Chemical Engineering Research
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• v.58 no.1
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• pp.142-149
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• 2020

In this study, the electrochemical performance of Graphite/Silicon/Pitch composites as anode material was investigated to improve the low theoretical capacity of artificial graphite. Spherical artificial graphite surface was coated with polyvinylpyrrolidone (PVP) amphiphiles material to synthesize Graphite/Silica material by silica islands growth. The Graphite/Silicon/Pitch composites were prepared by petroleum pitch coating and magnesiothermic reduction. The Graphite/Silicon/Pitch composite electrodes manufactured using poly(vinylidene fluoride) (PVDF), carboxymethyl cellulose (CMC) and polyacrylic acid (PAA) binders. The coin type half cell was assembled using various electrolytes and additives. The Graphite/Silicon/Pitch composites were analysed by X-ray diffraction (XRD), scanning electron microscope (SEM) and a thermogravimetric analyzer (TGA). The electrochemical characteristics of Graphite/Silicon/Pitch composite were investigated by constant current charge/discharge, rate performance, cyclic voltammetry and electrochemical impedance spectroscopy. The Graphite/Silicon/Pitch composites showed high cycle stability at a graphite/silica/pitch ratio (1:4:8 wt%). When the electrode is prepared using PAA binder, the high capacity and stability is obtained. The coin type half cell assembled using EC: DMC: EMC electrolyte showed high initial capacity (719 mAh/g) and excellent cycle stability. The rate performance has an capacity retention (77%) at 2 C/0.1 C and an capacity recovery (88%) at 0.1 C / 0.1 C when the vinylene carbonate (VC) was added.

• Korean Chemical Engineering Research
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• v.57 no.6
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• pp.832-840
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• 2019

To improve the electrochemical performances of the cathode materials, boron-doped $LiNi_{0.90}Co_{0.05}Ti_{0.05}O_2$ were synthesized by using concentration gradient precursor. The characteristics of the prepared cathode materials were analyzed by XRD, SEM, EDS, PSA, ICP-OES and electrical conductivity measurement. The electrochemical performances were investigated by initial charge/discharge capacity, cycle stability, C-rate, cyclic voltammetry and electrochemical impedance spectroscopy. The cathode material with 0.5 mol% boron exhibited a capacity of 187 mAh/g (0.5 C) in a voltage range of 2.7~4.3 V(vs. $Li/Li^+$), and an capacity retention of 94.7% after 50 cycles. In the relatively high voltage range of 2.7~4.5 V(vs. $Li/Li^+$), it showed a high capacity of 200 mAh/g and capacity retention of 80.5% after 50 cycles.

• Journal of the Institute of Electronics and Information Engineers
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• v.54 no.4
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• pp.99-107
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• 2017

This paper proposes a battery model coefficient correction method for improving the accuracy of existing lithium battery equivalent models. BMS(battery management system) has been researched and developed to minimize shortening of battery life by keeping SOC(state of charge) and state of charge of lithium battery used in various industrial fields such as EV. However, the cell balancing operation based on the battery cell voltage can not follow the SOC change due to the internal resistance and the capacitor. Various battery equivalent models have been studied for estimation of battery SOC according to the internal resistance of the battery and capacitors. However, it is difficult to apply the same to all the batteries, and it tis difficult to estimate the battery state in the transient state. The existing battery electrical equivalent model study simulates charging and discharging dynamic characteristics of one kind of battery with error rate of 5~10% and it is not suitable to apply to actual battery having different electric characteristics. Therefore, this paper proposes a battery model coefficient correction algorithm that is suitable for real battery operating environments with different models and capacities, and can simulate dynamic characteristics with an error rate of less than 5%. To verify proposed battery model coefficient calibration method, a lithium battery of 3.7V rated voltage, 280 mAh, 1600 mAh capacity used, and a two stage RC tank model was used as an electrical equivalent model of a lithium battery. The battery charge/discharge test and model verification were performed using four C-rate of 0.25C, 0.5C, 0.75C, and 1C. The proposed battery model coefficient correction algorithm was applied to two battery models, The error rate of the discharge characteristics and the transient state characteristics is 2.13% at the maximum.

• Journal of the Korean Electrochemical Society
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• v.21 no.3
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• pp.47-54
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• 2018

To maximize the areal capacity($mAh\;cm^{-2}$) of $LiNi_{0.5}Co_{0.2}Mn_{0.3}O_2$(NCM523) electrode with the same loading level of $15mg\;cm^{-2}$, three NCM523 electrodes with 4, 2, and 1 wt% poly(vinylidene fluoride)(PVdF) binder content are fabricated. Due to the delamination issue of electrode composite at the edge during punching process, the 1 wt% electrode is excluded for further evaluation. When the PVdF binder content decreases from 4 to 2 wt%, both adhesion strength and shear stress decrease from 0.4846 to $0.2627kN\;m^{-1}$ by -46% and from 3.847 to 2.013 MPa by -48%, respectively. Regardless of these substantial decline of mechanical properties, their initial electrochemical properties such as initial coulombic efficiency and voltage profile are almost the same. However, owing to high loading level, the 2 wt% electrode not only exhibits worse cycle performance than the 4 wt% electrode, but also cannot maintain its mechanical integrity only after 80 cycles. Therefore, if the binder content is reduced to increase the area capacity, the mechanical properties as well as the cycle performance must be carefully evaluated.