• Polymer(Korea)
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• v.32 no.2
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• pp.183-188
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• 2008

Reinforced open cell micro structured foams were prepared by the polymerization of high internal phase emulsions incorporating inorganic thickeners. Organoclays were used as oil phase thickener, and sodium montmorillonite was used as aqueous phase thickener. Rheological properties of emulsions increased as oil phase thickener concentration and agitation speed increased, due to the reduced drop size reflecting both competition between continuous and dispersed phase viscosities and increase of shear force. Drop size variation with thickener concentration could be explained by a dimensional analysis between capillary number and viscosity ratio. Upon the foams polymerized by the emulsions, compression properties, such as crush strength and Young's modulus were measured and compared. Among the microcellular foams, the foam incorporated with an organoclay having reactive group showed outstanding properties. It is speculated that the exfoliated silicate layers inside polystyrene matrix, resulting in nanocomposite foam, are the main reason why this foam has enhanced properties.

• Polymer(Korea)
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• v.36 no.1
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• pp.34-40
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• 2012

The foaming of poly(butylene succinate) (PBS) using supercritical $CO_2(scCO_2)$ was studied. In order to improve the melt strength, PBS was modified using the reactive compounding technique. Rapid decompression of $scCO_2$-saturated PBS at a temperature above the depressed $T_m$ yielded expanded microcellular foams. The resulting foam structure could be controlled by manipulating process conditions. Experiments varying the foaming temperature while holding other variables constant showed that higher temperatures produced larger cells and reduced cell densities. Higher saturated pressures led to higher nucleation densities and smaller cell sizes. Decreasing the rate of depressurization permitted a longer period of cell growth and therefore larger cells were obtained.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.1
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• pp.74-79
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• 2022

In this study, the effect of a sudden decrease in internal humidity and a decrease in hydration level due to the tight internal structure of high-strength concrete and cement composites was investigated. To verify the change in the internal Si hydration, waste glass foam beads were used as a lightweight aggregate, and the internal unreacted hydrate reduction and hydrate formation tendency were identified over the mid- to long-term. Waste glass foam beads were mixed with 5, 10, and 20 %, and were used by pre-wetting. As the mixing rate of the waste glass foamed beads increased, the strength showed a tendency to decrease. In addition, when the mixing amount of pre-wetted waste glass foam beads increases inside through XRD analysis, TGA analysis, and Si NMR analysis, it is judged that the hydration degree of internal Si is different because moisture is supplied to the paste.

• Polymer(Korea)
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• v.39 no.2
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• pp.210-218
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• 2015

The reaction behavior of rigid polyurethane foams were studied on the effects of gelling catalysts of amine type, such as; dimethylcyclohexyl amine (DMCHA) and of potassium type, such as; potassium octoate (PO). Rigid polyurethane foams were provided with polymeric 4,4'-diphenylmethane diisocyanate, polyester polyol, silicone surfactant, blowing agent and a few gelling catalysts. As the contents of catalyst, DMCHA increased from 0 to 2.0 g, the reaction time decreased from ca. 330 to ca. 35 sec and due to the exothermic reaction, the maximum temperature increased from ca. 217 to ca. $234^{\circ}C$, respectively. As the contents of PO increased from 0 to 2.5 g, the reaction time decreased from ca. 79 to ca. 38 sec and the maximum temperature increased from ca. 182 to ca. $271^{\circ}C$, respectively. The kinetic parameters were calculated and the conversions were based on the temperature rising method of adiabatic process. As the content of DMCHA increased, the rate constant $k_0$ increased. But in the case of PO catalyst, $k_0$ did hardly depend upon its amount, and showed us similar reaction rate constants.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.30 no.1
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• pp.63-72
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• 2024

Poly (butylene adipate-co-terephthalate) (PBAT) is one of the representative biodegradable polymers with high ductility and processability to replace petroleum-based polymers. Many investigations have been conducted to broaden the applications of PBAT in a variety of industries, including the food packaging, agricultural mulching film, and logistics and distribution fields. Foaming process is widely known technique to generate the cell structure within the polymer matrix, offering the insulation and light weight properties. However, there was no commercially feasible foam product based on biodegradable polymers, especially PBAT, and maintaining a proper melt viscosity of the polymer would be a key parameter for the foaming process. In this study, chemical foaming agent and cross-linking agent were introduced to PBAT, and a compression molding process was applied to prepare a foam sheet. The correlation between cell morphological structures and mechanical and physical properties was evaluated. It was found that PBAT with foam structures effectively reduced the density and thermal conductivity, allowing them to be suitable for applications such as insulation and lightweight packaging or cushion materials.

• Proceedings of the Korea Water Resources Association Conference
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• 2009.05a
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• pp.1817-1821
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• 2009

최근 전자제품 사용의 증가로 인해 버려지는 전자제품의 양도 함께 증가하고 있으며 이렇게 늘어난 전자폐기물이 부적절한 방식으로 처리될 경우 우리에게 악영향을 미치는 위험물질이 될 수 있다. 본 연구에서는 이러한 전자폐기물 중 하나인 폐 LCD 유리를 이용한 수질정화용 여재를 이용하여 전자폐기물에 의한 오염을 줄이고, 동시에 강우시 표면 유출로 인하여 발생되는 비점오염을 제어하고자 하였다. 본 연구에서 이용한 수처리 여재는 기존 수처리 여재의 단점을 보완하는 대체 여재 개발이라는 목적에 적합할 것으로 판단된다. 이에 본 연구에서 발포기술이 적용된 폐 LCD 유리 여재의 비점오염에 의한 수질정화능력평가를 하기 위해 실험 장치를 구성하여 실험하였다. 반응조는 직경 0.10 m, 높이 0.75 m 크기(총용량= 5.89 $\ell$)로 두께 10mm의 투명 아크릴판으로 3조를 제작하였다. 유입수는 미량 펌프를 이용하여 유입하였다. 각 반응조의 체류시간에 의한 수질정화능력을 평가하였다. 연구 결과, 오염물질에 대한 제거효율 범위는 SS $64.1%\sim88.2%$, BOD $29.8\sim52.4%$, COD $56.8\sim66.1%$, T-N $39.4\sim\;52.3%$, T-P $14.1\sim36.8%$로 나타났다. 체류시간이 가장 길었던 반응조의 경우, 대부분의 측정항목에서 높은 처리 효율을 볼 수 있었다. 초기에 처리 효율이 낮은 것은 미생물이 부착되지 않았기 때문이라고 판단되며, 실험의 중반과 후반에서 미생물이 부착이 되는 시점부터 높은 처리효율을 보이는 것으로 나타났다.

• Elastomers and Composites
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• v.38 no.4
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• pp.316-325
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• 2003

The blends of waste-polyethylene (W-PE)/waste-ethylene vinyl acetate copolymer (W-EVA) with inorganic and phosphorous flame retardants (i.e., aluminium hydroxide, magnesium hydroxide, and so on) were prepared by melt mixing techniques at different compositions and foamed. The flame retardancy and foaming properties of the blends, limiting oxygen index (LOI), heat release rate (HRR), carbon monoxide yield (COY), total heat release (THR), effective heat of combustion (EHC), expandability and cell structure were investigated using cone calorimeter, SEM, LOI tester and polarizing microscope. When the composition ratios of the W-PE/W-EVA blends were 50/50 (w/w), and the ranges of the flame retardants contents were $175{\sim}220 phr$, we could obtain foams with the uniform and closed cell, high expandability (1900 % or more), high LOI, and low HRR values. These results depend on crosslinking and loaming conditions, a char formation and smoke suppressing effect. Aluminium hydroxide had more effect in the increase of LOI than magnesium hydroxide, while magnesium hydroxide considerably affected the decrease of HRR and COY.

• The Journal of Engineering Geology
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• v.30 no.2
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• pp.185-198
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• 2020

High-density rapid expansion material is a method that increases the solid volume of injection materials due to hydration and foam reactions at the same time as spraying. It is an effective method for securing ground stability, restoring subsidence, and loading during construction of structures. In this regard, through the mechanical experiments of injection materials, the stability of the foundation ground of the structure and the effect of increasing the endurance using site construction were analyzed. The results of the experiment showed that the unit weight of soil decreased by 10.5% after injection of the filling material, and the allowable support for the structure was deemed safe, and the subsidence by each section after ground improvement was determined to be safe at 2.28, 1.55 and 0.46 cm, respectively, with an acceptable subsidence of less than 5 cm. After the field test, five inclinometers were installed on the top floor of the target building to measure the displacement of the X and Y axes. As a result of the measurement, no displacement related to the phenomenon of inequality or subsidence cracks of the structure was measured for about 16 months (509 days) after construction. This can be judged to be a sufficient increase in the stability of the ground after the injection of rapid expansion.

• Journal of the Korean Institute of Gas
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• v.5 no.4 s.16
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• pp.79-84
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• 2001

In this study, the effect of polyol structure(OH-value, functionality) on the reactivity, mechanical property and cell morphology of polyurethane foam and the possibility of replacing HFC-36smfc was examined by evaluating how each blowing agent(CFC-11, HCFC-l4lb, HFC-36smfc) affects the reactivity, mechanical property and cell morphology. Results of the experiment showed that as the functionality and OH-value of polyol increased, there was an increase in the temperature profile, reaction rate, density and compressive strength. However. as the functionality and OH-value increased. the ceil size became smaller The use of different kinds of blowing agents did not appear to have and significant influence on the temperature profile, reaction rate, density and compressive strength. The foam using HFC-365mfc produced more uniform cells compared to the foam using HCFC-l4lb.

• Polymer(Korea)
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• v.29 no.5
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• pp.457-462
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• 2005

Polyurethane foams (PUFs) were prepared from polymeric 4,4'-diphenylmethane diisocyanate (PMDI), mixed polyol with OH value of 480, silicone surfactant, three catalysts, and hydrofluorocarbon(HFC) as blowing agent. Balance (PC-8), gelling (33LV), and trimerization (TMR-2) catalysts were used. The effect of the catalysts on the physical properties of PUF with increase of isocyanate (NCO) index and aging time was investigated. The cell size of the PUF with PC-8 and 33LV slightly increased with an increase in NCO index from 100 to 170 but compressive strength did not change significantly. In case of trimerization catalyst, the compressive strength of PUF increased from 8.75 to 1$10.5 kg_f/cm^2$ and the cell size decreased with an increase in NCO index. The compressive strength of the PUF with 33LV increased from 9.21 to $10.15 kg_f/cm^2$ with an increase in aging time. However, there was no detectable change in the compressive strength of PUF with TMR-2. A possible interpretation of the results includes an additional cross-link reaction of non-reacted MDI and FTIR spectrum illustrated the change of NCO peak.