• Korean Journal of Materials Research
• /
• v.5 no.4
• /
• pp.405-411
• /
• 1995

급냉응고된 Al-3.51wt%Li-0.34wt%Zr 합금의 시효거동을 시차주사열량계(DSC)에 의한 열분석 방법으로 조사하였다. DSC에 의한 비열측정 결과 $\delta$’의 석출에 의한 발열반응과 $\delta$, $\beta$ 및 복합석출상의 석출에 의한 발열반응을 확인하였으며 $\delta$’ 및 $\delta$의 재고용에 의한 2개의 흡열반응을 확인하였다. 7$0^{\circ}C$ 저온시효시 $\delta$’의 석출에 의한 발열반응 이전에 흡열반응이 나타났으며 이것은 $\delta$’ 석출 이전에 $\delta$’ 전구생성물이 형성되었음을 의미한다. DSC 곡선상에 나타난 발열과 흡열곡선을 해석하여 얻은 $\delta$’상 석출과 재고용의 활성화에너지값은 각각 83KJ/mol과 98KJ/mol로서 Al-Li 2원계 및 Al-Li-Mg에 비해 높은 값을 나타내엇으며, 시효에 의한 강화가 일어나 DSC에 의한 비열변화 조사결과 나타난 $\delta$’상 석출 완료 시효조건점 (21$0^{\circ}C$, 1시간)에서 최고경도값(Hv 160)을 나타내었다.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 1996.05a
• /
• pp.124-124
• /
• 1996

• Journal of the Korean Ceramic Society
• /
• v.38 no.6
• /
• pp.545-550
• /
• 2001

본 연구에서는 분사연소합성(SCS)을 위한 기초단계로서 용액연소합성에 대한 거동을 살펴보고자 알루미나 합성을 모델로 하였으며 이를 위해 전구체에 대한 열분해거동, 그리고 각 온도에서의 평형종 분압 계산 및 합성과정을 조사하였다. 각각의 열중량 분석(TGA) 결과 산화제와 환원제(연료)의 열분해 이력이 서로 다르게 나타났으며, 열역학 응용 프로그램인 ChemSag에 의한 평형종 분압의 계산에서 연소속도를 저하시킬 수 있는 $CO_2$와 수증기 가스 분압이 상당부분 존재하였다. 산화제/환원제 혼합물의 열분석(DTA/TG) 결과 산화제와 환원제의 열분해 거동의 차이, 그리고 매우 작은 시료의 양으로 인해 263$^{\circ}C$에서 발열피크가 매우 작게 나타났다. 열분석 시료에 비해 발열 에너지를 높이기 위해 산화제와 환원제 혼합 전구체를 비이커에서 증기압을 조절하며 가열시켜 본 결과 27$0^{\circ}C$에서 $\alpha$-Al$_2$O$_3$생성물을 얻을 수 있었다. 따라서 분사연소합성 반응을 통해 세라믹 원료를 합성하기 위해서는 연소과정 중 열분해 거동과 평형종의 분압을 고려하여야 한다.

• Proceedings of the Korean Ceranic Society Conference
• /
• 2003.10a
• /
• pp.72.2-72
• /
• 2003

• Composites Research
• /
• v.33 no.2
• /
• pp.44-49
• /
• 2020

The cure kinetics of carbon fiber-reinforced prepreg for Vacuum Bag Only(VBO) process was studied by differential scanning calorimetry (DSC). The total heat of reaction (ΔH_total = 537.1 J/g) was defined by the dynamic scanning test using prepregs and isothermal scanning tests were performed at 130℃~180℃. The test results of isothermal scanning were observed that the heat of reaction was increased as the temperature elevated. The Kratz model was applied to analyze the cure kinetics of resin based on the test results. To verify the simulation model, the degree of cure from panels using different cure cycles were compared with the measurement. The simulation model showed that the error against the experimental value was less than 3.4%.

• Journal of the Korean Ceramic Society
• /
• v.41 no.1
• /
• pp.62-68
• /
• 2004

In this study, SHS process has been employed to fabricate porous $MoSi_2$ material with electric-resistive heating capability through the control of pore size. The preform for SHS reaction was consisted of molybdenum powder with different sizes and silicon powder with different contained quantity. The size of the $MoSi_2$ particles thus formed was determined by the generated heat of combustion, not by the size of molybdenum powder. However, the pore size of $MoSi_2$ composite was proportional to the particle size of molybdenum powder. that is the coarser the molybdenum powder used, the larget the formed pore size. Based on these results, the porous $MoSi_2$ composite could be fabricated with a desired pore size. By orienting the porous molybdenum disilicide-based material in the form of pore size gradient, porous materials used for filters with improved dirt-holding capacity can be manufactured.

• Composites Research
• /
• v.30 no.3
• /
• pp.181-187
• /
• 2017

The effect of nanoscopic and microscopic Fe, $Fe_3O_4$, and Ni particles and their shapes and substrate materials on the heating behavior of thermoplastic polyurethane (TPU) adhesive films was investigated via induction heating. The heat generation tendency of $Fe_3O_4$ particles was higher than that shown by Fe and Ni particles in the TPU adhesive films. When the Fe and Ni particle size was larger than the penetration skin depth, the initial heating rate and maximum temperature increased with an increase in the particle size. This is attributed to the eddy current heat loss. The heating behavior of the TPU films with Ni particles of different shapes was examined, and different hysteresis heat losses were observed depending on the particle shape. Consequently, the flake-shaped Ni particles showed the most favorable heat generation because of the largest hysteresis loss. The substrate materials also affected the heating behavior of the TPU adhesive films in an induction heating system, and the thermal conductivity of the substrate materials was determined to be the main factor affecting the heating behavior.

• Proceedings of the KIEE Conference
• /
• 2009.07a
• /
• pp.2158_2159
• /
• 2009

본 논문에서는 DC전원설비 접속부에서의 접촉불량에 의한 발열 특성에 대하여 실험, 분석하였으며 사용된 DC 전원설비는 상용 교류전원을 직류전원으로 변환하는 AC/DC 컨버터의 출력전원을 이용하는 LED 가로등 조명설비의 전원 접속부을 대상으로 하였다. 외부의 기계적 진동에 의해 동전선 접속부에 아크와 열이 발생하며 이때 발생한 발열 온도와 열 분포를 측정하였으며 적열부가 형성된 후 25분이 경과하였을 때 최고 $842.68^{\circ}C$까지 온도가 상승하였으며 접속부의 접촉전압은 1.5~1.6V, 통전전류는 6.6~6.9A로 약간의 변화만 나타남을 볼 수 있었다. 또한 DC전원에서 동전선 접속부에서의 산화물 생성과 증식 거동에 대하여 분석하였으며 AC전원에서와 유사하게 산화물이 형성되어 성장함을 볼 수 있었다. 이러한 실험과 분석 결과는 향후, DC 전원설비에서의 전기화재 예방을 위한 자료로 활용 가능할 것으로 기대된다.

• Tunnel and Underground Space
• /
• v.14 no.4
• /
• pp.269-274
• /
• 2004

In this study reduced-scale experiments were conducted to determine the backlayering distance in tunnel fires. The 1/20 scale experiments were carried out under the Froude scaling using ethanol square pool fire ranging from 8 to 1km in each side with total heat release rate from 2.47 to 12.30 ㎾. It has been found that ventilation velocity increases with aspect ratio(tunnel height/tunnel width). At L$\_$B/$\^$*/ ＜5 the ventilation velocity increases proportional to the backlayering distance from 0.25 power of the heat release rate. However at L$\_$B/$\^$*/ $\geq$5 the ventilation velocity varies as the 0.3 power of the heat release rate.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2009.05a
• /
• pp.359-360
• /
• 2009

This Study is performed Mock-up test accounting for height of placement to review behavior of mass concrete according to kinds of cement & form. First, we measured hydration heat and show a different hydration heat generation characteristics as compared with each other. And we measured mortar outflow, the strength of concrete core and standard specimens, concrete's ability to resist chloride ion penetration in order to durability estimation of concrete. This study was aims to improve quality of mass concrete under marine environment.