• Title/Summary/Keyword: 발색도

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Electrochemical Characteristic on Lithium Intercalation into the Interface between Organic Electrolyte and Amorphous WO3 Thin Film Prepared by e-beam Evaporation Method (e-beam 증발법으로 제조된 비정질 WO3박막과 전해질 계면으로 삽입되는 리튬의 층간 반응에 관한 전기화학적 특성)

  • Min, Byoung-Chul;Sohn, Tae-Won;Ju, Jeh-Beck
    • Applied Chemistry for Engineering
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    • v.8 no.6
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    • pp.1022-1028
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    • 1997
  • This work was performed to study the characteristics of electrochemical intercalation reactions occurring at the interface between the organic electrolyte and tungsten trioxide thin film (thickness of $4000{\AA}$) prepared by e-beam evaporation method as cathodically coloring oxide with regard to the electrochromism by the intercalating reactions of the lithium cation in the 1M $LiClO_4/PC$ organic solution. The characteristics of electrochemical intercalation reactions were investigated by various DC electrochemical methods such as cathodic Tafel polarization test, multiple and the single sweep cyclic voltammetry and the coulomety titrations method. The surfaces of thin films were observed with the patterns of X ray diffraction after the coloring and bleaching reactions. In comparison with the previous results that $WO_3$ thin film intersely detached from the surface of electrode when the hydrogen cation was intercalated into $WO_3$ thin film in the o.1N $H_2SO_4$ aqueous solution, the intercalation reaction of lithium cation into $WO_3$ thin film in the 1M $LiClO_4/PC$ organic solution was shown that the stable bleaching and coloration was appeared within 1.0V of the applied overpotential. When the overpotential of electrochromic reaction for lithium cation in the 1M $LiClO_4/PC$ organic solution had been applied up to 1.5V, the accumulation phenomenon of lithium in amorphous $WO_3$ thin film layer occurred because the inserted lithium into amorphous $WO_3$ thin layer for coloring process was not fully removed from the thin layer to the electrolyte during bleaching process. It was found that there is a limitation of applied overpotential for coloring process by the reduction of the current densities of bleaching and coloration after few number of coloring and bleaching cycles.

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Effects of Proteins on the Reactivity of Various Phenolic Compounds with the Folin-Ciocalteu Reagent (다양한 페놀성 물질과 Folin-Ciocalteu 시약과의 반응성에 미치는 단백질의 영향)

  • Park, Kyung A;Choi, Yoo-mi;Kang, Smee;Kim, Mi-Ri;Hong, Jungil
    • Korean Journal of Food Science and Technology
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    • v.47 no.3
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    • pp.299-305
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    • 2015
  • The Folin-Denis assay using the Folin-Ciocalteu (F-C) reagent has been commonly used for analyzing the total phenolic compound content in various food products. In the present study, the effects of proteins on the reactivity of the F-C reagent with different phenolic compounds were investigated. Bovine serum albumin (BSA) or skim milk proteins showed a concentration-dependent increase in color response in the Folin-Denis assay; these proteins decreased the color response of most phenolic compounds tested. The reactivity of phenolic compounds was significantly less pronounced in the presence of BSA and this interference was greater at higher concentrations of phenolic compounds. The reactivity of phenolic compounds with the F-C reagent was reduced significantly by their oxidation; the reaction of the oxidized products with the F-C reagent was more severely affected by BSA. The interfering effects in the Folin-Denis assay might be attributable to binding interactions of phenolic compounds with proteins.

The Effect of Micro Constituent Element on the Development of Unique Color of Koryo Celadon (고려 청자 유약 발색에 미량 성분이 미치는 영향)

  • 김형태;이세용;함청순;최의석
    • Journal of the Korean Ceramic Society
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    • v.38 no.6
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    • pp.522-530
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    • 2001
  • 발굴된 과거 고려청자의 화학성분조성과 물리적 특성에 대한 평가를 하고 미량성분의 청자의 발색에 미치는 영향을 고찰한 결과, 고려 청자 태토는 Fe$_2$O$_3$가 2%, TiO$_2$가 0.8% 함유되어 있었으며, 청자유는 석회.장석유로서 Fe$_2$O$_3$가 1.0~1.2%, TiO$_2$가 0.16% 포함되어 있었다. 비색청자의 경우 미량성분인 MnO$_2$가 P$_2$O$_{5}$의 함량이 0.37%와 0.76%, CuO는 300~500ppm 정도 함유하고 있었다. 반사율 측정 결과 일반적인 청자가 540~570nm의 장파장대에서의 반사율이 급격히 떨어지는데 반하여, 13세기 비색 청자의 것은 적색 파장대에서 10%이상 높았다. CoO는 미량 첨가로도 유약의 청색 파장대 반사율이 높고, 적색 파장대의 반사율이 급격히 떨어지며 청자 발색에 부정적인 영향을 미쳤다. CuO는 0.05%를 첨가했을 경우 적색 파장대에서 반사율 곡선이 높게 나타나고 있어 비색 청자발색에 효과적이었다. 또한 명도를 나타내는 L*값도 CuO가 첨가된 유약이 가장 높았고, 비색청자의 색상은 녹청자에 비해 맑고 깊은 색감을 보였다.

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Development of Simple Colorimetric Method for Detecting Contamination of Liquid Spawn of Oyster Mushroom by pH Indicator (pH지시약을 이용한 느타리버섯 액체종균 오염 간이진단법 개발)

  • Jang, Myoung-Jun;Lee, Yun-Hae;Ju, Young-Cheol
    • The Korean Journal of Mycology
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    • v.36 no.1
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    • pp.9-15
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    • 2008
  • For the detection of contaminated liquid spawn, we selected suitable medium, indicator and developed method of diagnosis. The growth of pathogenic bacteria, Pseudomonas sp., and fungi, Trichoderma sp., in YPL media was better than in PDA and NA. In addition, the changes of color and absorbance of media were obviously showed when contaminated liquid spawn by pathogenic bacteria and fungi was incubated on YPL including phenol red for 48 hour at $25^{\circ}C$. The color of YPLP after incubating of infected liquid spawn by Pseudomonas sp. and Trichoderma sp. were changed from orange to red and to scarlet, respectively. Whereas, the color of YPLP after incubation of only Pleurotus ostreatus indicated yellow at liquid spawn. Therefore, it is possible to easily distinguish contaminated liquid spawn by color of change in YPLP.

The develop of hydrogen coating agent used for discolor improvement of DTP (Color발색을 개선한 실사출력용 수성코팅제 개발)

  • Lee, Eun-Jeong;Gu, Gang;Yun, Jin-Yong;Jo, Yeon-Jeong
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.04a
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    • pp.138-140
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    • 2008
  • 현재 현수막의 코팅에서 기능을 부여하는 수요가 늘고 있다. 본 실험에서는 코팅제의 유기용제 사용으로 인한 환경오염 문제및 폐기물 처리비용 부담을 줄이기 위하여 수성코팅제를 개발하려한다. acryl binder, 탄산칼슘, silica, 유화제등을 혼합한 코팅제를 knife coating한 후 170$^{\circ}C$로 1분 30초간 열처리 하였다. 이때 acryl binder의 첨가비율은 35${\sim}$55%로 변화를 주었다. 처리한 폴리에스테르에 DTP printing을 한 후 CCM 측정, 내수성, 접착성을 알아본 결과 acryl binder의 첨가비율은 45%일때 가장 우수한 발색성 및 printing 특성을 나타내었다. 기존 수성코팅제에 대비 20${\sim}$30% 발색성이 개선되었다.

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Analysis on the Physical Properties of $Prism^{(R)}$ Fabrics for garment According to Caustic Reduction Conditions (의류용 구조발색 섬유의 감량조건에 따른 물성 분석)

  • Jo, Jin-Hwang;Kim, Sang-Ryong;Choe, Yeong-Hui;Kim, Seung-Jin
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.10a
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    • pp.59-60
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    • 2008
  • 본 연구는 섬유의 구조적, 광학적 설계에 의해 빛의 간섭현상을 이용하여 색을 발현하는 구조발색 의류소재의 개발을 위하여 삼각단면의 구조발색섬유를 방사하고 직물을 제직한후 온도와 시간에 따른 삼각단면 섬유소재의 감량조건을 달리하여 그에 따른 $Prism^{(R)}$ 의류용 직물의 역학물성 및 태 특성을 측정하였다. 역학물성에는 인장특성, 인열특성을 측정하였으며 KES-FB system을 이용하여 역학물성을 측정 후 Hand value를 산출하였다.

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Characteristics of Color Development of the Black Concrete depending on CASB added Superplasticizer Dosages (CASB-SP 혼입율 변화에 따른 블랙콘크리트의 발색 특성)

  • Kim, Kyoung-Hoon;Hong, Seak-Min;Yoo, Seung-Yeup;Oh, Chi-hyun;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.05a
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    • pp.73-75
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    • 2012
  • In this study, basic physical properties and color development of the black concrete depending on CASB-SP dosages are investigated. According to results, It showed that the slump and air contents of the concrete containing CASB-SP meet all requirements of concrete except when CASB-SP 5.0 % is used. It also showed that the more the CASB-SP is used, the higher the compressive strength becomes. On the other hand, It is found that if the CASB-SP 5.0 % is used, the compressive strength was reduced as the more CASB-SP 5 % is used. In terms of color, it was found out that the more CASB-SP is used, the darker the black becomes.

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A Study on Growth of Citrine (황수정 육성에 관한 연구)

  • 박로학;유영문
    • Korean Journal of Crystallography
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    • v.1 no.1
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    • pp.8-13
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    • 1990
  • Synthetic citrines were grown by hydrothermal method. For the establishment of grown conditions of large citrine, various types and/or amount of nutrients, seed orientations, mineralizers, colorants and temperature gradients were studied. For the evaluation of the quality of as grown citrine, color tone, crystal form, macro-and micro-defects were observed and crystal structure and absorption spectrums were analyzed. As a result, large sized citrines of 205mm L x 58mm W x 35mm T with excellent color tone and minium defects were grown.

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Fundamental Properties and Chromaticity Development of Color Mortar with Pigment Type and Contents (칼라 안료 종류 및 혼입률 변화에 따른 칼라 모르타르의 기초물성 및 발색특성)

  • Park, Jun-Hee;Lee, Myung-Ho;Jung, Sang-Woon;Zha, O-Yang;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.11a
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    • pp.190-191
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    • 2013
  • In this research, the fundamental experiment for colour concrete(by using pigment) has been invested. Fundamental properties and dyeability for the colour mortar as the changing replacement ratio of pigment has been tested. For the conclusion, with the increasing ratio of pigment, the flow and compressive strength for the mortar has been decreased, For the dyeability, there's little difference when replacement ratio of dyestuff changed when the colour is red and yellow, but large difference when the blue pigment was used. Consider about the workability and strength of the mortar, the optimum pigment's replacement ratio is fixed as 2.5%.

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Expression and Inheritance Patterns of Gus Gene Driven by an Endosperm-Specific Promoter in Transgenic Tobacco (배유 특이 프로모터에 의해 유도된 GUS 유전자의 형질전환 담배 내에서의 발현 및 유전 양상)

  • Park, Young Doo;Kim, Hyoung Seok
    • Horticultural Science & Technology
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    • v.18 no.5
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    • pp.594-598
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    • 2000
  • This study was carried out to investigate the tissue-specific expression of ${\beta}$-glucuronidase (gus) gene driven by endosperm-specific promoter (Z4 promoter) in the transgenic tobacco and to find out inheritance pattern of transgene to the next generation. Tobacco (Nicotiana tabaccum cv. Havana SR1) was transformed with Agrobacterium tumerfaciens LBA4404 harboring BV3 construct containing gus gene driven by Z4 promoter and a kanamycin resistant gene. Seven hundred bp PCR products, indicating the presence of npt II gene, were found in the all eight transformants by PCR analysis using nptII primers. To study the expression pattern of the two different kind of promoters, leaf disks of the Z4pro-gus-transformed plants and 35Spro-gus-transformed plants were analyzed histochemically for gus activity. As a result, leaf disks of Z4pro-gus-transformed plants showed very weak and partial positive gus activity. In contrast, leaf disks of 35Spro-gus-transformed plants showed relatively strong positive gus activity. To investigate the expressed position of Z4 promoter, seeds from Z4pro-gus-transformed plants and 35Spro-gus-transformed plants were analyzed histochemically for gus activity. Z4pro-gus-transformed seeds showed positive gus activity restricted to the endosperm. However, the blue-colored product in 35Spro-gus-transformed seeds was observed in all the area including endosperm. Kanamycin resistance assay showed that transgenes were stably inherited to next generation in all lines.

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