• Title/Summary/Keyword: 발색도

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Analysis of the Physical Properties of Morphotex(R) According to Caustic Reduction Conditions (감량조건에 따른 Morphotex(R) 소재의 역학물성 분석)

  • Kim, Sang-Ryong;Kim, Seung-Jin;Gwon, O-Gyeong
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.04a
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    • pp.150-152
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    • 2008
  • 사회가 발달하여 감성사회로 접어들면서, 섬유산업도 새로운 감성소재를 개발하기 위한 연구를 추구하고 있다. 이러한 분야의 연구수단으로 생체모방(Biomimetics)을 활용하는 연구개발이 활발히 진행되고 있는데, 이중 미래지향적인 차세대 섬유로 Morphotex(R)를 이용한 Morpho 직물이 있다. 감성소재분야에서 '구조발색섬유'라고 불리어지는 독특한 색미를 가진 섬유소재인 Morphotex$^{(R)}$는 남미의 MORPHO 나비 날개의 구조적 발색원리를 모방하여 만든 광발색섬유로 염료와 안료를 사용하지 않는 친환경섬유이면서 고기능성과 쾌적성을 겸비한 소재로 요즘 많은 각광을 받고 있다. 본 연구에서는 구조발색 소재를 이용하여 제직한 감성의류소재 직물의 감량조건에 따른 감성특성을 비교.분석해보았다. 먼저 구조발색 소재로 제직 된 직물의 감량공정특성에 따른 구조발색 소재 직물의 인장 인열 특성을 분석하였으며 또한 KES-FB system으로 구조발색 소재 직물의 역학특성을 측정하고 측정한 역학특성으로부터 감성태를 평가해 보았다.

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Effect of Carbon Amino Silica Black Contained Superplasticizer on the Engineering Properties and Chromaticity of Black Color Concrete (카본 아미노 실리카 블랙 기반 고성능 감수제가 블랙 컬러 콘크리트의 공학적 특성 및 발색도에 미치는 영향)

  • Han, Min-Cheol;Hong, Seok-Min
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.3
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    • pp.181-188
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    • 2013
  • This paper is to investigate experimentally an effect of carbon amino silica black-superplasticizer(CASB-SP)on the engineering properties and chromaticity of black color concrete with 0.45 of W/C(water to cement). CASB-SP and carbon black were applied for pigment of the concrete. To prevent efflorescence of concrete, four different water repellent agents were also applied. As results, it was found that use of CASB-SP increased the slump and air contents. Furthermore, the use of CASB-SP increased the compressive strength. As CASB-SP dosages increased, chromaticity was well developed. For the effect of water repellent agent, the use of epoxy type was effective for protection from efflorescence. Based on test results, it was evaluated that 0.5% of CASB-SP effectively improve the concrete quality as well as enhance the chromaticity with proper dosage.

Study on Color Formation of Cheolhwa Buncheong Stoneware Glaze by Pigment Raw Materials of Iron Oxides and Firing Conditions (철산화물 안료 원료와 번조조건에 따른 철화분청사기의 유약 발색 연구)

  • Kim, Ji Hye;Han, Min Su;Jeong, Young Yu;Choi, Sung Jae
    • Journal of Conservation Science
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    • v.35 no.6
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    • pp.573-587
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    • 2019
  • In this study, reproducing specimens were made from mixing domestically produced magnetite, clay and non-plastic raw materials to reproduce the pigments used in the manufacture of traditional cheolhwa buncheong stoneware. In order to reveal the color fomation of glaze, 30 specimens with good color development were analyzed scientifically. Magnetite, which is the main raw material of the pigment, is a pigment capable of creating a dark black color in a reducing environment at 1,200℃. However, it reacts with the additionally added lime component and discolors to greenish yellow color in oxidizing environment at 1,230℃. Hematite is not significantly affected by the firing temperature and environment, but develops a dark black color when mixed with clay with iron content of more than 10%. The fluidity of the pigment is determined by R2O3/RO2 value, which also affects the color development. In the microtexture observation, the color formation of the glaze layer and the iron oxide crystals identified some differences depending on the particle size of the pigment and the firing environment. Reproduced specimens made of magnetite are present in the form of aggregates of iron oxide in the interface between glaze layer and slip layer in the oxidizing environment at 1,200℃. However, in the reducing environment, aggregates of iron oxides do not exist in the reproduced specimens, and they are homogeneously distributed in the glaze layer and formed a dark black color. In contrast, hematite-based specimens form dendritic structures in the glaze layer in an oxidizing environment and develop black.

Studies on the Synthesis of Yellow Coupler and Color Development (황색 발색제의 합성과 발색현상에 관한 연구)

  • Kim, Yeoung-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.1
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    • pp.116-121
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    • 2012
  • In this paper, yellow coupler was prepared by the reaction of ${\alpha}$-pivaloyl- 2-chloro-5-aminoacetaniline hydrogen chloride with 1-hexadecane sulfonyl chloride in the presence of pyridine. The product was identified by using various analytical tools such as melting poin elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, mass spectrometer. The reaction of yellow coupler with CD-3(color development agent) was shown yellow color.

Feasibility Study of On-site Analysis on Ammonium ion (암모늄이온의 현장 분석 방법 개발에 관한 기초 연구)

  • Jung, Yong-Jun
    • Journal of Wetlands Research
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    • v.16 no.2
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    • pp.275-280
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    • 2014
  • Because ammonia in water body can cause water pollution as a result of generating ammonium ion, it is of importance in the management of water quality. This work performed to analyze the ammonium ion by measuring the color band length on the basis of modifying the indophenol method. When 1-naphthol was employed as a coloring agent, the maximum absorbance was shown near 720nm, where the proper injection was in the range of 0.5-1.5ml. About 80% of absorbance was observed after the color development was made within the 20 minutes. In the manufacturing of coloring agent, the proper concentration of NaOH was 1.5-2.5M, and the effect of pH on the color development is negligible. In addition, the color development was effectively in the region of room temperature.

Development of Coloring Method of Didecyldimethylammonium Chloride (DDAC) in Wood Treated with Alkaline Copper Quat (ACQ) Preservative (구리·알킬암모늄화합물계 목재방부제(ACQ)를 처리한 목재 중의 Didecyldimethylammonium Chloride (DDAC) 성분의 발색처리 방법 개발)

  • Lee, Jong Shin;Choi, Gwang Sik
    • Journal of the Korean Wood Science and Technology
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    • v.46 no.3
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    • pp.253-259
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    • 2018
  • To determine the depth of preservative penetration in ACQ treated wood, the degree of penetration of Cu was measured. In this study, we developed a DDAC coloring method to investigate the penetration depth of DDAC, which is one of the active ingredient of ACQ, into wood. The following conclusions were obtained. The DDAC component reacts with a 2', 7'-dichlorofluorescein indicator and results in a deep orange color. This orange coloring reaction appears not only in DDAC solutions but also in ACQ treated wood tissues in which DDAC is present. It is possible to visually verify that DDAC has better wood penetration than Cu in the spruce, which is an refractory wood species, by the DDAC coloring method developed this study. In addition to the results, it is necessary to investigate the difference in penetration of Cu and DDAC for other wood species with poor preservative penetration.

The Physical Property of the Structural Color Yarn and Fabric for Emotional Garment Using Biomimetic Technology (생체모방기술을 응용한 감성의류용 구조발색사와 직물의 물성)

  • Kim, Hyun-Ah;Kim, Seung-Jin
    • Science of Emotion and Sensibility
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    • v.15 no.1
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    • pp.141-148
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    • 2012
  • This study investigated the structural coloration and fabric hand of the caustic reduced fabrics for emotional garment using structural color yarns, which was spun by 37 alternating nylon and polyester layers capable of producing basic colors using biomimetic technology. The colorations of the three kinds of structural color yarns were confirmed using multi angle spectro-photometer, and their triangular cross sections composed with 37 alternating nylon and polyester layers were measured using SEM and were discussed with layer length in relation with coloration and spinning conditions were also set up. The apparent color difference and reflectance of the three kinds of fabrics with different density and weave pattern were analysed as ranging from 400nm to 700nm. The optimum fabric structural design which is made by warp and weft densities(194ends/in ${\times}$ 105picks/in) and caustic reduction condition by $100^{\circ}C$ temperature and 60minutes with NaOH, 20g/l solution were decided through analysis of the mechanical properties and fabric hands of these three kinds of fabrics treated with 3 kinds of the caustic reduction conditions. And it was shown that the rate of caustic reduction was increased from 13% to 23% with increasing temperature and time of caustic reduction. The extensibility, bending rigidity and shear modulus of caustic reduction treated fabrics were decreased by treatment of caustic reduction, on the other hand fabric compressibility was increased. And it was shown that the hand value of specimen number one which was treated with temperature $100^{\circ}C$ and time 60minute was the best and the hand of this fabric was better than that of Morpho $fabric^{(R)}$ made by Teijin co. Japan.

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Introduction of Chromophores on the Activated Surface of Poly(2-trialkylstannylthioethyl acrylate) Films (Poly(2-trialkylstannylthioethyl acrylate) 필름의 표면 활성화를 통한 발색단 도입)

  • Yun, Jong Chul;Do, Jung Yun
    • Polymer(Korea)
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    • v.36 no.6
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    • pp.795-802
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    • 2012
  • Surface modification of a hydrophobic acrylic polymer film has been performed through simple chemical treatment to give a reactive surface. 2-Triphenylstannylthioethyl acrylate was polymerized under UV-illumination with various contents of a comonomer. When the polymer film was treated with fluoride ion, thiol functional group (SH) was generated on the film surface, which was observed through infrared absorption spectroscopy. The surface was functionalized by thiol addition reaction to acrylic chromophores. The SH content on the surface was controlled with a comonomer, tris(hydroxymethyl)ethane triacrylate, and examined with UV-Vis absorbance of the chromophore attached film. Similarly, a polymer film from 2-tributylstannylthioethyl acrylate was prepared. Destannylation from the triphenylstannyl and tributylstannyl surface completed after 30 and 5 min, respectively. The SH-exposed surface was modified with an isocyanate attached chromophore within 10 min, while acrylic chromophore required 24 h.

Comparison of Color-developing Methods for Phosphorus Analysis in Various Extractants for Soil Phosphorus (몇가지 토양인산(土壤燐酸) 추출용액(抽出溶液)의 인산(燐酸) 발색방법(發色方法) 비교(比較))

  • Yoon, Jung-Hui;Park, Baeg-Gyoon;Hwang, Ki-Sung
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.2
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    • pp.114-119
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    • 1998
  • Intensity and stability of the blue color of phospho-molybdate complex in P analysis are known to be influenced by the matrix, reducing regent and acidity of the extractants. Objective of this research was to compare the efficiency of the color-developing reagents for P concentrations in distilled water and extracts of Lancaster, Mehlich II, and Mehlich III methods. Efficiencies on which to base this study were evaluated by the optimum ranges of P, reproducibility of calibration curve and stability of the developed color. Color-developing reagents employed were ammonium molybdate-1,2,4- aminonaphtholsulfonic acid (ANS), ammonium molybdate-ascorbic acid-bismuth subcarbonate (AB), and ammonium molybdate-ascorbic acid-antimony potassium tartarate (AA). The ANS revealed the lowest sensitivity but the widest ranges for P concentrations in color development. On the other hand, the AA bore the narrowest color-developing ranges and its sensitivity was similar to AB. However, at P concentrations lower than $0.5mg\;L^{-1}$, AA was more sensitive than AB. Based on the data on the ranges of calibration curve, stability of color and reproducibility of analytical data. AA reagent was considered to be suitable for the determination of P in distilled water and AB reagent was practically recommendable for soil P analysis in extracts by Lancaster, Mehlich II, and Mehlich III procedures.

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