• Title/Summary/Keyword: 발달환경자원

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A Comparison Study of Alum Sludge and Ferric Hydroxide Based Adsorbents for Arsenic Adsorption from Mine Water (알럼 및 철수산화물 흡착제의 광산배수 내 비소 흡착성능 비교연구)

  • Choi, Kung-Won;Park, Seong-Sook;Kang, Chan-Ung;Lee, Joon Hak;Kim, Sun Joon
    • Economic and Environmental Geology
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    • v.54 no.6
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    • pp.689-698
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    • 2021
  • Since the mine reclamation scheme was implemented from 2007 in Korea, various remediation programs have been decontaminated the pollution associated with mining and 254 mines were managed to reclamation from 2011 to 2015. However, as the total amount of contaminated mine drainage has been increased due to the discovery of potential hazards and contaminated zone, more efficient and economical treatment technology is required. Therefore, in this study, the adsorption properties of arsenic was evaluated according to the adsorbents which were derived from water treatment sludge(Alum based adsorbent, ABA-500) and granular ferric hydroxide(GFH), already commercialized. The alum sludge and GFH adsorbents consisted of aluminum, silica materials and amorphous iron hydroxide, respectively. The point of zero charge of ABA-500 and GFH were 5.27 and 6.72, respectively. The result of the analysis of BET revealed that the specific surface area of GFH(257 m2·g-1) was larger than ABA-500(126~136 m2·g-1) and all the adsorbents were mesoporous materials inferred from N2 adsorption-desorption isotherm. The adsorption capacity of adsorbents was compared with the batch experiments that were performed at different reaction times, pH, temperature and initial concentrations of arsenic. As a result of kinetic study, it was confirmed that arsenic was adsorbed rapidly in the order of GFH, ABA-500(granule) and ABA-500(3mm). The adsorption kinetics were fitted to the pseudo-second-order kinetic model for all three adsorbents. The amount of adsorbed arsenic was increased with low pH and high temperature regardless of adsorbents. When the adsorbents reacted at different initial concentrations of arsenic in an hour, ABA-500(granule) and GFH could remove the arsenic below the standard of drinking water if the concentration was below 0.2 mg·g-1 and 1 mg·g-1, respectively. The results suggested that the ABA-500(granule), a low-cost adsorbent, had the potential to field application at low contaminated mine drainage.

Seismic Stratigraphy of Upper Devonian Carbonates Area in Northern Alberta, Canada (캐나다 북부 알버타주 데본기 후기 탄산염암 지역의 탄성파 층서)

  • Lee, Min-Woo;Oh, Jin-Yong;Yun, Hye-Su
    • Economic and Environmental Geology
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    • v.44 no.6
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    • pp.503-511
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    • 2011
  • The Upper Devonian Grosmont Formation in northern Alberta, Canada, underlies the erosion unconformity that formed between the Cretaceous and Upper Devonian. The formation is divided into four units on the basis of intercalated shales and showing a typical shelf environment of shallowing-upward. It was possible to separate four units(LG~UG3), considering the seismic interpretation attributes of polarity, continuity, frequency/spacing and amplitude and showing the reflection characteristics of the medium-high amplitude, medium-low frequency, good continuity, and subparallel reflection events. The formation can be interpreted as shelf or platform, based on in-situ core data. However, it is difficult, only with reflection attributes and features, to recognize the boundaries and sedimentary environment of parasequence. Therefore, we try to interprete by parasequence set in this study. The parasequence set was formed by erosion unconformity with systems tracts. The erosion unconformity can be recognized by facies data and karst, erosional surface. Grosmont carbonate deposits ranging from platform and shelf to shelf slope are; by wedge-shaped strata of characterized by complex sigmoid-oblique progradational configurations, reflecting a depositional history of upbuilding and outbuilding in response to sea-level changes. Most of the sedimentary units is interpreted as platforms under regression and lowstand environments that support is evidences. In particular, shale layer at the basal part of the highstand systems tracts represents the regressive to lowstand of sea level.

Magma Differentiation and Mineral Accumulation of the Sangnae-ri Dolerite Sill in the Okchon Belt (옥천대내 상내리 조립현무암질 암상에서의 마그마 분화와 광물의 집적)

  • Ahn, Kun-Sang;Kim, Hee-Nam;Shin, In-Hyun
    • Economic and Environmental Geology
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    • v.26 no.3
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    • pp.363-370
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    • 1993
  • Various sizes of dolerite sills occur in the Mungyong area, one of well-exposed areas in Okchon belt. All of previous geochemical studies concluded that chemical variations of basic rocks, so-called Sangnae-ri amphibolite, result from the fractional crystallization. The second sill, which is a well differentiated one in the Sangnae-ri area, displays systematic compositional variation associated with gradual change of grain size in vertical sections. In order to clarify the chemical variation in the sill, whether chemical composition of each part of the sill is appropriately derived from the original liquid (represented by the average composition) by addition or subtraction of initial phenocystic minerals are tested(Iwamori program, 1989). According to the calculation, it is shown that major vertical chemical variation of the sill resulted from the accumulation of phenocrysts(olivine, clinopyrxoene, plagioclase, titanomagnetite) which already existed at the time of emplacement or formed just after the emplacement.

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Characteristics on the Occurrence of Oxidized Copper at Suparaura, Peru: Preliminary Study (페루 수빠라우라 산화동 산출지의 특성: 예비연구)

  • Kim, Eui-Jun;Heo, Chul-Ho;Koh, Sang-Mo
    • Economic and Environmental Geology
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    • v.44 no.1
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    • pp.11-20
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    • 2011
  • Geological survey on the occurrence of copper oxide in Suparaura area around Abancay in the south-central part of Peru had been carried out. Geology of the area is composed of granitoids such as granodiorite, tonalite and andesitic porphyry related to Tertiary igneous activity, Ferrobamba formation with Cretaceous limestone and sandstone in descending order. Red sandstone is widely distributed and emplaced with their attitude of $N70^{\circ}W$ strike and $60^{\circ}NE$ dip. Copper oxides were mineralized along the bedding plane of red sandstone with maximum width of 30 cm. Ore-body structure bounding red sandstone strata have different occurrence characteristics with generally known porphyry system in terms of alteration, mineral assemblage and occurrence mode. Therefore, it is thought to be stratiform sediment-hosted copper (SSC) deposits genetically corresponding to Mississippi-valley type from preliminary study.

Thermo-hydraulic Modeling in Fault Zones (단층대에서의 열-수리적 거동 모델링)

  • Lee, Young-Min;Kim, Jong-Chan;Koo, Min-Ho;Keehm, Young-Seuk
    • Economic and Environmental Geology
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    • v.42 no.6
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    • pp.609-618
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    • 2009
  • High permeable faults are important geological structures for fluid flow, energy, and solute transport. Therefore, high permeable faults play an important role in the formation of hydrothermal fluid (or hot spring), high heat flow, and hydrothermal ore deposits. We conducted 2-D coupled thermal and hydraulic modeling to examine thermohydraulic behavior in fault zones with various permeabilities and geometric conditions. The results indicate discharge temperature in fault zones increases with increasing fault permeability. In addition, discharge temperature in fault zones is linearly correlated with Peclet number ($R^2=0.98$). If Peclet number is greater than 1, discharge temperature in fault zones can be higher than $32^{\circ}C$. In this case, convection is dominant against conduction for the heat transfer in fault zones.

Application of Seismic Tomography to the Region in and Near Southern Korean Peninsula (한반도 남부의 지진파 토모그라피 연구)

  • Kang, Ik-Bum;Park, Jung-Ho
    • Economic and Environmental Geology
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    • v.39 no.4 s.179
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    • pp.507-524
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    • 2006
  • 3-D seismic tomographic inversion is applied to investigation on velocity structure in and near Korean Peninsula. Firstly, it is applied to the region in southeastern Korean Peninsula. According to the results low-velocity zone seems to be clearly appeared in the so called Gyeongsang sedimentary basin and high-velocity zone is shown at the section of 7.5 km depth it implies the inclusion of plutonic rocks at the sedimentary basin. At the depth about $20{\sim}30$ km existence of low-velocity zone seems to be related with the development of Yangsan fault system. Secondly it is applied to the region not only in Korean Peninsula but also East Sea using data from both Korean Peninsula and Japan Islands. Accorging to the results, subduction zone starting from eastern part of Japan seems to be extended to the region beneath the East Sea.

On the Prospecting Plans of Mulkum Iron Mine Viewed by the Character and Mode of Occurrence of Ore bodyies (물금철산의 광체발달 양상과 그에 따른 탐광계획)

  • Kim, Seon Eok;Kang, Yang Pyeong
    • Economic and Environmental Geology
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    • v.2 no.1
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    • pp.13-33
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    • 1969
  • The Mulkum mine, located in Mulkum-myon, Yangsan-Kun, Kyeongsang Province, is one of the biggest iron mine in Korea. The geology of this mine and its vicinity consists of Chusan andesitic rocks and Datae-dong andesite porphyry of the Kyeongsang System which were intruded by biotite granite widely distributed near the vicinity of Mulkum-ni. The ore deposits, embedded in Dotae-dong andesite porphyry, are fissure-filling vein type in origin. Up to present ore bodies of Main vein, No. 2 vein, Eastern No. 1, 2 vein and Western No. 1 vein are exploited. Generally the veins strike N 10-25 E and dip to 60-90 SE. The proved length of vein is more than 500 meters and its depth 150 meters in Main vein with 3-4 meters of thickness in average. Ore minerals are mainly magnetite and locally associated with small amounts of hematite, sphecularite and chalcopyrite. Gangue minerals are quartz, epidote, chlorite, pyroxene, and garnet, etc. The modes of occurrence of vein are as follow; 1. Branching and parallel vein patterns are observed around main shaft in -1 level. 2. Multiple cymoid loops and subrectangular vein patterns are observed around main shaft in -2 level. 2. Single vein patterns are observed in -3 and -5 level. The ore-shoots plunge northeasterly about 20-30 degrees. In conclusion, the tectonically fractured zone belongs to the poorly mineralized zone and shoots are formed as single vein type. The general trends of one-shoots must be applied the prospecting of the deep-seated ore body in the deposits.

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Characteristics of Water Levels and Occurrences of Thermal Groundwater at the Yuseong Spa Area (유성지구 지열수자원의 산출 및 수위변동 특성)

  • Moon, Sang-Ho;Ha, Kyoo-Chul;Kim, Yung-Sik;Cho, Sung-Hyeon
    • Economic and Environmental Geology
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    • v.39 no.5 s.180
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    • pp.537-554
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    • 2006
  • Water levels of thermal groundwater ($>30^{\circ}C$) were recorded from March 2002 to June 2006 at several monitoring wells within the Yuseong spa area. Using these data, we elucidated the long-term cyclic fluctuations of thermal groundwater levels with 1 year period. We also observed a noticeable water level variation with periods of 0.5, 1 and 7 days in most monitoring wells, which indicates relatively good hydraulic connectivity within the main hotspring area. By comparing water level variations among several wells, we found out that E-W and N-S trending geological structures should be an important control factor for emplacement and flow of thermal groundwater in the study area. It may be also inferred that geothermal source is highly associated with the hydraulic connectivity of aquifers at the Yuseong spa area.

Modeling Study for Effects of Hydrothermal Clay Vein on Slope Stability (열수변질 점토맥이 사면 안정성에 미치는 영향에 관한 모델링 연구)

  • Jo, Hwan-Ju;Jo, Ho-Young;Jeong, Kyung-Mun
    • Economic and Environmental Geology
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    • v.43 no.2
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    • pp.185-196
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    • 2010
  • Clay veins that occurred in a slope by hydrothermal alteration, can significantly affect its slope stability. The effect of clay veins on the slope stability was investigated by numerical modeling study. Various parameters such as cohesion, internal friction angle, orientation, groundwater level, rainfall intensity and duration, have been modelled. As shear strength increased, factor of safety increased. As groundwater level developed, factor of safety decreased. For the case of slip surface developed on interface, factor of safety was lower than that for case of slip surface developed on either weathered soil or clay vein. The effect of various soil types of the slope stability was also investigated by simulating seepage through the slopes with various soils. The groundwater level significantly increased on the slopes with silty and generic soils. For the slope with sandy soil, almost no change in groundwater level was observed due to rapid drainage.

P Wave Velocity Anisotropy and Microcracks of the Pochon Granite Due to Cyclic Loadings (압축피로에 의한 포천화강암의 미세균열 발달과 P파속도 이방성)

  • Kim, Yeonghwa;Jang, Bo-An;Moon, Byeung Kwan
    • Economic and Environmental Geology
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    • v.30 no.4
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    • pp.353-362
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    • 1997
  • P wave velocities of core samples from the Pocheon granite were measured before and after applications of cyclic loading. Then. distribution of the pre-existing microcracks and microcracks developed due to the cyclic loading was investigated by analyzing P wave velocity anisotropies and microscopic observations from thin sections. Anisotropy constants were calculated with three different ways: (1) $C_A$ between the maximum and the minimum velocities, (2) $C_AI$ between velocities measured along the axial direction and the average of six velocities measured in the planes perpendicular to the loading axis (rift plane) and (3) $C_AII$ between the maximum and the minimum velocities measured in the plane perpendicular to the loading axis. Among anisotropy constants. $C_AI$ was the most effective anisotropy constant to identify the rift plane whose orientation is parallel to the pre-existing microcracks as well as the distribution of stress induced microcracks. $C_AI$ decreased after cyclic loading and the relationship between $C_AI$ and number of cycles shows comparatively coherent negative trends. indicating that stress induced microcracks are aligned perpendicular to the orientation of pre-existing microcracks and that the amounts are proportional to the number of loading cycles. The difference of anisotropy constants before and after cyclic loading was effective in delineating the level of cracks and we called it Induced Crack Index. Velocity measurements and microscopic observations show that anisotropy was caused mainly due to microcracks aligned to a particular direction.

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