• Title/Summary/Keyword: 반응 조건 최적화

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Optimization of Antioxidant Extraction from Dandelion (Taraxacum officinale) Leaves Using BBD-RSM (BBD-RSM을 이용한 민들레로부터 항산화성분의 추출공정 최적화)

  • Han, Kyongho;Jang, Hyun Sik;Hong, In Kwon
    • Applied Chemistry for Engineering
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    • v.30 no.4
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    • pp.408-414
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    • 2019
  • In this study, an antioxidant was extracted from dandelion leaves using traditional hot water and ultrasonic extraction methods. In order to optimize the extraction yield and total flavonoid, an antioxidant, Box-Behnken design (BBD) model among response surface analysis methods was used. In the case of hot water extraction, the extraction temperature and time as well as the ratio of alcohol/ultrapure water were set as variables, and for the ultrasonic extraction, the ultrasonic survey century and irradiation time and the ratio of alcohol/ultrapure water were variables. Optimum extraction conditions in the hot water extraction method were the extraction temperature and time of $45.76^{\circ}C$ and 1.75 h and the ratio of alcohol/ultrapure water of 41.92 vol.%. While for the ultrasonic extraction method the survey century of 512.63 W, the ratio of alcohol/ultrapure water of 56.97 vol.% and the extraction time of 20.79 min were optimum conditions. Expected reaction yield and flavonoid content values under the optimized condition were calculated as 22.09 wt.% and 28.98 mg QE/mL dw, respectively. In addition, the error value of less than 3% was obtained validating our optimization process.

Optimization and Evaluation of Flight Control Laws to Satisfy Longitudinal Handling Quality and Stability Margin Requirements (종축 비행성 요구도 및 안정성 여유 만족을 위한 비행제어법칙 최적화 및 평가)

  • Kim, Seong Hyeon;Ko, Deuk Won;Lee, Tae Hyun;Kim, Dong Hwan;Kim, Byoung Soo
    • Journal of Aerospace System Engineering
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    • v.15 no.5
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    • pp.8-15
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    • 2021
  • This paper describes a design method using an optimization technique to satisfy the longitudinal handling quality of high maneuverable jet aircraft. The dynamic inversion technique was applied to the target aircraft, and the control gain optimization satisfied the longitudinal short-period handling quality, however, the stability margin was not considered. If the stability margin is not satisfied, it is necessary to directly readjust the gains through trial and error methods for improvement. To improve this, an additional compensator and an optimization constraint were added to the control gain optimization procedure. In addition, the degree of handling quality satisfaction with the optimization result was reevaluated, and additional control evaluation criteria for the convergence of the time response and the steady state error that the flight performance requirement set as the optimization constraint cannot be reflected, and the results are described.

Pt/$Ce_{(1-x)}Zr_{(x)}O_2$ catalyst optimization for water gas shift reaction (WGS 반응용 Pt/$Ce_{(1-x)}Zr_{(x)}O_2$ 촉매 최적화)

  • Jeong, Dae-Woon;Kim, Ki-Sun;Eum, Ic-Hwan;Lee, Sung-Hun;Koo, Kee-Young;Yoon, Wang-Lai;Roh, Hyun-Seog
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.213-216
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    • 2009
  • WGS(Water Gas Shift)반응은 일산화탄소(CO)를 이산화탄소($CO_2$)로 전환하는 반응으로 일체형 수소생산시스템의 실현을 위한 고순도 수소생산에 있어서 중요한 단계이다. WGS 반응은 열역학적 평형을 고려하여 고온전이반응(HTS: High Temperature Shift)과 저온전이반응(LTS: Low Temperature Shift) 두 단계 반응으로 진행된다. 두 단계 공정의 통합을 위해 낮은 온도에서 높은 활성을 갖는 WGS 반응용 촉매 개발이 필요하다. 최근 낮은 온도에서 높은 활성을 갖는 귀금속 촉매에 다양한 담체를 적용시킨 연구가 활발히 진행되고 있다. 선행 연구 결과, Ce-$ZrO_2$ 구조는 Ce/Zr 비에 따라 다양한 특성 변화를 관찰하였다. 따라서 낮은 온도에서 높은 활성을 갖는 WGS 반응용 촉매 제조를 위해 환원성 담체인 $CeZrO_2$에 Pt 을 담지시켜 성능을 평가하였다. 제조된 모든 담체는 공침법(Co-precipitation)으로 제조 하였으며 $500^{\circ}C$에서 6시간 소성하였다. 제조된 담체에 백금(Pt)을 함침법(Incipient Wetness Impregnate)으로 담지시켰다. 특성분석은 BET를 이용하여 표면적을 측정하였다. 촉매 반응 실험조건은 $200^{\circ}C{\sim}400^{\circ}C$ 온도범위에서 기체공간속도(GHSV: Gas Hourly Space Velocity) 45,000 ml/$h{\cdot}g-cat$ 으로 혼합가스($H_2$:60%, $N_2$:20%,$CH_4$:1%,CO:9%,$CO_2$:10%)를 흘려 반응 후 배출되는 가스를 Micro-Gas Chromatography 를 이용하여 측정하였다.

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Optimization for the Physical Properties of Steamed Foam Cakes Prepared with Single-stage Method by Response Surface Methodology (반응표면 분석법에 의한 단단계법 거품형 찜 케이크의 물리적 특성의 최적화)

  • Kwhak, Sung-Ho;Jang, Myung-Sook
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.4
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    • pp.557-566
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    • 2005
  • In preparation of steamed foam-cakes, effects of whipping time, amount of wheat flour, and amounts of emulsifier on physical properties of the steamed foam cakes were investigated using RSM (response surface methodology). The three independent variables selected for the RSM experiment were whipping time $(X_1)$, amount of wheat flour $(X_2)$, and amounts of wheat flour $(X_2)$, and concentration of emulsifier $(X_3)$ were set for single-stage mixing, respectively. A rotatable central composite design was used for treatment arrangement. The responses from the product for loaf volume, color values and textural properties were analysed. In the analysis of variance for the foam cakes prepared by single-stage method, significant interactions were observed between independent variables (experimental factors) and physical property like loaf volume (p<0.05); textural properties like hardness, gumminess, and chewiness (p<0.05). Among independent variables, concentration of emulsifier had the most effects on physical properties while whipping time. The ordinary points in surface response showed maximal points with physical property like colorimetric b value while other properties revealed saddle points. The 3-dimensional response surface graphs of the predicted regression models displayed decreasing loaf volumes with increasing whipping times and emulsifier concentrations beyond optimum levels. The optimum conditions for best loaf volume and textural property (hardness, gummimess and chewiness) of the products selected by extracting intersectional areas of the contour maps that commonly overlapped all characteristics were; $11\~13$ min whipping time, $470\~486\;g$ amount of wheat flour, and $19\~20\;g$ emulsifier concentration, in case of single-stage method. The median values extracted from the RSM experimental results for optimum manufacturing conditions for single-stage method, i.e., 12 min whipping time, 478 g amount of wheat flour, and 20 g emulsifier concentration were empirically proven to fit the predicted levels of physical properties from the final foam cakes.

Emulsification of Natural Sunscreen with Green Tea Extract : Optimization Using CCD-RSM (녹차추출물이 함유된 천연 자외선차단 크림의 제조: CCD-RSM을 이용한 최적화)

  • Lee, Seung Bum;Zuo, Chengliang;Xu, Yang;Hong, In Kwon
    • Applied Chemistry for Engineering
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    • v.31 no.5
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    • pp.532-538
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    • 2020
  • In this study, emulsification process were conducted to manufacture the natural sunscreen from raw materials such as shea butter, olive emulsifier wax, and green tea extract. The emulsification was optimized by using the central composite design model-response surface methodology (CCD-RSM) where the response values were established as the mean droplet size (MDS) and emulsion stability index (ESI) after 7 days in addition to UV absorbance at 300nm. The amount of emulsifier and additives and emulsification time were established as operating variables and the optimal conditions of sunscreen emulsification were accepted as 3.70, 2.47 wt.%, and 15.42 min, respectively according to the result of CCD-RSM. On the other hand, the response values were estimated as 1173.80 nm and 99.56% for MDS and ESI, respectively, after 7 days, in addition to UV absorbance at 300 nm (2.47). The average error from actual experiments was a low level as about 3.0 ± 1.5%, which is mainly due to the fact that the optimization using CCD-RSM applied in this study was in the relatively high significant level.

Optimal Design of Gas/Liquid Separator for Fuel Cell System using CFD (CFD를 활용한 연료전지용 기액분리기 최적설계)

  • Lim, Jongkoo;Park, Jongcheol;Kho, Back Kyun;Kwon, Ki Wook;Shin, Hyunkhil;Hur, Taeuk;Cho, Sungbaek
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.85.1-85.1
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    • 2010
  • 캐스케이드형 연료전지 시스템에 있어서 각 스택의 단에서 전기화학반응에 의해 생성된 물을 분리하여 적절하게 배출시켜주는 것은 스택의 성능 및 내구성 향상을 위해 매우 중요하다. 이를 위해 연료전지 스택 각 단의 상이한 조건에 맞는 기액분리기의 설계가 필요하다. 유량에 따른 기액분리기의 부피와 원활한 연료 가스와 생성수의 분리를 위한 내부구조 및 입구 속도 등의 변수들에 따라 기액분리기의 성능 뿐만 아니라 연료전지 시스템 전체의 성능에 영향을 준다. 그러나 기액분리기의 폐쇄적 구조 때문에 실험을 통해 내부의 거동 및 현상을 파악할 수 없어 앞서 언급한 변수들의 효과를 확인할 수 없는 문제점이 있다. 이에 CFD(Computational Fluid Dynamics, 전산유체역학)를 활용하여 각 조건에 따른 기액분리기 내부의 현상을 파악하고 이를 통해 기액분리기 설계를 최적화하였다.

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염색가공 공정폐수에서 반응성 염료 분해 균주의 분리 및 배양 최적화

  • Sin, Jong-Cheol;Choe, Gwang-Geun;Jin, Jong-Hwa;Jeon, Hyeon-Hui;Kim, Sang-Yong;Lee, Jin-Won
    • 한국생물공학회:학술대회논문집
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    • 2003.04a
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    • pp.356-360
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    • 2003
  • Hundreds of microbial species were isolated and collected from dye-processing wastewater. Among them three species (named as RA1, RA2, and YA1) showed excellent ability of dye degradation. Especially, YA1 species could remove 53% of dye in 24 hours. To find optimal growth conditions for the isolated species, further research is going on.

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Optimal Design of the Steel Wheel's Disc Hole Using Approximation Function (근사함수를 이용한 스틸휠의 디스크 홀의 최적화)

  • 임오강;유완석;김우현;조재승
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.16 no.1
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    • pp.105-111
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    • 2003
  • Wheel for passenger car support the car weight with tires, and they transmit rolling and braking power into the ground. Whittling away at wheel weight is more effective to boost fuel economy than lighting vehicle body structure. A shape of hole in disk is optimized for minimizing the weight of steel wheel. Pro/ENGINEER program is used for formulating the design model, and ANSYS package is selected for analyzing the design model. It has difficulties to interface these commercial software directly. For Combining both programs, response surface methodology is applied to construct approximation functions for maximum stresses and maximum displacements are obtained by full factorial design of five levels. This steel wheel is modeled in 14-inch diameter of rim, and wide parameter of hole in disk is only selected as design variable for reducing the weight of steel whee. PLBA(Pshenichny-Lim-Belegundu-Arora) algorithm, which used the second-order information in the direction finding problem and uses the active set strategy, is used for solving optimization problems.

A Study on the Optimization of Ni-ZSM-5 Endothermic Catalyst Preparation for Decomposition of n-Dodecane (n-dodecane 분해를 위한 Ni-ZSM-5 흡열촉매 제조 최적화 연구)

  • Hyeonsu Jeong;Younghee Jang;Ye Hwan Lee;Sung Chul Kim;Byung Hun Jeong;Sung Su Kim
    • Applied Chemistry for Engineering
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    • v.34 no.6
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    • pp.619-625
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    • 2023
  • In order to solve problems caused by the heat load of hypersonic aircraft, this study examined the optimization of the Si/Al ratio of the catalyst and nickel ion exchange to improve the performance of the hydrocarbon decomposition reaction (endothermic reaction). It was confirmed that the catalysts prepared through Si/Al ratio optimization and nickel ion exchange showed about 10% improvement in heat absorption performance compared to thermal cracking at 4 MPa and 550 ℃. FT-IR and NH3-TPD analyses were found to identify factors affecting activity changes, and it was observed that the Si/Al ratio of the HZSM-5 catalyst was closely correlated with acid site development and catalytic activity. In addition, TGA and O2-TPO analyses were conducted to observe the carbon deposition inhibition properties of the nickel-added catalyst.

Topology, Shape and Sizing Optimization of the Jig Supporting High Voltage Pothead (고전압 장비 지그의 동특성에 대한 위상, 형상 및 치수 최적화)

  • Choi, Bong-Kyun;Lee, Jae-Hwan;Kim, Young-Joong
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.26 no.5
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    • pp.351-358
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    • 2013
  • In the electric power supplying industry, outdoor sealing end (pothead) is used and sometimes it is necessary to check the seismic qualification analysis or test which is intended to demonstrate that the equipment have adequate integrity to withstand stress of the specified seismic event and still performs their function. And since the pothead is mounted on the supporting jig, the avoidance of resonance between the pothead and jig is required. In order to design jig, three types of optimization are performed to get the minimum weight while satisfying the natural frequency constraint using ANSYS. Optimal array, position and thickness of truss members of the jig are obtained through topology, shape and sizing optimization process, respectively. And seismic analysis of the pothead on the jig for given RRS acceleration computes the displacement and stress of the pothead which shows the safety of the pothead. The obtained natural frequency, mass, and member thickness of the jig are compared with those of the reference jig which was used for seismic experimental test. The numerical results of the jig in the research is more optimized than the jig used in the experimental test.