• Title/Summary/Keyword: 반응 안정성

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c-BN 박막의 박리현상에 미치는 공정인자의 영향

  • 이성훈;변응선;이건환;이구현;이응직;이상로
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.148-148
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    • 1999
  • 다이아몬드에 버금가는 높은 경도뿐만 아니라 높은 화학적 안정성 및 열전도성 등 우수한 물리화학적 특성을 가진 입방정 질화붕소(cubic Boron Nitride)는 마찰.마모, 전자, 광학 등의 여러 분야에서의 산업적 응용이 크게 기대되는 자료이다. 특히 탄화물형성원소에 대해 안정하여 철계금속의 가공을 위한 공구재료로의 응용 또한 기대되는 재료이다. 특히 탄화물형성원소에 대해 안정하여 철계금속의 가공을 위한 공구재료로의 응용 또한 크게 기대된다. 이 때문에 각종의 PVD, CVD 공정을 이용하여 c-BN 박막의 합성에 대한 연구가 광범위하게 진행되어 많은 성공사례들이 보고되고 있다. 그러나 이러한 c-BN 박막의 유용성에도 불구하고 아직 실제적인 응용이 이루어지지 못한 것은 증착직후 급격한 박리현상을 보이는 c-BN 박막의 밀착력문제때문이다. 본 연구에서는 평행자기장을 부가한 ME-ARE(Magnetically Enhanced Activated Reactive Evaporation)법을 이용하여 c-BN 박막을 합성하고, 합성된 c-BN 박막의 밀착력에 미치는 공정인자의 영향을 규명하여, 급격한 박리현상을 보이는 c-BN 박막의 밀착력 향상을 위한 최적 공정을 도출하고자 하였다. BN 박막 합성은 전자총에 의해 증발된 보론과 (질소+아르곤) 플라즈마의 활성화반응증착(activated reactive evaporation)에 의해 이루어졌다. 기존의 ARE장치와 달리 열음극(hot cathode)과 양극(anode)사이에 평행자기장을 부여하여 플라즈마를 증대시켜 반응효율을 높혔다. 합성실험용 모재로는 p-type으로 도핑된 (100) Si웨이퍼를 30$\times$40 mm크기로 절단 후, 100%로 희석된 완충불산용액에 10분간 침적하여 표면의 산화층을 제거한후 사용하였다. c-BN 박막을 얻기 위한 주요공정변수는 기판바이어스 전압, discharge 전류, Ar/N가스유량비이었다. 증착공정 인자들을 변화시켜 다양한 조건에서 c-BN 박막의 합성하여 밀착력 변화를 조사하였다. 합성된 박막의 결정성 분석을 FTIR을 이용하였으며, Bn 박막의 상 및 미세구조관찰을 위해 투과전자현미경(TEM;Philips EM400T) 분석을 병행하였고, 박막의 기계적 물성 평가를 위해 미소경도를 측정하였다. 증착된 c-BN 박막은 3~10 GPa의 큰 잔류응력으로 인해 증착직후 급격한 박리현상을 보였다. 이의 개선을 위해 증착중 기판바이어스 제어 및 후열처리를 통해 밀착력을 수~수백배 향상시킬 수 있었다. c-BN 박막의 합성을 위해서는 증착중인 박막표면으로 큰 에너지를 갖는 이온의 충돌이 필요하기 때문에 기판 바이어스가 요구되는데, c-BN의 합성단계를 핵생성 단계와 성장 단계로 구분하여 인가한 기판바이어스를 달리하였다. 이 결과 그림 1에서 나타낸 것처럼 c-BN 박막의 핵생성에 필요한 기판바이어스의 50% 정도만을 인가하였을 때 잔류응력은 크게 경감되었으며, 밀착력이 크게 향상되었다.

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A Study on Suspension Optimization of the Korean Personal Rapid Transit Vehicle (한국형 PRT차량의 현가장치 최적화 연구)

  • Kim, Hyun Tae;Kim, Jun Woo;Cho, Jeong Gil;Koo, Jeong Seo;Kang, Seokwon;Jeong, Raggyo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.3
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    • pp.317-326
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    • 2016
  • In this study, running stability and ride quality analyses, applying the 'ISO 3888 (double lane change)' and 'ISO 2631-1' (mechanical vibration and shock) tests, were performed for the suspension optimization of the Korean personal rapid transit (PRT) vehicle. The suspension optimization results for running stability and ride quality were derived by applying the multiresponse surface method. From the comparisons of the optimization results for different ratios of the objective functions of running stability and ride quality, we derived the best objective function ratio of 3.9-to-6.1 to improve both the running stability and the ride quality. With the optimized results, the suspension stiffness became 30.68 N/mm, between the value of the $S_2$ and $S_3$ models, and the damping coefficient equaled that of the $D_1$ model. When compared with the suspension of the current PRT vehicle, the roll angle, yaw rate, sideslip angle, and ride comfort were improved by 0.37, 0.37, 2.8, and 5, respectively.

Preparation and Stability of Silyl Adlayers on 2×1-Reconstructed and Modified Si(100) Surfaces (Si(100)-2×1 표면과 개질된 Si(100) 표면 상에서 실릴 (Silyl) 흡착충의 형성과 안정성)

  • Jo, Sam-K.
    • Journal of the Korean Vacuum Society
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    • v.18 no.1
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    • pp.15-23
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    • 2009
  • Saturation-coverage silyl, $-SiH_3(a)$, overlayers were prepared from $Si_2H_6$ adsorption on three comparative surfaces: clean unmodified; D-precovered; and atomically roughened Si(100). Together with its precursor-mediated adsorption behavior, the surface reactivity of $Si_2H_6$ was found to be the highest on the unmodified Si(100)-$2{\times}1$ surface. This was correlated with its dissociative adsorption mechanism, in which both the $H_3Si-SiH_3$ bond scission and the dual surface $Si-SiH_3(a)$ bond formation require a surface dangling bond 'pair'. The unusually high thermal stability of $-SiH_3(a)$ on the unmodified surface was ascribed to a nearly close-packed $-SiH_3(a)$ coverage of ${\sim}0.9$ monolayer and the consequent lack of dangling bonds on the silyl-packed surface.

Effects of Soil pH on Growth, Yield and Its Varietal Differences in Soybean Cultivars. (토양산도에 따른 대두품종의 생육 및 수량반응과 그의 품종간 차이)

  • 이홍석;이석하
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.31 no.4
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    • pp.483-492
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    • 1986
  • To find out the responses of plant growth, nodulation, and yield of soybean and their varietal differences to different soil pH, 16 soybean cultivars were examined under three different levels of soil pH. In general, as the soil pH decreased, plant growth, nodulation, yield and yield component and protein con-tents of grains were decreased in most of cultivars studied. But there were significant varietal differences in the responses of the characters investigated to soil pH. Jangbaegkong was evaluated as the most tolerant cultivar to acid soil, and Ulsan, Bongeui, Hwanggeumkong, and LC7852 were also relatively torelant to acid soil. There were significant correlation between soil pH and grain yield in 7 cultivars among 16, but were not in other cultivars.

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Investigation of the Adsorption Phenomena of Surfactant on Hydrophilic Surface by Spectroscopic Method (분광학적 방법에 의한 계면활성제의 친수성 표면에 대한 흡착양상 연구)

  • Kim, Dong-Su
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.12
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    • pp.2215-2226
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    • 2000
  • Adsorption characteristics for homologous xanthates on quartz surface has been investigated by FT-IR spectroscopy to understand the adsorption mechanism in relation with verification of the influence of surfactants on the stability of hydrophilic suspended solids in aqueous system. Contact angle measurement for water droplets on quartz surface treated with xanthate was also conducted as a supplementary study for spectroscopic investigation to grant a reliability to the interpretation of experimental results. It has been observed that monolayer of ethyl xanthate was formed on quartz surface as the adsorption progressed and double layer of ethyl xanthate was formed eventually through the reverse oriented adsorption of xanthate molecules on the monolayer. Similar trend of adsorption to the case of ethyl xanthate was found for propyl and butyl xanthates and adsorption was observed to occur more rapidly as the number of carbon atom in alkyl group of xanthate homologs increased. Thermodynamic aspect of adsorption was discussed using Young's equation and the variation in adsorption rate was examined according to the concentration of ethyl xanthate. Based on the result, it has been concluded that the adsorption features of surfactant on substrate in aquatic system is governed by molecular structure and concentration of surfactant and its residual time in aqueous environment as dissolved state also influences greatly the stability of hydrophilic suspended particles.

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Production of Biodiesel Using Immobilized Lipase from Proteus vulgaris (Proteus vulgaris에서 유래한 리파아제의 고정화 및 바이오디젤 생산)

  • Yoon, Shin-Ah;Han, Jin-Yee;Kim, Hyung-Kwoun
    • Microbiology and Biotechnology Letters
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    • v.39 no.3
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    • pp.238-244
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    • 2011
  • Biodiesel, mono-alkyl esters of long chain fatty acids, is one of the alternative fuels derived from renewable lipid feedstock, such as vegetable oils or animal fats. For decade, various lipases have been used for the production of biodiesel. However, the production of biodiesel by enzymatic catalyst has profound restriction in industry application due to high cost. To overcome these problems, many research groups have studied extensively on the selection of cheap oil sources, the screening of suitable lipases, and development of lipase immobilization methods. In this study, we produced biodiesel from plant oil using Proteus vulgaris lipase K80 expressed in Escherichia coli cells. The recombinant lipase K80 was not only expressed in high level but also had high specific lipase activity and high stability in various organic solvents. Lipase K80 could produce biodiesel from olive oil by 3-stepwise methanol feeding method. The immobilized lipase K80 also produced biodiesel using the same 3-stepwise method. The immobilized lipase could produce biodiesel efficiently from various plant oils and waste oils.

Culture of Nile Tilapia (Oreochromis niloticus) in Recirculating Aquaculture System (순환여과식 양식 시스템에서 나일 틸라피아(Oreochromis niloticus)의 사육)

  • Seo Kuen Hack;Kim Byong Jin;Jo Jae Yoon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.35 no.1
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    • pp.27-34
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    • 2002
  • The performances of fish culture were evaluated in the integrated recirculating aquaculture system consisting of a double drain type rearing tank ($2.5 m^3$), a sedimentation tank, a floating bead filter, a foam separator and a rotating biological contactor. A system was stocked with nile tilapia at an initial rearing densities of $5\%$ (A), $5\%$ (B) and $7\%$ (C) oyer 30 days. Feed coefficient was 1.62, 1,79 and 1.80 and average daily growth rate was $0.452\%$, 0.u5% and $0.423\%$, respectively. The level of TAN was maintained below $1 g/m^3$ for $5\%$ of initial rearing density and $2-4 g/m^3$ for $7\%$. The dissolved oxygen level ($2-4 g/m^3$) was not optimum but should not be inhibitory to fish growth. The total suspended solid was completely removed during overall experimental period.

DEVELOPMENTAL PSYCHOPHARMACOLOGY - DEVELOPMENTAL PHARMACOKINETICS, PHARMACODYNAMICS AND PHARMACOGENETICS - (발달학적 정신약물학 - 발달학적 약동학, 약역학 및 약물유전학 -)

  • Cho, Soo-Churl
    • Journal of the Korean Academy of Child and Adolescent Psychiatry
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    • v.14 no.2
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    • pp.157-173
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    • 2003
  • The history of pediatric psychopharmacology is very short and the research on safety, efficacy and side effects is preliminary and long-term effect on growth and maturation is not well known yet. Clinical findings have shown that the responses to antidepressants, antipsychotics, CNS stimulants and steroids in children and adolescents might be different from adult populations. Based on these findings, this paper reviewed three issues, Firstly, in developmental pharmacokinetics. the author discussed the developmental factors affecting drug absorption, distribution, protein-binding, metabolism and excretion. Secondly, in developmental pharmacodynamics, developmental characteristics of dopamine, serotonin, norepinephrine receptors and their clinical implications were reviewed. Lastly, in pharamcogenetic part, the clinical utility of pharmacogenetics, pharmacokinetic aspects of pharmacogenetics, the pharmacodynamic aspects of pharmacogenetics, the association studies of dopamine-related alleles in neuropsychiatric disorders such as attention-deficit hyperactivity disorders or Tourette’s disorders, pharmacogenetic studies dopamine-related alleles and the pharmacogenetic studies of serotonin-related alleles. Based on these preliminary research, future pharmacogenetic applications in childhood and adolescent psychiatry were also discussed.

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Solvent-tolerant Lipases and Their Potential Uses (유기용매 내성 리파아제와 그 이용가능성)

  • Joo, Woo Hong
    • Journal of Life Science
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    • v.27 no.11
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    • pp.1381-1392
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    • 2017
  • This review described solvent-tolerant lipases and their potential industrial, biotechnological and environmental impacts. Although organic solvent-tolerant lipase was first reported in organic solvent-tolerant bacterium, many organic solvent-tolerant lipases are in not only solvent-tolerant bacteria but also solvent-intolerant bacterial and fungal strains, such as the well-known Bacillus, Pseudomonas, Streptomyces and Aspergillus strains. As these lipases are not easily inactivated in organic solvents, there is no need to immobilize them in order to prevent an enzyme inactivation by solvents. Therefore, the solvent-tolerant lipases have the potential to be used in many biotechnological and biotransformation processes. With the solvent-tolerant lipases, a large number insoluble substrates become soluble, various chemical reactions that are initially impossible in water systems become practical, synthesis reactions (instead of hydrolysis) are possible, side reactions caused by water are suppressed, and the possibility of chemoselective, regioselective and enantioselective transformations in solvent and non-aqueous systems is increased. Furthermore, the recovery and reuse of enzymes is possible without immobilization, and the stabilities of the lipases improve in solvent and non-aqueous systems. Therefore, lipases with organic-solvent tolerances have attracted much attention in regards to applying them as biocatalysts to biotransformation processes using solvent and non-aqueous systems.

Cardiovascular Responses over the Time Course during Muscle Group III Stimulation in Prehypertensive Individuals (고혈압 전단계자들에 대한 골격근 Group III 자극 시 시간에 따른 심혈관 반응)

  • Park, Won-Il;Park, Si-Young;Choi, Hyun-Min;Lee, Joon-Hee;Jeon, Jong-Mok;Kim, Jong-Kyung;Shim, Jae-Kun;Nho, Ho-Sung
    • Journal of Life Science
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    • v.19 no.11
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    • pp.1568-1574
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    • 2009
  • The purpose of this study was to investigate whether group III muscle afferents play an important role eliciting abnormal blood pressure response mediated during passive muscle stretch in prehypertensive individuals. Eleven middle-aged prehypertensive men (average BP 133/80 mmHg) and nine middle-aged normotensive men (average BP 119/74 mmHg) participated in this study. After 1 min rest baseline data collection, the subject's foot was flexed (dorsiflexion) by an automated cybex for one minute. Systolic blood pressure (SBP), diastolic blood pressure (DBP), mean arterial blood pressure (MAP), heart rate, stroke volume, cardiac output, and total peripheral resistance were continuously measured on a beat-by-beat basis from a finger via a Finapres device for 1 minute. To evaluate the role of mechanoreflex, a component of exercise pressor reflex, SBP, DBP, and MAP responses over the course of time were examined. The results showed that the pressor response mediated by the muscle mechanoreflex was faster in prehypertensive individuals compared to the normotensive individuals. The substantial pressor response was observed within mean 20 sec of the onset of passive stretch in prehypertension, while mean 45 sec in normotension (p<0.05). It is concluded that excessive pressor response produced during exercise in prehypertension may be due to the dysfunction of the mechano-receptors.